Synthesis and Properties Evolution of a Family of Tiara-like Phenylethanethiolated Palladium Nanoclusters
Tiara-like thiolated group 10 transition metal (Ni, Pd, Pt) nanoclusters have attracted extensive interest due to their fundamental scientific significance and potential application in a number of fields. However, the properties ( e.g. the absorption) evolution with the ring size’s increase was not...
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| Published in | Scientific reports Vol. 5; no. 1; p. 16628 |
|---|---|
| Main Authors | , , , , , , , |
| Format | Journal Article |
| Language | English |
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Nature Publishing Group UK
16.11.2015
Nature Publishing Group |
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| Abstract | Tiara-like thiolated group 10 transition metal (Ni, Pd, Pt) nanoclusters have attracted extensive interest due to their fundamental scientific significance and potential application in a number of fields. However, the properties (
e.g.
the absorption) evolution with the ring size’s increase was not investigated so far to our best knowledge, due to the challenge of obtaining a series of nanocluster analogues. Herein, we successfully synthesized, isolated and identified a family of [Pd(SC
2
H
4
Ph)
2
]
n
nanoclusters (totally 17 novel clusters, n = 4–20). Their structures were determined to be tiara-like by single crystal X-ray crystallography together with theoretical calculation; their formation mechanism was proposed to be a substitution—polycondensation—ring-closure process based on experimental observations. All of these clusters are rather robust (anti-reductive and anti-oxidative) owing to their tiara-like structures with large HOMO-LUMO gaps. Finally, the optical and electrochemical evolution with the increase of ring size was investigated and it is found that both optical and electrochemical gaps have a “turning point” at a size corresponding to n = 8 for [Pd(SR)
2
]
n
nanoclusters. |
|---|---|
| AbstractList | Tiara-like thiolated group 10 transition metal (Ni, Pd, Pt) nanoclusters have attracted extensive interest due to their fundamental scientific significance and potential application in a number of fields. However, the properties (
e.g.
the absorption) evolution with the ring size’s increase was not investigated so far to our best knowledge, due to the challenge of obtaining a series of nanocluster analogues. Herein, we successfully synthesized, isolated and identified a family of [Pd(SC
2
H
4
Ph)
2
]
n
nanoclusters (totally 17 novel clusters, n = 4–20). Their structures were determined to be tiara-like by single crystal X-ray crystallography together with theoretical calculation; their formation mechanism was proposed to be a substitution—polycondensation—ring-closure process based on experimental observations. All of these clusters are rather robust (anti-reductive and anti-oxidative) owing to their tiara-like structures with large HOMO-LUMO gaps. Finally, the optical and electrochemical evolution with the increase of ring size was investigated and it is found that both optical and electrochemical gaps have a “turning point” at a size corresponding to n = 8 for [Pd(SR)
2
]
n
nanoclusters. Tiara-like thiolated group 10 transition metal (Ni, Pd, Pt) nanoclusters have attracted extensive interest due to their fundamental scientific significance and potential application in a number of fields. However, the properties (e.g. the absorption) evolution with the ring size's increase was not investigated so far to our best knowledge, due to the challenge of obtaining a series of nanocluster analogues. Herein, we successfully synthesized, isolated and identified a family of [Pd(SC2H4Ph)2]n nanoclusters (totally 17 novel clusters, n = 4-20). Their structures were determined to be tiara-like by single crystal X-ray crystallography together with theoretical calculation; their formation mechanism was proposed to be a substitution-polycondensation-ring-closure process based on experimental observations. All of these clusters are rather robust (anti-reductive and anti-oxidative) owing to their tiara-like structures with large HOMO-LUMO gaps. Finally, the optical and electrochemical evolution with the increase of ring size was investigated, and it is found that both optical and electrochemical gaps have a "turning point" at a size corresponding to n = 8 for [Pd(SR)2]n nanoclusters. Tiara-like thiolated group 10 transition metal (Ni, Pd, Pt) nanoclusters have attracted extensive interest due to their fundamental