Neighboring Pd single atoms surpass isolated single atoms for selective hydrodehalogenation catalysis
Abstract Single atom catalysts have been found to exhibit superior selectivity over nanoparticulate catalysts for catalytic reactions such as hydrogenation due to their single-site nature. However, improved selectively is often accompanied by loss of activity and slow kinetics. Here we demonstrate t...
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Published in | Nature communications Vol. 12; no. 1; p. 5179 |
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Main Authors | , , , , , , , |
Format | Journal Article |
Language | English |
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30.08.2021
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Abstract | Abstract
Single atom catalysts have been found to exhibit superior selectivity over nanoparticulate catalysts for catalytic reactions such as hydrogenation due to their single-site nature. However, improved selectively is often accompanied by loss of activity and slow kinetics. Here we demonstrate that neighboring Pd single atom catalysts retain the high selectivity merit of sparsely isolated single atom catalysts, while the cooperative interactions between neighboring atoms greatly enhance the activity for hydrogenation of carbon-halogen bonds. Experimental results and computational calculations suggest that neighboring Pd atoms work in synergy to lower the energy of key meta-stable reactions steps, i.e., initial water desorption and final hydrogenated product desorption. The placement of neighboring Pd atoms also contribute to nearly exclusive hydrogenation of carbon-chlorine bond without altering any other bonds in organohalogens. The promising hydrogenation performance achieved by neighboring single atoms sheds light on a new approach for manipulating the activity and selectivity of single atom catalysts that are increasingly studied in multiple applications. |
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AbstractList | Single atom catalysts have been found to exhibit superior selectivity over nanoparticulate catalysts for catalytic reactions such as hydrogenation due to their single-site nature. However, improved selectively is often accompanied by loss of activity and slow kinetics. Here we demonstrate that neighboring Pd single atom catalysts retain the high selectivity merit of sparsely isolated single atom catalysts, while the cooperative interactions between neighboring atoms greatly enhance the activity for hydrogenation of carbon-halogen bonds. Experimental results and computational calculations suggest that neighboring Pd atoms work in synergy to lower the energy of key meta-stable reactions steps, i.e., initial water desorption and final hydrogenated product desorption. The placement of neighboring Pd atoms also contribute to nearly exclusive hydrogenation of carbon-chlorine bond without altering any other bonds in organohalogens. The promising hydrogenation performance achieved by neighboring single atoms sheds light on a new approach for manipulating the activity and selectivity of single atom catalysts that are increasingly studied in multiple applications. Single atom catalysts have been found to exhibit superior selectivity over nanoparticulate catalysts for catalytic reactions such as hydrogenation due to their single-site nature. However, improved selectively is often accompanied by loss of activity and slow kinetics. Here we demonstrate that neighboring Pd single atom catalysts retain the high selectivity merit of sparsely isolated single atom catalysts, while the cooperative interactions between neighboring atoms greatly enhance the activity for hydrogenation of carbon-halogen bonds. Experimental results and computational calculations suggest that neighboring Pd atoms work in synergy to lower the energy of key meta-stable reactions steps, i.e., initial water desorption and final hydrogenated product desorption. The placement of neighboring Pd atoms also contribute to nearly exclusive