Correlating Pressure‐Induced Emission Modulation with Linker Rotation in a Photoluminescent MOF

• Published in: Angewandte Chemie International Edition Vol. 59; no. 21; pp. 8118 - 8122
• Main Authors: Sussardi, Alif, Hobday, Claire L., Marshall, Ross J., Forgan, Ross S., Jones, Anita C., Moggach, Stephen A.
• Format: Journal Article
• Language: English
• Published: Germany Wiley Subscription Services, Inc 18.05.2020; John Wiley and Sons Inc
• Edition: International ed. in English
• Subjects: Absorption; Absorption spectra; Chromophores; Communication; Communications; Conformation; Crystallography; Crystals; Diamond anvil cells; Emission spectra; Fluorescence; high-pressure chemistry; Luminescence; Metal-organic frameworks; Modulation; Optical properties; Perturbation; Photoluminescence; photophysics; Rotation; Single crystals; UV/Vis spectroscopy; high-pressure chemistry; photophysics; fluorescence; UV/Vis spectroscopy; metal-organic frameworks

Conformational changes of linker units in metal‐organic frameworks (MOFs) are often responsible for gate‐opening phenomena in selective gas adsorption and stimuli‐responsive optical and electrical sensing behaviour. Herein, we show that pressure‐induced bathochromic shifts in both fluorescence emiss...