Effectiveness of crystallitic carbon from coal as milling aid and for hydrogen storage during milling with magnesium
► Carbon from coal acted as dispersant, lubricant and milling media for Mg milling. ► The Mg easily hydrided into β-MgH2 and γ-MgH2 during milling under hydrogen. ► Nanocomposites with hydrogen capacity of 6.67wt.% were prepared by 3h of milling. ► CH dangling bonds made some contribution to hydroge...
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| Published in | Fuel (Guildford) Vol. 109; pp. 68 - 75 |
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| Main Authors | , , , , , , , , , |
| Format | Journal Article |
| Language | English |
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Kidlington
Elsevier Ltd
01.07.2013
Elsevier |
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| Abstract | ► Carbon from coal acted as dispersant, lubricant and milling media for Mg milling. ► The Mg easily hydrided into β-MgH2 and γ-MgH2 during milling under hydrogen. ► Nanocomposites with hydrogen capacity of 6.67wt.% were prepared by 3h of milling. ► CH dangling bonds made some contribution to hydrogen capacity of the composites.
This paper is concerned with the functions of crystallitic carbon, prepared from anthracite coal by demineralization and carbonization, for making Mg-based nanocomposites for hydrogen storage by reactive milling under hydrogen atmosphere. The TEM and XRD analysis show that in the presence of 30wt.% of crystallitic carbon, the Mg easily hydrided into β-MgH2 of particle size 20–60nm and crystal grain size 29.7nm and a small amount of γ-MgH2 after 3h of milling under 1MPa H2. The hydrogen content of the composites is up to 5.81wt.% determined by water displacement method, and its dehydrogenation peak temperature is 344.2°C by DSC analysis. The enthalpy and entropy changes of the hydrogen desorption reaction are 42.7kJ/mol and 80.7J/molK, respectively, calculated by the van’t Hoff equation from the p–C–T data in 300–380°C. With the extension of milling time, more γ-MgH2 yielded, and the endothermic peak of γ-MgH2 separated from that of β-MgH2. The CH dangling bonds in the hydrogenated carbon were determined by FT-IR analysis. The dehydrogenation temperature of the materials decreased with the addition of Co, Ni, Fe and Al. |
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| AbstractList | This paper is concerned with the functions of crystallitic carbon, prepared from anthracite coal by demineralization and carbonization, for making Mg-based nanocomposites for hydrogen storage by reactive milling under hydrogen atmosphere. The TEM and XRD analysis show that in the presence of 30 wt.% of crystallitic carbon, the Mg easily hydrided into I2-MgH2 of particle size 20a60 nm and crystal grain size 29.7 nm and a small amount of I3-MgH2 after 3 h of milling under 1 MPa H2. The hydrogen content of the composites is up to 5.81 wt.% determined by water displacement method, and its dehydrogenation peak temperature is 344.2 degree C by DSC analysis. The enthalpy and entropy changes of the hydrogen desorption reaction are 42.7 kJ/mol and 80.7 J/mol K, respectively, calculated by the vanat Hoff equation from the paCaT data in 300a380 degree C. With the extension of milling time, more I3-MgH2 yielded, and the endothermic peak of I3-MgH2 separated from that of I2-MgH2. The CH dangling bonds in the hydrogenated carbon were determined by FT-IR analysis. The dehydrogenation temperature of the materials decreased with the addition of Co, Ni, Fe and Al. This paper is concerned with the functions of crystallitic carbon, prepared from anthracite coal by demineralization and carbonization, for making Mg-based nanocomposites for hydrogen storage by reactive milling under hydrogen atmosphere. The TEM and XRD analysis show that in the presence of 30wt.% of crystallitic carbon, the Mg easily hydrided into β-MgH₂ of particle size 20–60nm and crystal grain size 29.7nm and a small amount of γ-MgH₂ after 3h of milling under 1MPa H₂. The hydrogen content of the composites is up to 5.81wt.% determined by water displacement method, and its dehydrogenation peak temperature is 344.2°C by DSC analysis. The enthalpy and entropy changes of the hydrogen desorption reaction are 42.7kJ/mol and 80.7J/molK, respectively, calculated by the van’t Hoff equation from the p–C–T data in 300–380°C. With the extension of milling time, more γ-MgH₂ yielded, and the endothermic peak of γ-MgH₂ separated from that of β-MgH₂. The CH dangling bonds in the hydrogenated carbon were determined by FT-IR analysis. The dehydrogenation temperature of the materials decreased with the addition of Co, Ni, Fe and Al. ► Carbon from coal acted as dispersant, lubricant and milling media for Mg milling. ► The Mg easily hydrided into β-MgH2 and γ-MgH2 during milling under hydrogen. ► Nanocomposites with hydrogen capacity of 6.67wt.