hydrogenation of carbon-chlorine bond without altering any other bonds in organohalogens. The promising hydrogenation performance achieved by neighboring single atoms sheds light on a new approach for manipulating the activity and selectivity of single atom catalysts that are increasingly studied in multiple applications.Single atom catalysts have exhibited high selectivity for hydrogenation, yet improved selectively is often accompanied by loss of activity. Here the authors report that synergistic interactions of neighboring Pd single atoms lead to both high activity and selectivity for hydrodehalogenation catalysis. Abstract Single atom catalysts have been found to exhibit superior selectivity over nanoparticulate catalysts for catalytic reactions such as hydrogenation due to their single-site nature. However, improved selectively is often accompanied by loss of activity and slow kinetics. Here we demonstrate that neighboring Pd single atom catalysts retain the high selectivity merit of sparsely isolated single atom catalysts, while the cooperative interactions between neighboring atoms greatly enhance the activity for hydrogenation of carbon-halogen bonds. Experimental results and computational calculations suggest that neighboring Pd atoms work in synergy to lower the energy of key meta-stable reactions steps, i.e., initial water desorption and final hydrogenated product desorption. The placement of neighboring Pd atoms also contribute to nearly exclusive hydrogenation of carbon-chlorine bond without altering any other bonds in organohalogens. The promising hydrogenation performance achieved by neighboring single atoms sheds light on a new approach for manipulating the activity and selectivity of single atom catalysts that are increasingly studied in multiple applications. Single atom catalysts have been found to exhibit superior selectivity over nanoparticulate catalysts for catalytic reactions such as hydrogenation due to their single-site nature. However, improved selectively is often accompanied by loss of activity and slow kinetics. Here we demonstrate that neighboring Pd single atom catalysts retain the high selectivity merit of sparsely isolated single atom catalysts, while the cooperative interactions between neighboring atoms greatly enhance the activity for hydrogenation of carbon-halogen bonds. Experimental results and computational calculations suggest that neighboring Pd atoms work in synergy to lower the energy of key meta-stable reactions steps, i.e., initial water desorption and final hydrogenated product desorption. The placement of neighboring Pd atoms also contribute to nearly exclusive hydrogenation of carbon-chlorine bond without altering any other bonds in organohalogens. The promising hydrogenation performance achieved by neighboring single atoms sheds light on a new approach for manipulating the activity and selectivity of single atom catalysts that are increasingly studied in multiple applications. Single atom catalysts have exhibited high selectivity for hydrogenation, yet improved selectively is often accompanied by loss of activity. Here the authors report that synergistic interactions of neighboring Pd single atoms lead to both high activity and selectivity for hydrodehalogenation catalysis. Single atom catalysts have exhibited high selectivity for hydrogenation, yet improved selectively is often accompanied by loss of activity. Here the authors report that synergistic interactions of neighboring Pd single atoms lead to both high activity and selectivity for hydrodehalogenation catalysis. |
ArticleNumber | 5179 |
Author | Weon, Seunghyun Muhich, Christopher Stavitski, Eli Chu, Chiheng Gupta, Srishti Niu, Junfeng Kim, Jae-Hong Huang, Dahong |
