Designation of highly efficient catalysts for one pot conversion of glycerol to lactic acid
Production of lactic acid from glycerol is a cascade catalytic procedure using multifunctional catalysts combined with oxidative and acidic catalytic sites. Therefore, a series of silver-exchanged phosphomolybdic acid catalysts (Ag x H 3−x PMo 12 O 40 , x = 1 ~ 3, abbreviated as Ag x PMo) was design...
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Published in | Scientific reports Vol. 6; no. 1; p. 29840 |
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Main Authors | , , , , |
Format | Journal Article |
Language | English |
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19.07.2016
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Abstract | Production of lactic acid from glycerol is a cascade catalytic procedure using multifunctional catalysts combined with oxidative and acidic catalytic sites. Therefore, a series of silver-exchanged phosphomolybdic acid catalysts (Ag
x
H
3−x
PMo
12
O
40
, x = 1 ~ 3, abbreviated as Ag
x
PMo) was designed and applied in glycerol oxidation with O
2
as an oxidant to produce lactic acid (LA) without adding any base. Among all, total silver exchanged phosphomolybdic acid (Ag
3
PMo) was found to be the most active one with LA selectivity of 93% at 99% conversion under mild conditions of 5 h at 60 °C. The exceptionally high efficiency was contributed to the generation of strong Lewis acid sites, enhanced redox potentials and water-tolerance. More importantly, Ag
3
PMo was tolerant in crude glycerol from biodiesel production. And the reaction mechanism was also discussed. Meanwhile, Ag
3
PMo acted as a heterogeneous catalyst for 12 recycles without loss of activity. |
---|---|
AbstractList | Production of lactic acid from glycerol is a cascade catalytic procedure using multifunctional catalysts combined with oxidative and acidic catalytic sites. Therefore, a series of silver-exchanged phosphomolybdic acid catalysts (Ag
x
H
3−x
PMo
12
O
40
, x = 1 ~ 3, abbreviated as Ag
x
PMo) was designed and applied in glycerol oxidation with O
2
as an oxidant to produce lactic acid (LA) without adding any base. Among all, total silver exchanged phosphomolybdic acid (Ag
3
PMo) was found to be the most active one with LA selectivity of 93% at 99% conversion under mild conditions of 5 h at 60 °C. The exceptionally high efficiency was contributed to the generation of strong Lewis acid sites, enhanced redox potentials and water-tolerance. More importantly, Ag
3
PMo was tolerant in crude glycerol from biodiesel production. And the reaction mechanism was also discussed. Meanwhile, Ag
3
PMo acted as a heterogeneous catalyst for 12 recycles without loss of activity. Production of lactic acid from glycerol is a cascade catalytic procedure using multifunctional catalysts combined with oxidative and acidic catalytic sites. Therefore, a series of silver-exchanged phosphomolybdic acid catalysts (Agx H3-x PMo12 O40 , x = 1 ~ 3, abbreviated as Agx PMo) was designed and applied in glycerol oxidation with O2 as an oxidant to produce lactic acid (LA) without adding any base. Among all, total silver exchanged phosphomolybdic acid (Ag3 PMo) was found to be the most active one with LA selectivity of 93% at 99% conversion under mild conditions of 5 h at 60 °C. The exceptionally high efficiency was contributed to the generation of strong Lewis acid sites, enhanced redox potentials and water-tolerance. More importantly, Ag3 PMo was tolerant in crude glycerol from biodiesel production. And the reaction mechanism was also discussed. Meanwhile, Ag3 PMo acted as a heterogeneous catalyst for 12 recycles without loss of activity. Production of lactic acid from glycerol is a cascade catalytic procedure using multifunctional catalysts combined with oxidative and acidic catalytic sites. Therefore, a series of silver-exchanged phosphomolybdic acid catalysts (AgxH3-xPMo12O40, x = 1 ~ 3, abbreviated as AgxPMo) was designed and applied in glycerol oxidation with O2 as an oxidant to produce lactic acid (LA) without adding any base. Among all, total silver exchanged phosphomolybdic acid (Ag3PMo) was found to be the most active one with LA selectivity of 93% at 99% conversion under mild conditions of 5 h at 60 °C. The exceptionally high efficiency was contributed to the generation of strong Lewis acid sites, enhanced redox potentials and water-tolerance. More importantly, Ag3PMo was tolerant in crude glycerol from biodiesel production. And the reaction mechanism was also discussed. Meanwhile, Ag3PMo acted as a heterogeneous catalyst for 12 recycles without loss of activity. |
ArticleNumber | 29840 |
Author | Dan Zhang Wang, Xiaohong Tao, Meilin Huang, Guohui Guan, Hongyu |
Author_xml | – sequence: 1 givenname: Meilin surname: Tao fullname: Tao, Meilin organization: Key Lab of Polyoxometalate Science of Ministry of Education, Northeast Normal University – sequence: 2 surname: Dan Zhang fullname: Dan Zhang organization: Key Lab of Polyoxometalate Science of Ministry of Education, Northeast Normal University – sequence: 3 givenname: Hongyu surname: Guan fullname: Guan, Hongyu organization: Key Lab of Polyoxometalate Science of Ministry of Education, Northeast Normal University – sequence: 4 givenname: Guohui surname: Huang fullname: Huang, Guohui email: huanggh699@nenu.edu.cn organization: School of Biology, Northeast Normal University – sequence: 5 givenname: Xiaohong surname: Wang fullname: Wang, Xiaohong email: wangxh665@nenu.edu.cn organization: Key Lab of Polyoxometalate Science of Ministry of Education, Northeast Normal University |
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SubjectTerms | 140/146 142/136 704/106 704/158 Acid production Acids Catalysis Glycerol Humanities and Social Sciences Metals multidisciplinary Oxidation Oxidizing agents Raw materials Science |
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Title | Designation of highly efficient catalysts for one pot conversion of glycerol to lactic acid |
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