scientific significance and potential application in a number of fields. However, the properties (e.g. the absorption) evolution with the ring size's increase was not investigated so far to our best knowledge, due to the challenge of obtaining a series of nanocluster analogues. Herein, we successfully synthesized, isolated and identified a family of [Pd(SC2 H4 Ph)2 ]n nanoclusters (totally 17 novel clusters, n = 4-20). Their structures were determined to be tiara-like by single crystal X-ray crystallography together with theoretical calculation; their formation mechanism was proposed to be a substitution--polycondensation--ring-closure process based on experimental observations. All of these clusters are rather robust (anti-reductive and anti-oxidative) owing to their tiara-like structures with large HOMO-LUMO gaps. Finally, the optical and electrochemical evolution with the increase of ring size was investigated, and it is found that both optical and electrochemical gaps have a "turning point" at a size corresponding to n = 8 for [Pd(SR)2 ]n nanoclusters. Tiara-like thiolated group 10 transition metal (Ni, Pd, Pt) nanoclusters have attracted extensive interest due to their fundamental scientific significance and potential application in a number of fields. However, the properties (e.g. the absorption) evolution with the ring size's increase was not investigated so far to our best knowledge, due to the challenge of obtaining a series of nanocluster analogues. Herein, we successfully synthesized, isolated and identified a family of [Pd(SC2H4Ph)2]n nanoclusters (totally 17 novel clusters, n = 4-20). Their structures were determined to be tiara-like by single crystal X-ray crystallography together with theoretical calculation; their formation mechanism was proposed to be a substitution-polycondensation-ring-closure process based on experimental observations. All of these clusters are rather robust (anti-reductive and anti-oxidative) owing to their tiara-like structures with large HOMO-LUMO gaps. Finally, the optical and electrochemical evolution with the increase of ring size was investigated, and it is found that both optical and electrochemical gaps have a "turning point" at a size corresponding to n = 8 for [Pd(SR)2]n nanoclusters.Tiara-like thiolated group 10 transition metal (Ni, Pd, Pt) nanoclusters have attracted extensive interest due to their fundamental scientific significance and potential application in a number of fields. However, the properties (e.g. the absorption) evolution with the ring size's increase was not investigated so far to our best knowledge, due to the challenge of obtaining a series of nanocluster analogues. Herein, we successfully synthesized, isolated and identified a family of [Pd(SC2H4Ph)2]n nanoclusters (totally 17 novel clusters, n = 4-20). Their structures were determined to be tiara-like by single crystal X-ray crystallography together with theoretical calculation; their formation mechanism was proposed to be a substitution-polycondensation-ring-closure process based on experimental observations. All of these clusters are rather robust (anti-reductive and anti-oxidative) owing to their tiara-like structures with large HOMO-LUMO gaps. Finally, the optical and electrochemical evolution with the increase of ring size was investigated, and it is found that both optical and electrochemical gaps have a "turning point" at a size corresponding to n = 8 for [Pd(SR)2]n nanoclusters. |
| ArticleNumber | 16628 |
| Author | Chen, Jishi Liu, Liren Lin, Yuejian Yang, Jinlong Weng, Linhong Liao, Lingwen Wang, Chengming Wu, Zhikun |
| Author_xml | – sequence: 1 givenname: Jishi surname: Chen fullname: Chen, Jishi organization: Key Laboratory of Materials Physics, Anhui Key Laboratory of Nanomaterials and Nanotechnology, Institute of Solid State Physics, Chinese Academy of Sciences, Department of Materials Science and Engineering, University of Science and Technology of China – sequence: 2 givenname: Liren surname: Liu fullname: Liu, Liren organization: Hefei National Laboratory for Physics Sciences at the Microscale, University of Science and Technology of China – sequence: 3 givenname: Linhong surname: Weng fullname: Weng, Linhong organization: Department of Chemistry, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Fudan University – sequence: 4 givenname: Yuejian surname: Lin fullname: Lin, Yuejian organization: Department of Chemistry, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Fudan University – sequence: 5 givenname: Lingwen surname: Liao fullname: Liao, Lingwen