High-Performance Epoxy Nanocomposites Reinforced with Three-Dimensional Carbon Nanotube Sponge for Electromagnetic Interference Shielding
Light‐weight and high‐performance electromagnetic interference (EMI)‐shielding epoxy nanocomposites are prepared by an infiltration method using a 3D carbon nanotube (CNT) sponge as the 3D reinforcement and conducting framework. The preformed, highly porous, and electrically conducting framework act...
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| Published in | Advanced functional materials Vol. 26; no. 3; pp. 447 - 455 |
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| Main Authors | , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Blackwell Publishing Ltd
20.01.2016
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| Subjects | |
| Online Access | Get full text |
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| Abstract | Light‐weight and high‐performance electromagnetic interference (EMI)‐shielding epoxy nanocomposites are prepared by an infiltration method using a 3D carbon nanotube (CNT) sponge as the 3D reinforcement and conducting framework. The preformed, highly porous, and electrically conducting framework acts as a highway for electron transport and can resist a high external loading to protect the epoxy nanocomposite. Consequently, a remarkable conductivity of 148 S m−1 and an outstanding EMI shielding effectiveness of around 33 dB in the X‐band are achieved for the epoxy nanocomposite with 0.66 wt% of CNT sponge, which is higher than that achieved for epoxy nanocomposites with 20 wt% of conventional CNTs. More importantly, the CNT sponge provides a dual advantage over conventional CNTs in its prominent reinforcement and toughening of the epoxy composite. Only 0.66 wt% of CNT sponge significantly increases the flexural and tensile strengths by 102% and 64%, respectively, as compared to those of neat epoxy. Moreover, the nanocomposite shows a 250% increase in tensile toughness and a 97% increase in elongation at break. These results indicate that CNT sponge is an ideal functional component for mechanically strong and high‐performance EMI‐shielding nanocomposites.
High‐performance electromagnetic interference shielding epoxy nanocomposites are prepared using a preformed highly porous and electrically conductive CNT sponge. The CNT sponge acts as the three‐dimensional conducting framework and as effective reinforcement. Only 0.66 wt% of CNT sponge leads to an outstanding EMI shielding effectiveness of around 33 dB in the X‐band, and vast increments in the flexural strength and tensile toughness are achieved. |
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| AbstractList | Light‐weight and high‐performance electromagnetic interference (EMI)‐shielding epoxy nanocomposites are prepared by an infiltration method using a 3D carbon nanotube (CNT) sponge as the 3D reinforcement and conducting framework. The preformed, highly porous, and electrically conducting framework acts as a highway for electron transport and can resist a high external loading to protect the epoxy nanocomposite. Consequently, a remarkable conductivity of 148 S m
−1
and an outstanding EMI shielding effectiveness of around 33 dB in the X‐band are achieved for the epoxy nanocomposite with 0.66 wt% of CNT sponge, which is higher than that achieved for epoxy nanocomposites with 20 wt% of conventional CNTs. More importantly, the CNT sponge provides a dual advantage over conventional CNTs in its prominent reinforcement and toughening of the epoxy composite. Only 0.66 wt% of CNT sponge significantly increases the flexural and tensile strengths by 102% and 64%, respectively, as compared to those of neat epoxy. Moreover, the nanocomposite shows a 250% increase in tensile toughness and a 97% increase in elongation at break. These results indicate that CNT sponge is an ideal functional component for mechanically strong and high‐performance EMI‐shielding nanocomposites. Light-weight and high-performance electromagnetic interference (EMI)-shielding epoxy nanocomposites are prepared by an infiltration method using a 3D carbon nanotube (CNT) sponge as the 3D reinforcement and conducting framework. The preformed, highly porous, and electrically conducting framework acts as a highway for electron transport and can resist a high external loading to protect the epoxy nanocomposite. Consequently, a remarkable conductivity of 148 S m super(-1) and an outstanding EMI shielding effectiveness of around 33 dB in the X-band are achieved for the epoxy nanocomposite with 0.66 wt% of CNT sponge, which is higher than that achieved for epoxy nanocomposites with 20 wt% of conventional CNTs. More importantly, the CNT sponge provides a dual advantage over conventional CNTs in its prominent reinforcement and toughening of the epoxy composite. Only 0.66 wt% of CNT sponge significantly increases the flexural and tensile strengths by 102% and 64%, respectively, as compared to those of neat epoxy. Moreover, the nanocomposite shows a 250% increase in tensile toughness and a 97% increase in elongation at break. These results indicate that CNT sponge is an ideal functional component for mechanically strong and high-performance EMI-shielding nanocomposites. High-performance electromagnetic interference shielding epoxy nanocomposites are prepared using a preformed highly porous and electrically conductive CNT sponge. The CNT sponge acts as the three-dimensional conducting framework and as effective reinforcement. Only 