A new surface structural approach to ion adsorption: Tracing the location of electrolyte ions

• Published in: Journal of colloid and interface science Vol. 293; no. 2; pp. 312 - 321
• Main Authors: Rahnemaie, Rasoul, Hiemstra, Tjisse, van Riemsdijk, Willem H.
• Format: Journal Article
• Language: English
• Published: San Diego, CA Elsevier Inc 15.01.2006; Elsevier
• Subjects: Adsorption; Basic Stern; CD model; Chemistry; complexation models; Diffuse double layer; electrical double-layer; Electrolyte ion; Exact sciences and technology; General and physical chemistry; Goethite; goethite alpha-feooh; Iron oxide; metal (hydr)oxides; molecular statics calculations; MUSIC model; oxide-water interface; primary charging behavior; proton binding; solid-solution interface; Surface physical chemistry; synthetic goethite; Three plane model; Basic Stern; Iron oxide; Adsorption; Diffuse double layer; Three plane model; MUSIC model; Goethite; Electrolyte ion; CD model; Iron oxide: Goethite; Transition element compounds; Ions; Electrolyte; Models; Tracing

Electrolyte ions differ in size leading to the possibility that the distance of closest approach to a charged surface differs for different ions. So far, ions bound as outersphere complexes have been treated as point charges present at one or two electrostatic plane(s). However, in a multicomponent...