Designation of highly efficient catalysts for one pot conversion of glycerol to lactic acid

Production of lactic acid from glycerol is a cascade catalytic procedure using multifunctional catalysts combined with oxidative and acidic catalytic sites. Therefore, a series of silver-exchanged phosphomolybdic acid catalysts (Ag x H 3−x PMo 12 O 40 , x = 1 ~ 3, abbreviated as Ag x PMo) was design...

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Published inScientific reports Vol. 6; no. 1; p. 29840
Main Authors Tao, Meilin, Dan Zhang, Guan, Hongyu, Huang, Guohui, Wang, Xiaohong
Format Journal Article
LanguageEnglish
Published London Nature Publishing Group UK 19.07.2016
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Abstract Production of lactic acid from glycerol is a cascade catalytic procedure using multifunctional catalysts combined with oxidative and acidic catalytic sites. Therefore, a series of silver-exchanged phosphomolybdic acid catalysts (Ag x H 3−x PMo 12 O 40 , x = 1 ~ 3, abbreviated as Ag x PMo) was designed and applied in glycerol oxidation with O 2 as an oxidant to produce lactic acid (LA) without adding any base. Among all, total silver exchanged phosphomolybdic acid (Ag 3 PMo) was found to be the most active one with LA selectivity of 93% at 99% conversion under mild conditions of 5 h at 60 °C. The exceptionally high efficiency was contributed to the generation of strong Lewis acid sites, enhanced redox potentials and water-tolerance. More importantly, Ag 3 PMo was tolerant in crude glycerol from biodiesel production. And the reaction mechanism was also discussed. Meanwhile, Ag 3 PMo acted as a heterogeneous catalyst for 12 recycles without loss of activity.
AbstractList Production of lactic acid from glycerol is a cascade catalytic procedure using multifunctional catalysts combined with oxidative and acidic catalytic sites. Therefore, a series of silver-exchanged phosphomolybdic acid catalysts (Ag x H 3−x PMo 12 O 40 , x = 1 ~ 3, abbreviated as Ag x PMo) was designed and applied in glycerol oxidation with O 2 as an oxidant to produce lactic acid (LA) without adding any base. Among all, total silver exchanged phosphomolybdic acid (Ag 3 PMo) was found to be the most active one with LA selectivity of 93% at 99% conversion under mild conditions of 5 h at 60 °C. The exceptionally high efficiency was contributed to the generation of strong Lewis acid sites, enhanced redox potentials and water-tolerance. More importantly, Ag 3 PMo was tolerant in crude glycerol from biodiesel production. And the reaction mechanism was also discussed. Meanwhile, Ag 3 PMo acted as a heterogeneous catalyst for 12 recycles without loss of activity.
Production of lactic acid from glycerol is a cascade catalytic procedure using multifunctional catalysts combined with oxidative and acidic catalytic sites. Therefore, a series of silver-exchanged phosphomolybdic acid catalysts (Agx H3-x PMo12 O40 , x = 1 ~ 3, abbreviated as Agx PMo) was designed and applied in glycerol oxidation with O2 as an oxidant to produce lactic acid (LA) without adding any base. Among all, total silver exchanged phosphomolybdic acid (Ag3 PMo) was found to be the most active one with LA selectivity of 93% at 99% conversion under mild conditions of 5 h at 60 °C. The exceptionally high efficiency was contributed to the generation of strong Lewis acid sites, enhanced redox potentials and water-tolerance. More importantly, Ag3 PMo was tolerant in crude glycerol from biodiesel production. And the reaction mechanism was also discussed. Meanwhile, Ag3 PMo acted as a heterogeneous catalyst for 12 recycles without loss of activity.
Production of lactic acid from glycerol is a cascade catalytic procedure using multifunctional catalysts combined with oxidative and acidic catalytic sites. Therefore, a series of silver-exchanged phosphomolybdic acid catalysts (AgxH3-xPMo12O40, x = 1 ~ 3, abbreviated as AgxPMo) was designed and applied in glycerol oxidation with O2 as an oxidant to produce lactic acid (LA) without adding any base. Among all, total silver exchanged phosphomolybdic acid (Ag3PMo) was found to be the most active one with LA selectivity of 93% at 99% conversion under mild conditions of 5 h at 60 °C. The exceptionally high efficiency was contributed to the generation of strong Lewis acid sites, enhanced redox potentials and water-tolerance. More importantly, Ag3PMo was tolerant in crude glycerol from biodiesel production. And the reaction mechanism was also discussed. Meanwhile, Ag3PMo acted as a heterogeneous catalyst for 12 recycles without loss of activity.
ArticleNumber 29840
Author Dan Zhang
Wang, Xiaohong
Tao, Meilin
Huang, Guohui
Guan, Hongyu
Author_xml – sequence: 1
  givenname: Meilin
  surname: Tao
  fullname: Tao, Meilin
  organization: Key Lab of Polyoxometalate Science of Ministry of Education, Northeast Normal University
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  surname: Dan Zhang
  fullname: Dan Zhang
  organization: Key Lab of Polyoxometalate Science of Ministry of Education, Northeast Normal University
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  givenname: Hongyu
  surname: Guan
  fullname: Guan, Hongyu
  organization: Key Lab of Polyoxometalate Science of Ministry of Education, Northeast Normal University
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  givenname: Guohui
  surname: Huang
  fullname: Huang, Guohui
  email: huanggh699@nenu.edu.cn
  organization: School of Biology, Northeast Normal University
– sequence: 5
  givenname: Xiaohong
  surname: Wang
  fullname: Wang, Xiaohong
  email: wangxh665@nenu.edu.cn
  organization: Key Lab of Polyoxometalate Science of Ministry of Education, Northeast Normal University
BackLink https://www.ncbi.nlm.nih.gov/pubmed/27431610$$D View this record in MEDLINE/PubMed
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Snippet Production of lactic acid from glycerol is a cascade catalytic procedure using multifunctional catalysts combined with oxidative and acidic catalytic sites....
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SubjectTerms 140/146
142/136
704/106
704/158
Acid production
Acids
Catalysis
Glycerol
Humanities and Social Sciences
Metals
multidisciplinary
Oxidation
Oxidizing agents
Raw materials
Science
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Title Designation of highly efficient catalysts for one pot conversion of glycerol to lactic acid
URI https://link.springer.com/article/10.1038/srep29840
https://www.ncbi.nlm.nih.gov/pubmed/27431610
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https://pubmed.ncbi.nlm.nih.gov/PMC4949431
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