organization: Key Laboratory of Materials Physics, Anhui Key Laboratory of Nanomaterials and Nanotechnology, Institute of Solid State Physics, Chinese Academy of Sciences – sequence: 6 givenname: Chengming surname: Wang fullname: Wang, Chengming organization: Hefei National Laboratory for Physics Sciences at the Microscale, University of Science and Technology of China – sequence: 7 givenname: Jinlong surname: Yang fullname: Yang, Jinlong organization: Hefei National Laboratory for Physics Sciences at the Microscale, University of Science and Technology of China – sequence: 8 givenname: Zhikun surname: Wu fullname: Wu, Zhikun organization: Key Laboratory of Materials Physics, Anhui Key Laboratory of Nanomaterials and Nanotechnology, Institute of Solid State Physics, Chinese Academy of Sciences |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/26567806$$D View this record in MEDLINE/PubMed |
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| Cites_doi | 10.1016/S0277-5387(00)86522-5 10.1023/A:1011310013637 10.1021/ic403050c 10.1002/anie.200600319 10.1016/S0020-1693(00)83966-3 10.1002/anie.201307480 10.1021/nn901137h 10.1016/S0277-5387(99)00245-4 10.1515/znb-1994-0609 10.1021/ja210596w 10.1021/ja906087a 10.1107/S0567740868004759 10.1038/nchem.589 10.1021/om00114a017 10.1002/adma.201400866 10.1038/nature12523 10.1038/ncomms4785 10.1021/ic061242o 10.1021/ja5017365 10.5012/bkcs.2009.30.4.846 10.1107/S0108270193005657 10.1039/c2dt30524k 10.1021/ic00169a010 10.1038/ncomms1802 10.1039/C4NR04981K 10.1021/jp055344w 10.1134/S1070328409020080 10.1107/S0108270187011892 10.1002/anie.200351896 10.1002/adfm.201001120 10.1039/b904932k 10.1021/ja049605b 10.1021/ja208555h 10.1021/ic00202a018 10.1002/anie.198900611 10.1021/ja403807f 10.1021/ja00950a049 10.1038/35003535 10.1038/nchem.1352 10.1002/smll.201102590 10.1021/ic4013069 10.3891/acta.chem.scand.48-0929 10.1515/znb-1987-0912 10.1002/anie.200907074 10.1016/S0277-5387(00)80392-7 10.1515/znb-1992-0706 10.1016/S0277-5387(00)84654-9 10.1039/B204273H 10.1039/J19700000875 |
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| References | Weissker (CR3) 2014; 5 Kunchur (CR41) 1968; 24 Kagalwala (CR12) 2013; 52 Gaete, Ros, Solans, Font-Atltaba, Brianso (CR23) 1984; 23 Tan (CR19) 2012; 41 Wu (CR9) 2012; 8 Zhang (CR7) 2014; 26 CR30 Ananikov (CR43) 2012; 134 Peng (CR50) 2000; 44 Wark, Stephan (CR26) 1989; 8 Dharmaratne, Krick, Dass (CR46) 2009; 131 Yamashina, Kataoka, Ura (CR45) 2014; 53 Cai, Kang (CR35) 1993; 12 Kriege, Henkel (CR39) 1987; 42 Woodward, Dahl, Abel, Crosse (CR17) 1965; 87 Wang (CR5) 2014; 53 Schneider, Horner, Olendzki (CR44) 1993; 49 Lopez-Acevedo, Kacprzak, Akola, Hakkinen (CR6) 2010; 2 Higgins, William Suggs (CR20) 1988; 145 Xiao, Jian, Zhang (CR29) 2009; 30 Jian, Jiao, Li, Zhao, Lu (CR31) 2003; 42 Lee, Donkers, Wang, Harper, Murray (CR49) 2004; 126 Sletten, Kovacs (CR33) 1994; 48 Stash, Perepelkova, Noskov, Buslaeva, Romm (CR40) 2001; 27 Mahmoudkhani, Langer (CR36) 1999; 18 Dance, Scudder, Secomb (CR14) 1985; 24 CR16 Chen, Choi, Kamat (CR8) 2013; 135 Miyamae, Yamamura (CR27) 1988; 44 Angamuthu, Bouwman (CR34) 2009; 11 Feld (CR28) 1992; 47 Wu, Chen, Jin (CR21) 2011; 21 Hakkinen (CR1) 2012; 4 Koo, Block, Kang, Liu, Zubieta (CR25) 1988; 7 Zhang (CR11) 2010; 49 Datta, John, Kulkarni, Pati (CR48) 2005; 109 Stash (CR42) 2009; 35 Chen, Kamat (CR10) 2014; 136 Capdevila (CR32) 1989; 8 Desireddy (CR2) 2013; 501 Zhang (CR13) 2011; 133 Dolamic, Knoppe, Dass, Burgi (CR4) 2012; 3 Qian, Zhu, Jin (CR47) 2009; 3 Barrera, Bayon, Suades, Germain, Declerq (CR37) 1984; 3 Yang, Smetana, Sorensen, Klabunde (CR18) 2007; 46 Kruger, Krebs, Henkel (CR22) 1989; 28 Schulbert, Mattes (CR38) 1994; 49 Zhang, Takada, Kolzer, Matsumoto, Tatsumi (CR15) 2006; 45 Zhu, Zhou, Yao, Liao, Wu (CR24) 2014; 6 HL Xiao (BFsrep16628_CR29) 2009; 30 M Zhu (BFsrep16628_CR24) 2014; 6 TA Wark (BFsrep16628_CR26) 1989; 8 Z Yang (BFsrep16628_CR18) 2007; 46 H Miyamae (BFsrep16628_CR27) 1988; 44 BK Koo (BFsrep16628_CR25) 1988; 7 Z Wu (BFsrep16628_CR21) 2011; 21 H Feld (BFsrep16628_CR28) 1992; 47 X Zhang (BFsrep16628_CR7) 2014; 26 AC Dharmaratne (BFsrep16628_CR46) 2009; 131 J-H Cai (BFsrep16628_CR35) 1993; 12 H Qian (BFsrep16628_CR47) 2009; 3 HC Weissker (BFsrep16628_CR3) 2014; 5 H Hakkinen (BFsrep16628_CR1) 2012; 4 O Lopez-Acevedo (BFsrep16628_CR6) 2010; 2 VP Ananikov (BFsrep16628_CR43) 2012; 134 AI Stash (BFsrep16628_CR40) 2001; 27 NG Kunchur (BFsrep16628_CR41) 1968; 24 BFsrep16628_CR30 X Peng (BFsrep16628_CR50) 2000; 44 J Sletten (BFsrep16628_CR33) 1994; 48 HN Kagalwala (BFsrep16628_CR12) 