Author_xml | – sequence: 1 givenname: Chiheng surname: Chu fullname: Chu, Chiheng – sequence: 2 givenname: Dahong surname: Huang fullname: Huang, Dahong – sequence: 3 givenname: Srishti orcidid: 0000-0002-5860-9658 surname: Gupta fullname: Gupta, Srishti – sequence: 4 givenname: Seunghyun orcidid: 0000-0003-4529-8069 surname: Weon fullname: Weon, Seunghyun – sequence: 5 givenname: Junfeng orcidid: 0000-0003-2592-3103 surname: Niu fullname: Niu, Junfeng – sequence: 6 givenname: Eli surname: Stavitski fullname: Stavitski, Eli – sequence: 7 givenname: Christopher orcidid: 0000-0003-3089-559X surname: Muhich fullname: Muhich, Christopher – sequence: 8 givenname: Jae-Hong orcidid: 0000-0003-2224-3516 surname: Kim fullname: Kim, Jae-Hong |
BackLink | https://www.osti.gov/servlets/purl/1825733$$D View this record in Osti.gov |
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Cites_doi | 10.1021/jacs.8b07476 10.1016/j.apcatb.2010.02.028 10.1021/acscatal.8b03738 10.1021/acs.nanolett.8b02606 10.1002/anie.201505073 10.1038/s41570-018-0010-1 10.1103/PhysRevB.59.1758 10.1021/jacs.5b06485 10.1103/PhysRevLett.77.3865 10.1021/acscatal.8b02660 10.1063/1.4865107 10.1103/PhysRevLett.93.116101 10.1038/s41565-019-0366-5 10.1021/cr60291a003 10.1063/1.5132354 10.1016/j.jcat.2018.07.033 10.1021/cr0102967 10.1063/1.3382344 10.1103/PhysRevB.54.11169 10.1126/science.1215864 10.1021/acs.analchem.7b04577 10.1016/0927-0256(96)00008-0 10.1021/cr00066a003 10.1016/S0039-6028(98)00363-X 10.1126/science.aaf5251 10.1103/PhysRevLett.77.5090 10.1021/ar300361m 10.1021/jacs.9b02132 10.1021/jp973430t 10.1016/j.ssc.2007.07.012 10.1021/acs.chemrev.9b00230 |
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References | L Zhang (25526_CR3) 2019; 120 G Kyriakou (25526_CR8) 2012; 335 A Catellani (25526_CR27) 1996; 77 YN Wen (25526_CR29) 2007; 144 D Huang (25526_CR15) 2018; 8 L Lin (25526_CR9) 2019; 14 G Brieger (25526_CR18) 1974; 74 H Yan (25526_CR6) 2018; 366 M Jorgensen (25526_CR11) 2019; 141 25526_CR17 W Vogel (25526_CR16) 1998; 102 JP Perdew (25526_CR24) 1996; 77 F Huang (25526_CR4) 2018; 140 SD Richardson (25526_CR14) 2018; 90 G Vile (25526_CR5) 2015; 54 J Cerda (25526_CR20) 2004; 93 XF Yang (25526_CR2) 2013; 46 S Grimme (25526_CR25) 2010; 132 K Mathew (25526_CR31) 2014; 140 F Alonso (25526_CR13) 2002; 102 G Kresse (25526_CR22) 1996; 54 PX Liu (25526_CR10) 2016; 352 G Kresse (25526_CR26) 1999; 59 H Yan (25526_CR7) 2015; 137 K Mathew (25526_CR30) 2019; 151 RAW Johnstone (25526_CR19) 1985; 85 A Wang (25526_CR1) 2018; 2 L Vitos (25526_CR28) 1998; 411 G Kresse (25526_CR23) 1996; 6 F-D Kopinke (25526_CR21) 2010; 96 W Chen (25526_CR12) 2018; 18 |
References_xml | – volume: 140 start-page: 13142 year: 2018 ident: 25526_CR4 publication-title: J. Am. Chem. Soc. doi: 10.1021/jacs.8b07476 contributor: fullname: F Huang – volume: 96 start-page: 323 year: 2010 ident: 25526_CR21 publication-title: Appl. Catal. B Environ. doi: 10.1016/j.apcatb.2010.02.028 contributor: fullname: F-D Kopinke – ident: 25526_CR17 doi: 10.1021/acscatal.8b03738 – volume: 18 start-page: 5905 year: 2018 ident: 25526_CR12 publication-title: Nano Lett. doi: 10.1021/acs.nanolett.8b02606 contributor: fullname: W Chen – volume: 54 start-page: 11265 year: 2015 ident: 25526_CR5 publication-title: Angew. Chem. Int. Ed. doi: 10.1002/anie.201505073 contributor: fullname: G Vile – volume: 2 start-page: 65 year: 2018 ident: 25526_CR1 publication-title: Nat. Rev. Chem. doi: 10.1038/s41570-018-0010-1 contributor: fullname: A Wang – volume: 59 start-page: 1758 year: 1999 ident: 25526_CR26 publication-title: Phys. Rev. B doi: 10.1103/PhysRevB.59.1758 contributor: fullname: G Kresse – volume: 137 start-page: 10484 year: 2015 ident: 25526_CR7 publication-title: J. Am. Chem. Soc. doi: 10.1021/jacs.5b06485 contributor: fullname: H Yan – volume: 77 start-page: 3865 year: 1996 ident: 25526_CR24 publication-title: Phys. Rev. Lett. doi: 10.1103/PhysRevLett.77.3865 contributor: fullname: JP Perdew – volume: 8 start-page: 9353 year: 2018 ident: 25526_CR15 publication-title: ACS Catal. doi: 10.1021/acscatal.8b02660 contributor: fullname: D Huang – volume: 140 start-page: 084106 year: 2014 ident: 25526_CR31 publication-title: J. Chem. Phys. doi: 10.1063/1.4865107 contributor: fullname: K Mathew – volume: 93 start-page: 116101 year: 2004 ident: 25526_CR20 publication-title: Phys. Rev. Lett. doi: 