Boron Carbide-Zirconium Boride In Situ Composites by the Reactive Pressureless Sintering of Boron Carbide-Zirconia Mixtures
The heating of B4C–YTZP (where YTZP denotes yttria‐stabilized zirconia polycrystals) mixtures, under an argon atmosphere, generates B4C–ZrB2 composites, because of a low‐temperature (<1500°C) carbide–oxide reaction. Composites derived from mixtures that include ≥15% YTZP are better sintered than...
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| Published in | Journal of the American Ceramic Society Vol. 84; no. 3; pp. 642 - 644 |
|---|---|
| Main Authors | , , |
| Format | Journal Article |
| Language | English |
| Published |
Westerville, Ohio
American Ceramics Society
01.03.2001
Blackwell Wiley Subscription Services, Inc |
| Subjects | |
| Online Access | Get full text |
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| Abstract | The heating of B4C–YTZP (where YTZP denotes yttria‐stabilized zirconia polycrystals) mixtures, under an argon atmosphere, generates B4C–ZrB2 composites, because of a low‐temperature (<1500°C) carbide–oxide reaction. Composites derived from mixtures that include ≥15% YTZP are better sintered than monolithic B4C that has been fired under the same conditions. Firing to ∼2160°C (1 h dwell) generates specimens with a bulk density of ≥91% of the theoretical density (TD) for cases where the initial mixture includes ≥15% YTZP. Mixtures that include 30% YTZP allow a fired density of ≥97.5% TD to be attained. The behavior of the B4C–YTZP system is similar to that of the B4C–TiO2 system. Dense B4C–ZrB2 composites attain a hardness (Vickers) of 30–33 GPa. |
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| AbstractList | The heating of B4C–YTZP (where YTZP denotes yttria‐stabilized zirconia polycrystals) mixtures, under an argon atmosphere, generates B4C–ZrB2 composites, because of a low‐temperature (<1500°C) carbide–oxide reaction. Composites derived from mixtures that include ≥15% YTZP are better sintered than monolithic B4C that has been fired under the same conditions. Firing to ∼2160°C (1 h dwell) generates specimens with a bulk density of ≥91% of the theoretical density (TD) for cases where the initial mixture includes ≥15% YTZP. Mixtures that include 30% YTZP allow a fired density of ≥97.5% TD to be attained. The behavior of the B4C–YTZP system is similar to that of the B4C–TiO2 system. Dense B4C–ZrB2 composites attain a hardness (Vickers) of 30–33 GPa. The heating of B 4 C–YTZP (where YTZP denotes yttria‐stabilized zirconia polycrystals) mixtures, under an argon atmosphere, generates B 4 C–ZrB 2 composites, because of a low‐temperature (<1500°C) carbide–oxide reaction. Composites derived from mixtures that include ≥15% YTZP are better sintered than monolithic B 4 C that has been fired under the same conditions. Firing to ∼2160°C (1 h dwell) generates specimens with a bulk density of ≥91% of the theoretical density (TD) for cases where the initial mixture includes ≥15% YTZP. Mixtures that include 30% YTZP allow a fired density of ≥97.5% TD to be attained. The behavior of the B 4 C–YTZP system is similar to that of the B 4 C–TiO 2 system. Dense B 4 C–ZrB 2 composites attain a hardness (Vickers) of 30–33 GPa. The heating of B sub 4 C-TYZP (where YTZP denotes yttria-stabilized zirconia polycrystals) mixtures, under an argon atmosphere, generated B sub 4 C-ZrB sub 2 composites, because of a low-temperature ( < 1500 deg C) carbide-oxide reaction. Composites derived from mixtures that include > =15% YTZP are better sintered than monolithic B sub 4 C that has been fired udner the same conditions. Fring to approx2160 deg C (1 h dwell) generates specimens with a bulk density of > =91% of the theoretical density (TD) for cases where the initial mixture includes > =15% YTZP. Mixtures that include 30% YTZP allow a fired density of > =97.5% TD to be attained. The behavior of the B sub 4 C-YTZP system is similar to that of the B sub 4 C-TiO sub 2 system. Dense B sub 4 C-ZrB sub 2 composites attain a hardness (Vickers) of 30-33 GPa. |
| Author | Goldstein, Adrian Goldenberg, Ayala Geffen, Ygal |
| Author_xml | – sequence: 1 givenname: Adrian surname: Goldstein fullname: Goldstein, Adrian organization: Israel Ceramic and Silicate Institute, Haifa 32000, Israel – sequence: 2 givenname: Ygal surname: Geffen fullname: Geffen, Ygal organization: Israel Ceramic and Silicate Institute, Haifa 32000, Israel – sequence: 3 givenname: Ayala surname: Goldenberg fullname: Goldenberg, Ayala organization: Israel Ceramic and Silicate Institute, Haifa 32000, Israel |
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| Cites_doi | 10.1111/j.1151-2916.1995.tb08671.x 10.1016/0025-5416(88)90485-5 10.1007/BF00240800 10.1111/j.1151-2916.1969.tb11975.x 10.1016/S0955-2219(98)00071-5 10.1007/s11661-999-0230-6 |
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| Keywords | Reaction sintering Yttrium Oxides Boron Carbides Stabilized zirconia Manufacturing Experimental study Composite material Non oxide ceramics Structural ceramic Zirconium Borides |
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| Snippet | The heating of B4C–YTZP (where YTZP denotes yttria‐stabilized zirconia polycrystals) mixtures, under an argon atmosphere, generates B4C–ZrB2 composites,... The heating of B 4 C–YTZP (where YTZP denotes yttria‐stabilized zirconia polycrystals) mixtures, under an argon atmosphere, generates B 4 C–ZrB 2 composites,... The heating of B sub 4 C-TYZP (where YTZP denotes yttria-stabilized zirconia polycrystals) mixtures, under an argon atmosphere, generated B sub 4 C-ZrB sub 2... |
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| SubjectTerms | Applied sciences boron carbide Building materials. Ceramics. Glasses Ceramic industries Chemical industry and chemicals Exact sciences and technology sinter/sintering Structural ceramics Technical ceramics zirconia: yttria-stabilized tetragonal polycrystal |
| Title | Boron Carbide-Zirconium Boride In Situ Composites by the Reactive Pressureless Sintering of Boron Carbide-Zirconia Mixtures |
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