2013; 52 T Kruger (BFsrep16628_CR22) 1989; 28 A Datta (BFsrep16628_CR48) 2005; 109 R Angamuthu (BFsrep16628_CR34) 2009; 11 K Schulbert (BFsrep16628_CR38) 1994; 49 C Zhang (BFsrep16628_CR11) 2010; 49 AI Stash (BFsrep16628_CR42) 2009; 35 I Schneider (BFsrep16628_CR44) 1993; 49 C Tan (BFsrep16628_CR19) 2012; 41 Y Yamashina (BFsrep16628_CR45) 2014; 53 W Gaete (BFsrep16628_CR23) 1984; 23 Y-S Chen (BFsrep16628_CR8) 2013; 135 Y-S Chen (BFsrep16628_CR10) 2014; 136 M Kriege (BFsrep16628_CR39) 1987; 42 W Zhang (BFsrep16628_CR13) 2011; 133 S Wang (BFsrep16628_CR5) 2014; 53 BFsrep16628_CR16 P Woodward (BFsrep16628_CR17) 1965; 87 JD Higgins (BFsrep16628_CR20) 1988; 145 F-F Jian (BFsrep16628_CR31) 2003; 42 H Barrera (BFsrep16628_CR37) 1984; 3 I Dolamic (BFsrep16628_CR4) 2012; 3 C Zhang (BFsrep16628_CR15) 2006; 45 D Lee (BFsrep16628_CR49) 2004; 126 A Desireddy (BFsrep16628_CR2) 2013; 501 M Capdevila (BFsrep16628_CR32) 1989; 8 IG Dance (BFsrep16628_CR14) 1985; 24 Z Wu (BFsrep16628_CR9) 2012; 8 AH Mahmoudkhani (BFsrep16628_CR36) 1999; 18 24781134 - Nat Commun. 2014;5:3785 23718130 - J Am Chem Soc. 2013 Jun 19;135(24):8822-5 24670058 - J Am Chem Soc. 2014 Apr 23;136(16):6075-82 25350274 - Nanoscale. 2014 Nov 6;6(23):14195-9 22653469 - Dalton Trans. 2012 Jul 21;41(27):8472-6 24817169 - Adv Mater. 2014 Jul 9;26(26):4565-8 22475174 - J Am Chem Soc. 2012 Apr 18;134(15):6637-49 24005327 - Nature. 2013 Sep 19;501(7467):399-402 7841020 - Acta Chem Scand. 1994 Nov;48(11):929-32 15137785 - J Am Chem Soc. 2004 May 19;126(19):6193-9 20422664 - Angew Chem Int Ed Engl. 2010 Jun 7;49(25):4209-12 19725520 - J Am Chem Soc. 2009 Sep 30;131(38):13604-5 22133284 - J Am Chem Soc. 2011 Dec 28;133(51):20680-3 19842474 - Phys Chem Chem Phys. 2009 Jul 21;11(27):5578-83 23865570 - Inorg Chem. 2013 Aug 5;52(15):9094-101 21124516 - Nat Chem. 2010 Apr;2(4):329-34 16366612 - J Phys Chem A. 2005 Dec 29;109(51):11647-9 22531183 - Nat Commun. 2012 Apr 24;3:798 24474712 - Angew Chem Int Ed Engl. 2014 Feb 24;53(9):2376-80 16622894 - Angew Chem Int Ed Engl. 2006 Jun 2;45(23):3768-72 22488747 - Small. 2012 Jul 9;8(13):2028-35 24661117 - Inorg Chem. 2014 Apr 7;53(7):3558-67 19860401 - ACS Nano. 2009 Nov 24;3(11):3795-803 17335274 - Inorg Chem. 2007 Apr 2;46(7):2427-31 14661205 - Angew Chem Int Ed Engl. 2003 Dec 1;42(46):5722-4 22614378 - Nat Chem. 2012 Jun;4(6):443-55 10716439 - Nature. 2000 Mar 2;404(6773):59-61 |
| References_xml | – volume: 8 start-page: 1253 year: 1989 end-page: 1259 ident: CR32 article-title: Preparation and X-ray crystal structure of [Ni {μ-S(CH ) N(CH ) } ], a cyclic hexameric homothiolate of nickel publication-title: Polyhedron doi: 10.1016/S0277-5387(00)86522-5 – volume: 27 start-page: 585 year: 2001 end-page: 590 ident: CR40 article-title: Palladium clusters Pd (SEt) (OAc) and Pd (SEt) : structure and properties publication-title: Russ. J. Coord. Chem. doi: 10.1023/A:1011310013637 – volume: 53 start-page: 3558 year: 2014 end-page: 3567 ident: CR45 article-title: Tiara-like octanuclear palladium(II) and platinum(II) thiolates and their inclusion complexes with dihalo- or iodoalkanes publication-title: Inorg. Chem. doi: 10.1021/ic403050c – ident: CR16 – volume: 45 start-page: 3768 year: 2006 end-page: 3772 ident: CR15 article-title: Nickel(II) thiolate complexes with a flexible -{Ni S } framework publication-title: Angew. Chem. Int. Ed. doi: 10.1002/anie.200600319 – volume: 145 start-page: 247 year: 1988 end-page: 252 ident: CR20 article-title: Preparation, structure and spectroscopic studies of the palladium mercaptides Pd (S- Pr) and Pd (S- Pr) publication-title: Inorg. Chim. Acta doi: 10.1016/S0020-1693(00)83966-3 – volume: 53 start-page: 2376 year: 2014 end-page: 2380 ident: CR5 article-title: A 200-fold quantum yield boost in the photoluminescence of silver-doped Ag Au nanoclusters: The 13th silver atom matters publication-title: Angew. Chem. Int. Ed. doi: 10.1002/anie.201307480 – volume: 3 start-page: 3795 year: 2009 end-page: 3803 ident: CR47 article-title: Size-focusing synthesis, optical and electrochemical properties of monodisperse Au (SC H Ph) nanoclusters publication-title: ACS Nano doi: 10.1021/nn901137h – volume: 12 start-page: 397 year: 1993 end-page: 400 ident: CR35 article-title: Synthesis and structure of hexakis [di-μ-(4-chloro-brnzylthio) nickel] tritetrachloromethane solvate, [Ni(SCH C H Cl- ) ] ·3CCl publication-title: Jiegou Huaxue (Chinese J. Struct. Chem.) – volume: 18 start-page: 3407 year: 1999 end-page: 3410 ident: CR36 article-title: Structural investigation of nickel thiolates: a cyclic hexanuclear