% were prepared by 3h of milling. ► CH dangling bonds made some contribution to hydrogen capacity of the composites. This paper is concerned with the functions of crystallitic carbon, prepared from anthracite coal by demineralization and carbonization, for making Mg-based nanocomposites for hydrogen storage by reactive milling under hydrogen atmosphere. The TEM and XRD analysis show that in the presence of 30wt.% of crystallitic carbon, the Mg easily hydrided into β-MgH2 of particle size 20–60nm and crystal grain size 29.7nm and a small amount of γ-MgH2 after 3h of milling under 1MPa H2. The hydrogen content of the composites is up to 5.81wt.% determined by water displacement method, and its dehydrogenation peak temperature is 344.2°C by DSC analysis. The enthalpy and entropy changes of the hydrogen desorption reaction are 42.7kJ/mol and 80.7J/molK, respectively, calculated by the van’t Hoff equation from the p–C–T data in 300–380°C. With the extension of milling time, more γ-MgH2 yielded, and the endothermic peak of γ-MgH2 separated from that of β-MgH2. The CH dangling bonds in the hydrogenated carbon were determined by FT-IR analysis. The dehydrogenation temperature of the materials decreased with the addition of Co, Ni, Fe and Al. This paper is concerned with the functions of crystallitic carbon, prepared from anthracite coal by demineralization and carbonization, for making Mg-based nanocomposites for hydrogen storage by reactive milling under hydrogen atmosphere. The TEM and XRD analysis show that in the presence of 30 wt.% of crystallitic carbon, the Mg easily hydrided into [beta]-MgH sub(2) of particle size 20-60 nm and crystal grain size 29.7 nm and a small amount of [gamma]-MgH sub(2) after 3 h of milling under 1 MPa H sub(2). The hydrogen content of the composites is up to 5.81 wt.% determined by water displacement method, and its dehydrogenation peak temperature is 344.2 [degrees]C by DSC analysis. The enthalpy and entropy changes of the hydrogen desorption reaction are 42.7 kJ/mol and 80.7 J/mol K, respectively, calculated by the van't Hoff equation from the p-C-T data in 300-380 [degrees]C. With the extension of milling time, more [gamma]-MgH sub(2) yielded, and the endothermic peak of [gamma]-MgH sub(2) separated from that of [beta]-MgH sub(2). The C-H dangling bonds in the hydrogenated carbon were determined by FT-IR analysis. The dehydrogenation temperature of the materials decreased with the addition of Co, Ni, Fe and Al. |
| Author | Wang, Naifei Niu, Haili Zhang, Qianqian Yu, Hongguan Chen, Haipeng Liu, Di Ding, Chao Han, Shuna Zhou, Shixue Zhang, Tonghuan |
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| Keywords | Crystallitic carbon Hydrogen storage material Magnesium Reactive milling Differential scanning calorimetry Particle size Demineralization Hydrogen Enthalpy Aluminium Desorption Iron Anthracite Carbonization Transmission electron microscopy Storage Dehydrogenation Coal Nickel X ray diffractometry Nanostructured materials |
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| Snippet | ► Carbon from coal acted as dispersant, lubricant and milling media for Mg milling. ► The Mg easily hydrided into β-MgH2 and γ-MgH2 during milling under... This paper is concerned with the functions of crystallitic carbon, prepared from anthracite coal by demineralization and carbonization, for making Mg-based... |
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| SubjectTerms | Aluminum Applied sciences Carbon carbonization Coal cobalt Crystallitic carbon Dehydrogenation desorption Energy Energy. Thermal use of fuels enthalpy Entropy equations Exact sciences and technology Fourier transform infrared spectroscopy Fuels hydrogen Hydrogen storage Hydrogen storage material iron Magnesium Mathematical analysis milling nanocomposites nickel particle size Reactive milling temperature transmission electron microscopy X-ray diffraction |
| Title | Effectiveness of crystallitic carbon from coal as milling aid and for hydrogen storage during milling with magnesium |
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