0.66 wt% of CNT sponge leads to an outstanding EMI shielding effectiveness of around 33 dB in the X-band, and vast increments in the flexural strength and tensile toughness are achieved. Light‐weight and high‐performance electromagnetic interference (EMI)‐shielding epoxy nanocomposites are prepared by an infiltration method using a 3D carbon nanotube (CNT) sponge as the 3D reinforcement and conducting framework. The preformed, highly porous, and electrically conducting framework acts as a highway for electron transport and can resist a high external loading to protect the epoxy nanocomposite. Consequently, a remarkable conductivity of 148 S m−1 and an outstanding EMI shielding effectiveness of around 33 dB in the X‐band are achieved for the epoxy nanocomposite with 0.66 wt% of CNT sponge, which is higher than that achieved for epoxy nanocomposites with 20 wt% of conventional CNTs. More importantly, the CNT sponge provides a dual advantage over conventional CNTs in its prominent reinforcement and toughening of the epoxy composite. Only 0.66 wt% of CNT sponge significantly increases the flexural and tensile strengths by 102% and 64%, respectively, as compared to those of neat epoxy. Moreover, the nanocomposite shows a 250% increase in tensile toughness and a 97% increase in elongation at break. These results indicate that CNT sponge is an ideal functional component for mechanically strong and high‐performance EMI‐shielding nanocomposites. High‐performance electromagnetic interference shielding epoxy nanocomposites are prepared using a preformed highly porous and electrically conductive CNT sponge. The CNT sponge acts as the three‐dimensional conducting framework and as effective reinforcement. Only 0.66 wt% of CNT sponge leads to an outstanding EMI shielding effectiveness of around 33 dB in the X‐band, and vast increments in the flexural strength and tensile toughness are achieved. |
| Author | Wang, Mu Yu, Zhong-Zhen Yang, Yanbing Chen, Yu Cao, Anyuan Zhang, Hao-Bin |
| Author_xml | – sequence: 1 givenname: Yu surname: Chen fullname: Chen, Yu organization: State Key Laboratory of Organic-Inorganic Composites, College of Materials Science and Engineering, Beijing University of Chemical Technology, 100029, Beijing, P. R. China – sequence: 2 givenname: Hao-Bin surname: Zhang fullname: Zhang, Hao-Bin email: zhanghaobin@mail.buct.edu.cn organization: State Key Laboratory of Organic-Inorganic Composites, College of Materials Science and Engineering, Beijing University of Chemical Technology, 100029, Beijing, P. R. China – sequence: 3 givenname: Yanbing surname: Yang fullname: Yang, Yanbing organization: Department of Advanced Materials and Nanotechnology, College of Engineering, Peking University, 100871, Beijing, P. R. China – sequence: 4 givenname: Mu surname: Wang fullname: Wang, Mu organization: State Key Laboratory of Organic-Inorganic Composites, College of Materials Science and Engineering, Beijing University of Chemical Technology, 100029, Beijing, P. R. China – sequence: 5 givenname: Anyuan surname: Cao fullname: Cao, Anyuan email: zhanghaobin@mail.buct.edu.cn organization: Department of Advanced Materials and Nanotechnology, College of Engineering, Peking University, 100871, Beijing, P. R. China – sequence: 6 givenname: Zhong-Zhen surname: Yu fullname: Yu, Zhong-Zhen email: zhanghaobin@mail.buct.edu.cn organization: State Key Laboratory of Organic-Inorganic Composites, College of Materials Science and Engineering, Beijing University of Chemical Technology, 100029, Beijing, P. R. China |
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| Copyright | 2015 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim |
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| Notes | National Natural Science Foundation of China - No. 51373011; No. 51125010; No. 51533001 China Scholarship Council for Young Scholar Studies Abroad - No. 201406885081 State Key Laboratory of Organic-Inorganic Composites - No. 201501007 Fundamental Research Funds for the Central Universities - No. YS201402 ArticleID:ADFM201503782 istex:6E3A1610A6CEA1E58F47581DDC7F7187F5143261 ark:/67375/WNG-LXFZRVWK-9 ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
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| PublicationDate | January 20, 2016 |
| PublicationDateYYYYMMDD | 2016-01-20 |
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| PublicationDecade | 2010 |
| PublicationTitle | Advanced functional materials |
| PublicationTitleAlternate | Adv. Funct. Mater |
| PublicationYear | 2016 |
| Publisher | Blackwell Publishing Ltd |
| Publisher_xml | – name: Blackwell Publishing Ltd |
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| Snippet | Light‐weight and high‐performance electromagnetic interference (EMI)‐shielding epoxy nanocomposites are prepared by an infiltration method using a 3D carbon... Light-weight and high-performance electromagnetic interference (EMI)-shielding epoxy nanocomposites are prepared by an infiltration method using a 3D carbon... |
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| SubjectTerms | carbon nanotube sponges Conduction Electromagnetic interference electromagnetic interference shielding epoxy Nanocomposites Noise levels Reinforcement Sponges structure-property relationships Three dimensional X-band |
| Title | High-Performance Epoxy Nanocomposites Reinforced with Three-Dimensional Carbon Nanotube Sponge for Electromagnetic Interference Shielding |
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