nickel thiolate with highly distorted NiS units publication-title: Polyhedron doi: 10.1016/S0277-5387(99)00245-4 – volume: 49 start-page: 770 year: 1994 end-page: 772 ident: CR38 article-title: Structure of 2 polynuclear nickel-thiolato-complexes [(μ-SMe) (Ni(MeNHCS )) ] and -[(μ-SMe) Ni] publication-title: Z. Naturforsch. B doi: 10.1515/znb-1994-0609 – volume: 134 start-page: 6637 year: 2012 end-page: 6649 ident: CR43 article-title: Catalytic adaptive recognition of thiol (SH) and selenol (SeH) groups toward synthesis of functionalized vinyl monomers publication-title: J. Am. Chem. Soc. doi: 10.1021/ja210596w – volume: 131 start-page: 13604 year: 2009 end-page: 13605 ident: CR46 article-title: Nanocluster size evolution studied by mass spectrometry in room temperature Au (SR) synthesis publication-title: J. Am. Chem. Soc. doi: 10.1021/ja906087a – volume: 24 start-page: 1623 year: 1968 end-page: 1633 ident: CR41 article-title: The crystal structure of palladium n-propyl mercaptide publication-title: Acta Crystallogr. B doi: 10.1107/S0567740868004759 – volume: 2 start-page: 329 year: 2010 end-page: 334 ident: CR6 article-title: Quantum size effects in ambient CO oxidation catalysed by ligand-protected gold clusters publication-title: Nature Chem. doi: 10.1038/nchem.589 – volume: 8 start-page: 2836 year: 1989 end-page: 2843 ident: CR26 article-title: Early metal thiolato species as metalloligands in the formation of early/late heterobimetallic complexes: syntheses and molecular structures of Cp Ti(SMe) , Cp V(SMe) , (Cp Ti(μ-SMe) ) Ni and (Ni(μ-SMe) ) publication-title: Organometallics doi: 10.1021/om00114a017 – volume: 26 start-page: 4565 year: 2014 end-page: 4568 ident: CR7 article-title: Ultrasmall Au (SG) nanomolecules for high tumor specificity and cancer radiotherapy publication-title: Adv. Mater. doi: 10.1002/adma.201400866 – volume: 501 start-page: 399 year: 2013 end-page: 402 ident: CR2 article-title: Ultrastable silver nanoparticles publication-title: Nature doi: 10.1038/nature12523 – volume: 5 start-page: 3785 year: 2014 ident: CR3 article-title: Information on quantum states pervades the visible spectrum of the ubiquitous Au (SR) gold nanocluster publication-title: Nature Commun. doi: 10.1038/ncomms4785 – volume: 46 start-page: 2427 year: 2007 end-page: 2431 ident: CR18 article-title: Synthesis and characterization of a new tiara Pd(II) thiolate complex, [Pd(SC H ) ] and its solution-phase thermolysis to prepare nearly monodisperse palladium sulfide nanoparticles publication-title: Inorg. Chem. doi: 10.1021/ic061242o – volume: 136 start-page: 6075 year: 2014 end-page: 6082 ident: CR10 article-title: Glutathione-capped gold nanoclusters as photosensitizers. Visible light-induced hydrogen generation in neutral water publication-title: J. Am. Chem. Soc. doi: 10.1021/ja5017365 – volume: 30 start-page: 846 year: 2009 end-page: 848 ident: CR29 article-title: Synthesis and structure analysis of α and β forms of [12] metallacrown-6 nickel(II) complex: [Ni (SCH CH CH ) ] publication-title: Bull. Korean Chem. Soc. doi: 10.5012/bkcs.2009.30.4.846 – volume: 49 start-page: 2091 year: 1993 end-page: 2093 ident: CR44 article-title: Structure of cyclo-hexakis[bis-μ-(methoxycarbonylmethylthiolato)-palladium(II)], [Pd(SCH COOCH ) ] publication-title: Acta Crystallogr. C doi: 10.1107/S0108270193005657 – volume: 41 start-page: 8472 year: 2012 end-page: 8476 ident: CR19 article-title: In situ synthesis of nickel tiara-like clusters with two different thiolate bridges publication-title: Dalton Trans. doi: 10.1039/c2dt30524k – volume: 23 start-page: 39 year: 1984 end-page: 43 ident: CR23 article-title: Synthesis and crystal and molecular structure of -tetrakis[bis(μ-N-methylpiperidine-4-thiolato)nickel(II)] publication-title: Inorg. Chem. doi: 10.1021/ic00169a010 – volume: 3 start-page: 798 year: 2012 ident: CR4 article-title: First enantioseparation and circular dichroism spectra of Au clusters protected by achiral ligands publication-title: Nature Commun. doi: 10.1038/ncomms1802 – volume: 6 start-page: 14195 year: 2014 end-page: 14199 ident: CR24 article-title: Reduction-resistant and reduction-catalytic double-crown nickel nanoclusters publication-title: Nanoscale doi: 10.1039/C4NR04981K – volume: 109 start-page: 11647 year: 2005 end-page: 11649 ident: CR48 article-title: Aromaticity in stable tiara nickel thiolates: computational and structural analysis publication-title: J. Phys. Chem. A doi: 10.1021/jp055344w – volume: 35 start-page: 136 year: 2009 end-page: 141 ident: CR42 article-title: Palladium