10.1103/PhysRevLett.93.116101 contributor: fullname: J Cerda – volume: 14 start-page: 354 year: 2019 ident: 25526_CR9 publication-title: Nat. Nanotechnol. doi: 10.1038/s41565-019-0366-5 contributor: fullname: L Lin – volume: 74 start-page: 567 year: 1974 ident: 25526_CR18 publication-title: Chem. Rev. doi: 10.1021/cr60291a003 contributor: fullname: G Brieger – volume: 151 start-page: 234101 year: 2019 ident: 25526_CR30 publication-title: J. Chem. Phys. doi: 10.1063/1.5132354 contributor: fullname: K Mathew – volume: 366 start-page: 70 year: 2018 ident: 25526_CR6 publication-title: J. Catal. doi: 10.1016/j.jcat.2018.07.033 contributor: fullname: H Yan – volume: 102 start-page: 4009 year: 2002 ident: 25526_CR13 publication-title: Chem. Rev. doi: 10.1021/cr0102967 contributor: fullname: F Alonso – volume: 132 start-page: 154104 year: 2010 ident: 25526_CR25 publication-title: J. Chem. Phys. doi: 10.1063/1.3382344 contributor: fullname: S Grimme – volume: 54 start-page: 11169 year: 1996 ident: 25526_CR22 publication-title: Phys. Rev. B doi: 10.1103/PhysRevB.54.11169 contributor: fullname: G Kresse – volume: 335 start-page: 1209 year: 2012 ident: 25526_CR8 publication-title: Science doi: 10.1126/science.1215864 contributor: fullname: G Kyriakou – volume: 90 start-page: 398 year: 2018 ident: 25526_CR14 publication-title: Anal. Chem. doi: 10.1021/acs.analchem.7b04577 contributor: fullname: SD Richardson – volume: 6 start-page: 15 year: 1996 ident: 25526_CR23 publication-title: Comp. Mater. Sci. doi: 10.1016/0927-0256(96)00008-0 contributor: fullname: G Kresse – volume: 85 start-page: 129 year: 1985 ident: 25526_CR19 publication-title: Chem. Rev. doi: 10.1021/cr00066a003 contributor: fullname: RAW Johnstone – volume: 411 start-page: 186 year: 1998 ident: 25526_CR28 publication-title: Surf. Sci. doi: 10.1016/S0039-6028(98)00363-X contributor: fullname: L Vitos – volume: 352 start-page: 797 year: 2016 ident: 25526_CR10 publication-title: Science doi: 10.1126/science.aaf5251 contributor: fullname: PX Liu – volume: 77 start-page: 5090 year: 1996 ident: 25526_CR27 publication-title: Phys. Rev. Lett. doi: 10.1103/PhysRevLett.77.5090 contributor: fullname: A Catellani – volume: 46 start-page: 1740 year: 2013 ident: 25526_CR2 publication-title: Acc. Chem. Res. doi: 10.1021/ar300361m contributor: fullname: XF Yang – volume: 141 start-page: 8541 year: 2019 ident: 25526_CR11 publication-title: J. Am. Chem. Soc. doi: 10.1021/jacs.9b02132 contributor: fullname: M Jorgensen – volume: 102 start-page: 1750 year: 1998 ident: 25526_CR16 publication-title: J. Phys. Chem. B. doi: 10.1021/jp973430t contributor: fullname: W Vogel – volume: 144 start-page: 163 year: 2007 ident: 25526_CR29 publication-title: Solid State Commun. doi: 10.1016/j.ssc.2007.07.012 contributor: fullname: YN Wen – volume: 120 start-page: 683 year: 2019 ident: 25526_CR3 publication-title: Chem. Rev. doi: 10.1021/acs.chemrev.9b00230 contributor: fullname: L Zhang |
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Snippet | Abstract
Single atom catalysts have been found to exhibit superior selectivity over nanoparticulate catalysts for catalytic reactions such as hydrogenation due... Single atom catalysts have been found to exhibit superior selectivity over nanoparticulate catalysts for catalytic reactions such as hydrogenation due to their... Single atom catalysts have exhibited high selectivity for hydrogenation, yet improved selectively is often accompanied by loss of activity. Here the authors... |
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SubjectTerms | Carbon Catalysis Catalyst synthesis Catalysts Chlorine Computer applications Desorption Heterogeneous catalysis Hydrogenation MATERIALS SCIENCE Nanoparticles Organohalogen compounds Palladium Pollution remediation Selectivity Single atom catalysts |
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Title | Neighboring Pd single atoms surpass isolated single atoms for selective hydrodehalogenation catalysis |
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