clusters Pd (SR) (OAc) and Pd (SR) (R = Bu, Ph): Structure and properties publication-title: Russ. J. Coord. Chem. doi: 10.1134/S1070328409020080 – volume: 44 start-page: 606 year: 1988 end-page: 609 ident: CR27 article-title: Structure of the triclinic form of hexakis[di-μ-(ethanethiolato)nickel] and redetermination of its monoclinic form publication-title: Acta Crystallogr. C doi: 10.1107/S0108270187011892 – volume: 42 start-page: 5722 year: 2003 end-page: 5724 ident: CR31 article-title: [Ni (SCH CH OH) ]: A double crown [12]metallacrown-6 nickel(II) cluster publication-title: Angew. Chem. Int. Ed. doi: 10.1002/anie.200351896 – ident: CR30 – volume: 21 start-page: 177 year: 2011 end-page: 183 ident: CR21 article-title: One-pot synthesis of Au (SG) 2- and 4-nm gold nanoparticles and comparison of their size-dependent properties publication-title: Adv. Funct. Mater. doi: 10.1002/adfm.201001120 – volume: 11 start-page: 5578 year: 2009 end-page: 5583 ident: CR34 article-title: Reduction of protons assisted by a hexanuclear nickel thiolate metallacrown: protonation and electrocatalytic dihydrogen evolution publication-title: Phys. Chem. Chem. Phys. doi: 10.1039/b904932k – volume: 126 start-page: 6193 year: 2004 end-page: 6199 ident: CR49 article-title: Electrochemistry and optical absorbance and luminescence of molecule-like Au nanoparticles publication-title: J. Am. Chem. Soc. doi: 10.1021/ja049605b – volume: 133 start-page: 20680 year: 2011 end-page: 20683 ident: CR13 article-title: Nickel–thiolate complex catalyst assembled in one step in water for solar H production publication-title: J. Am. Chem. Soc. doi: 10.1021/ja208555h – volume: 24 start-page: 1201 year: 1985 end-page: 1208 ident: CR14 article-title: -Ni (SCH COOEt) , a receptive octagonal toroid publication-title: Inorg. Chem. doi: 10.1021/ic00202a018 – volume: 28 start-page: 61 year: 1989 end-page: 62 ident: CR22 article-title: Nickel complexes containing sterically demanding thiolate ligands: [Ni S(SC H ) ]-, a mixed-valence nickel sulfide thiolate cluster and [Ni (SC H ) ], a homoleptic nickel thiolate publication-title: Angew. Chem. Int. Ed. doi: 10.1002/anie.198900611 – volume: 135 start-page: 8822 year: 2013 end-page: 8825 ident: CR8 article-title: Metal-cluster-sensitized solar cells. A new class of thiolated gold sensitizers delivering efficiency greater than 2% publication-title: J. Am. Chem. Soc. doi: 10.1021/ja403807f – volume: 87 start-page: 5251 year: 1965 end-page: 5253 ident: CR17 article-title: A new type of cyclic transition metal complex, [Ni(SC H ) ] publication-title: J. Am. Chem. Soc. doi: 10.1021/ja00950a049 – volume: 44 start-page: 59 year: 2000 end-page: 61 ident: CR50 article-title: Shape control of CdSe nanocrystals publication-title: Nature doi: 10.1038/35003535 – volume: 4 start-page: 443 year: 2012 end-page: 445 ident: CR1 article-title: The gold-sulfur interface at the nanoscale publication-title: Nature Chem. doi: 10.1038/nchem.1352 – volume: 8 start-page: 2028 year: 2012 end-page: 2035 ident: CR9 article-title: Well-defined nanoclusters as fluorescent nanosensors: A case study on Au (SG) publication-title: Small doi: 10.1002/smll.201102590 – volume: 52 start-page: 9094 year: 2013 end-page: 9101 ident: CR12 article-title: Photocatalytic hydrogen generation system using a nickel-thiolate hexameric cluster publication-title: Inorg. Chem. doi: 10.1021/ic4013069 – volume: 48 start-page: 929 year: 1994 end-page: 932 ident: CR33 article-title: The structure of a toroidal, neutral, homoleptic Ni(II) complex with a chelate dithiolate ligand, [Ni (SCH CH CH S) ] publication-title: Acta Chem. Scand. doi: 10.3891/acta.chem.scand.48-0929 – volume: 42 start-page: 1121 year: 1987 end-page: 1128 ident: CR39 article-title: Ni (SET) and Ni (SC H ) , homoleptic nickel-thiolates with pentagonal-prismatic and cubane-like sulfur frameworks publication-title: Z. Naturforsch. B doi: 10.1515/znb-1987-0912 – volume: 49 start-page: 4209 year: 2010 end-page: 4212 ident: CR11 article-title: Dodecanuclear-ellipse and decanuclear-wheel nickel(II) thiolato clusters with efficient femtosecond nonlinear absorption publication-title: Angew. Chem. Int. Ed. doi: 10.1002/anie.200907074 – volume: 7 start-page: 1397 year: 1988 end-page: 1399 ident: CR25 article-title: Syntheis and structural characterization of -pentakis [bis(μ-trimethylsilylthiomethane)nickel(II)], [Ni(SCH SiMe ) ] , a pentametallic tiara structure publication-title: Polyhedron doi: 10.1016/S0277-5387(00)80392-7 – volume: 47 start-page: 929 year: 1992 end-page: 936 ident: CR28 article-title: High mass resolution plasma desorption and secondary ion mass-spectrometry of neutral nickel thiolate complexes- crystal-structure of Ni (SC H ) publication-title: Z. Naturforsch. B doi: 10.1515/znb-1992-0706 – volume: 3 start-page: 969 year: 1984 end-page: 975 ident: CR37 article-title: Metal complexes of mercaptoamines-III. Different behaviour of β- and γ-(N,N-dimethyl)-mercaptoamines publication-title: Polyhedron doi: 10.1016/S0277-5387(00)84654-9 – volume: 12 start-page: 397 year: 1993 ident: BFsrep16628_CR35 publication-title: Jiegou Huaxue (Chinese J. Struct. Chem.) – volume: 53 start-page: 2376 year: 2014 ident: BFsrep16628_CR5 publication-title: Angew. Chem. Int. Ed. doi: 10.1002/anie.201307480 – volume: 44 start-page: 606 year: 1988 ident: BFsrep16628_CR27 publication-title: Acta Crystallogr. C doi: 10.1107/S0108270187011892 – volume: 2 start-page: 329 year: 2010 ident: BFsrep16628_CR6 publication-title: Nature Chem. doi: 10.1038/nchem.589 – volume: 27 start-page: 585 year: 2001 ident: BFsrep16628_CR40 publication-title: Russ. J. Coord. Chem. doi: 10.1023/A:1011310013637 – volume: 126 start-page: 6193 year: 2004 ident: BFsrep16628_CR49 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja049605b – volume: 8 start-page: 2836 year: 1989 ident: BFsrep16628_CR26 publication-title: Organometallics doi: 10.1021/om00114a017 – volume: 21 start-page: 177 year: 2011 ident: BFsrep16628_CR21 publication-title: Adv. Funct. Mater. doi: 10.1002/adfm.201001120 – volume: 53 start-page: 3558 year: 2014 ident: BFsrep16628_CR45 publication-title: Inorg. Chem. doi: 10.1021/ic403050c – volume: 28 start-page: 61 year: 1989 ident: BFsrep16628_CR22 publication-title: Angew. Chem. Int. Ed. doi: 10.1002/anie.198900611 – volume: 45 start-page: 3768 year: 2006 ident: BFsrep16628_CR15 publication-title: Angew. Chem. Int. Ed. doi: 10.1002/anie.200600319 – volume: 26 start-page: 4565 year: 2014 ident: BFsrep16628_CR7 publication-title: Adv. Mater. doi: 10.1002/adma.201400866 – volume: 48 start-page: 929 year: 1994 ident: BFsrep16628_CR33 publication-title: Acta Chem. Scand. doi: 10.3891/acta.chem.scand.48-0929 – volume: 131 start-page: 13604 year: 2009 ident: BFsrep16628_CR46 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja906087a – volume: 109 start-page: 11647 year: 2005 ident: BFsrep16628_CR48 publication-title: J. Phys. Chem. A doi: 10.1021/jp055344w – volume: 145 start-page: 247 year: 1988 ident: BFsrep16628_CR20 publication-title: Inorg. Chim. Acta doi: 10.1016/S0020-1693(00)83966-3 – volume: 42 start-page: 5722 year: 2003 ident: BFsrep16628_CR31 publication-title: Angew. Chem. Int. Ed. doi: 10.1002/anie.200351896 – volume: 8 start-page: 1253 year: 1989 ident: BFsrep16628_CR32 publication-title: Polyhedron doi: 10.1016/S0277-5387(00)86522-5 – volume: 18 start-page: 3407 year: 1999 ident: BFsrep16628_CR36 publication-title: Polyhedron doi: 10.1016/S0277-5387(99)00245-4 – volume: 3 start-page: 3795 year: 2009 ident: BFsrep16628_CR47 publication-title: ACS Nano doi: 10.1021/nn901137h – volume: 52 start-page: 9094 year: 2013 ident: BFsrep16628_CR12 publication-title: Inorg. Chem. doi: 10.1021/ic4013069 – volume: 133 start-page: 20680 year: 2011 ident: BFsrep16628_CR13 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja208555h – volume: 7 start-page: 1397 year: 1988 ident: BFsrep16628_CR25 publication-title: Polyhedron doi: 10.1016/S0277-5387(00)80392-7 – volume: 5 start-page: 3785 year: 2014 ident: BFsrep16628_CR3 publication-title: Nature Commun. doi: 10.1038/ncomms4785 – ident: BFsrep16628_CR16 doi: 10.1039/B204273H – volume: 8 start-page: 2028 year: 2012 ident: BFsrep16628_CR9 publication-title: Small doi: 10.1002/smll.201102590 – volume: 47 start-page: 929 year: 1992 ident: BFsrep16628_CR28 publication-title: Z. Naturforsch. B doi: 10.1515/znb-1992-0706 – volume: 3 start-page: 969 year: 1984 ident: BFsrep16628_CR37 publication-title: Polyhedron doi: 10.1016/S0277-5387(00)84654-9 – volume: 44 start-page: 59 year: 2000 ident: BFsrep16628_CR50 publication-title: Nature doi: 10.1038/35003535 – volume: 24 start-page: 1201 year: 1985 ident: BFsrep16628_CR14 publication-title: Inorg. Chem. doi: 10.1021/ic00202a018 – volume: 41 start-page: 8472 year: 2012 ident: BFsrep16628_CR19 publication-title: Dalton Trans. doi: 10.1039/c2dt30524k – volume: 49 start-page: 2091 year: 1993 ident: BFsrep16628_CR44 publication-title: Acta Crystallogr. C doi: 10.1107/S0108270193005657 – volume: 11 start-page: 5578 year: 2009 ident: BFsrep16628_CR34 publication-title: Phys. Chem. Chem. Phys. doi: 10.1039/b904932k – volume: 134 start-page: 6637 year: 2012 ident: BFsrep16628_CR43 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja210596w – volume: 46 start-page: 2427 year: 2007 ident: BFsrep16628_CR18 publication-title: Inorg. Chem. doi: 10.1021/ic061242o – volume: 49 start-page: 4209 year: 2010 ident: BFsrep16628_CR11 publication-title: Angew. Chem. Int. Ed. doi: 10.1002/anie.200907074 – volume: 87 start-page: 5251 year: 1965 ident: BFsrep16628_CR17 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja00950a049 – volume: 6 start-page: 14195 year: 2014 ident: BFsrep16628_CR24 publication-title: Nanoscale doi: 10.1039/C4NR04981K – volume: 49 start-page: 770 year: 1994 ident: BFsrep16628_CR38 publication-title: Z. Naturforsch. B doi: 10.1515/znb-1994-0609 – volume: 42 start-page: 1121 year: 1987 ident: BFsrep16628_CR39 publication-title: Z. Naturforsch. B doi: 10.1515/znb-1987-0912 – volume: 24 start-page: 1623 year: 1968 ident: BFsrep16628_CR41 publication-title: Acta Crystallogr. B doi: 10.1107/S0567740868004759 – volume: 135 start-page: 8822 year: 2013 ident: BFsrep16628_CR8 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja403807f – volume: 35 start-page: 136 year: 2009 ident: BFsrep16628_CR42 publication-title: Russ. J. Coord. Chem. doi: 10.1134/S1070328409020080 – volume: 4 start-page: 443 year: 2012 ident: BFsrep16628_CR1 publication-title: Nature Chem. doi: 10.1038/nchem.1352 – volume: 23 start-page: 39 year: 1984 ident: BFsrep16628_CR23 publication-title: Inorg. Chem. doi: 10.1021/ic00169a010 – volume: 501 start-page: 399 year: 2013 ident: BFsrep16628_CR2 publication-title: Nature doi: 10.1038/nature12523 – ident: BFsrep16628_CR30 doi: 10.1039/J19700000875 – volume: 30 start-page: 846 year: 2009 ident: BFsrep16628_CR29 publication-title: Bull. Korean Chem. Soc. doi: 10.5012/bkcs.2009.30.4.846 – volume: 136 start-page: 6075 year: 2014 ident: BFsrep16628_CR10 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja5017365 – volume: 3 start-page: 798 year: 2012 ident: BFsrep16628_CR4 publication-title: Nature Commun. doi: 10.1038/ncomms1802 – reference: 24661117 - Inorg Chem. 2014 Apr 7;53(7):3558-67 – reference: 16366612 - J Phys Chem A. 2005 Dec 29;109(51):11647-9 – reference: 25350274 - Nanoscale. 2014 Nov 6;6(23):14195-9 – reference: 14661205 - Angew Chem Int Ed Engl. 2003 Dec 1;42(46):5722-4 – reference: 15137785 - J Am Chem Soc. 2004 May 19;126(19):6193-9 – reference: 20422664 - Angew Chem Int Ed Engl. 2010 Jun 7;49(25):4209-12 – reference: 22133284 - J Am Chem Soc. 2011 Dec 28;133(51):20680-3 – reference: 23718130 - J Am Chem Soc. 2013 Jun 19;135(24):8822-5 – reference: 10716439 - Nature. 2000 Mar 2;404(6773):59-61 – reference: 22475174 - J Am Chem Soc. 2012 Apr 18;134(15):6637-49 – reference: 16622894 - Angew Chem Int Ed Engl. 2006 Jun 2;45(23):3768-72 – reference: 19842474 - Phys Chem Chem Phys. 2009 Jul 21;11(27):5578-83 – reference: 24670058 - J Am Chem Soc. 2014 Apr 23;136(16):6075-82 – reference: 23865570 - Inorg Chem. 2013 Aug 5;52(15):9094-101 – reference: 24474712 - Angew Chem Int Ed Engl. 2014 Feb 24;53(9):2376-80 – reference: 22614378 - Nat Chem. 2012 Jun;4(6):443-55 – reference: 24817169 - Adv Mater. 2014 Jul 9;26(26):4565-8 – reference: 19860401 - ACS Nano. 2009 Nov 24;3(11):3795-803 – reference: 22488747 - Small. 2012 Jul 9;8(13):2028-35 – reference: 24005327 - Nature. 2013 Sep 19;501(7467):399-402 – reference: 22653469 - Dalton Trans. 2012 Jul 21;41(27):8472-6 – reference: 17335274 - Inorg Chem. 2007 Apr 2;46(7):2427-31 – reference: 21124516 - Nat Chem. 2010 Apr;2(4):329-34 – reference: 19725520 - J Am Chem Soc. 2009 Sep 30;131(38):13604-5 – reference: 24781134 - Nat Commun. 2014;5:3785 – reference: 7841020 - Acta Chem Scand. 1994 Nov;48(11):929-32 – reference: 22531183 - Nat Commun. 2012 Apr 24;3:798 |
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| Snippet | Tiara-like thiolated group 10 transition metal (Ni, Pd, Pt) nanoclusters have attracted extensive interest due to their fundamental scientific significance and... |
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| SubjectTerms | 119/118 140/146 639/638/263/914 639/925/357/354 Crystallography Electrochemistry Evolution Humanities and Social Sciences Laboratories Ligands Materials science multidisciplinary Palladium Physics Science Single crystals Sulfur X-ray crystallography |
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| Title | Synthesis and Properties Evolution of a Family of Tiara-like Phenylethanethiolated Palladium Nanoclusters |
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