Hierarchical Graphene-Carbon Fiber Composite Paper as a Flexible Lateral Heat Spreader
As a low dimensional crystal, graphene attracts great attention as heat dissipation material due to its unique thermal transfer property exceeding the limit of bulk graphite. In this contribution, flexible graphene–carbon fiber composite paper is fabricated by depositing graphene oxide into the carb...
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| Published in | Advanced functional materials Vol. 24; no. 27; pp. 4222 - 4228 |
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| Main Authors | , , , , , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Blackwell Publishing Ltd
16.07.2014
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| Subjects | |
| Online Access | Get full text |
| ISSN | 1616-301X 1616-3028 |
| DOI | 10.1002/adfm.201304144 |
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| Abstract | As a low dimensional crystal, graphene attracts great attention as heat dissipation material due to its unique thermal transfer property exceeding the limit of bulk graphite. In this contribution, flexible graphene–carbon fiber composite paper is fabricated by depositing graphene oxide into the carbon fiber precursor followed by carbonization. In this full‐carbon architecture, scaffold of one‐dimensional carbon fiber is employed as the structural component to reinforce the mechanical strength, while the hierarchically arranged two‐dimensional graphene in the framework provides a convenient pathway for in‐plane acoustic phonon transmission. The as‐obtained hierarchical carbon/carbon composite paper possesses ultra‐high in‐plane thermal conductivity of 977 W m−1 K−1 and favorable tensile strength of 15.3 MPa. The combined mechanical and thermal performances make the material highly desirable as lateral heat spreader for next‐generation commercial portable electronics.
Flexible graphene–carbon fiber composite paper with an ultra‐high thermal diffusivity of 5458 mm2 s−1, a very large thermal conductivity of 977 W m−1 K−1, and a tensile strength of 15.3 MPa is fabricated through facile filtration route, in which the close packed graphene nanosheets provide high thermal conductivity, while carbon fiber acts as the structural scaffold to render excellent mechanical properties. |
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| AbstractList | As a low dimensional crystal, graphene attracts great attention as heat dissipation material due to its unique thermal transfer property exceeding the limit of bulk graphite. In this contribution, flexible graphene–carbon fiber composite paper is fabricated by depositing graphene oxide into the carbon fiber precursor followed by carbonization. In this full‐carbon architecture, scaffold of one‐dimensional carbon fiber is employed as the structural component to reinforce the mechanical strength, while the hierarchically arranged two‐dimensional graphene in the framework provides a convenient pathway for in‐plane acoustic phonon transmission. The as‐obtained hierarchical carbon/carbon composite paper possesses ultra‐high in‐plane thermal conductivity of 977 W m−1 K−1 and favorable tensile strength of 15.3 MPa. The combined mechanical and thermal performances make the material highly desirable as lateral heat spreader for next‐generation commercial portable electronics.
Flexible graphene–carbon fiber composite paper with an ultra‐high thermal diffusivity of 5458 mm2 s−1, a very large thermal conductivity of 977 W m−1 K−1, and a tensile strength of 15.3 MPa is fabricated through facile filtration route, in which the close packed graphene nanosheets provide high thermal conductivity, while carbon fiber acts as the structural scaffold to render excellent mechanical properties. As a low dimensional crystal, graphene attracts great attention as heat dissipation material due to its unique thermal transfer property exceeding the limit of bulk graphite. In this contribution, flexible graphene-carbon fiber composite paper is fabricated by depositing graphene oxide into the carbon fiber precursor followed by carbonization. In this full-carbon architecture, scaffold of one-dimensional carbon fiber is employed as the structural component to reinforce the mechanical strength, while the hierarchically arranged two-dimensional graphene in the framework provides a convenient pathway for in-plane acoustic phonon transmission. The as-obtained hierarchical carbon/carbon composite paper possesses ultra-high in-plane thermal conductivity of 977 W m super(-1) K super(-1) and favorable tensile strength of 15.3 MPa. The combined mechanical and thermal performances make the material highly desirable as lateral heat spreader for next-generation commercial portable electronics. Flexible graphene-carbon fiber composite paper with an ultra-high thermal diffusivity of 5458 mm super(2) s super(-1), a very large thermal conductivity of 977 W m super(-1) K super(-1), and a tensile strength of 15.3 MPa is fabricated through facile filtration route, in which the close packed graphene nanosheets provide high thermal conductivity, while carbon fiber acts as the structural scaffold to render excellent mechanical properties. As a low dimensional crystal, graphene attracts great attention as heat dissipation material due to its unique thermal transfer property exceeding the limit of bulk graphite. In this contribution, flexible graphene–carbon fiber composite paper is fabricated by depositing graphene oxide into the carbon fiber precursor followed by carbonization. In this full‐carbon architecture, scaffold of one‐dimensional carbon fiber is employed as the structural component to reinforce the mechanical strength, while the hierarchically arranged two‐dimensional graphene in the framework provides a convenient pathway for in‐plane acoustic phonon transmission. The as‐obtained hierarchical carbon/carbon composite paper possesses ultra‐high in‐plane thermal conductivity of 977 W m −1 K −1 and favorable tensile strength of 15.3 MPa. The combined mechanical and thermal performances make the material highly desirable as lateral heat spreader for next‐generation commercial portable electronics. |
| Author | Zhou, Guangmin Kong, Qing-Qiang Wang, Mao-Zhang Gao, Jian-Guo Zhang, Xing-Hua Zhang, Qiang Tao, Ze-Chao Li, Feng Liu, Zhuo Cai, Rong Chen, Cheng-Meng |
| Author_xml | – sequence: 1 givenname: Qing-Qiang surname: Kong fullname: Kong, Qing-Qiang organization: Key Laboratory of Carbon Materials, Institute of Coal Chemistry, Chinese Academy of Sciences, 27 Taoyuan South Road, 030001, Taiyuan, China – sequence: 2 givenname: Zhuo surname: Liu fullname: Liu, Zhuo organization: Key Laboratory of Carbon Materials, Institute of Coal Chemistry, Chinese Academy of Sciences, 27 Taoyuan South Road, 030001, Taiyuan, China – sequence: 3 givenname: Jian-Guo surname: Gao fullname: Gao, Jian-Guo organization: Key Laboratory of Carbon Materials, Institute of Coal Chemistry, Chinese Academy of Sciences, 27 Taoyuan South Road, 030001, Taiyuan, China – sequence: 4 givenname: Cheng-Meng surname: Chen fullname: Chen, Cheng-Meng email: ccm@sxicc.ac.cn organization: Key Laboratory of Carbon Materials, Institute of Coal Chemistry, Chinese Academy of Sciences, 27 Taoyuan South Road, 030001, Taiyuan, China – sequence: 5 givenname: Qiang surname: Zhang fullname: Zhang, Qiang organization: Beijing Key Laboratory of Green Chemical, Reaction Engineering and Technology, Department of Chemical Engineering, Tsinghua University, 10084, Beijing, China – sequence: 6 givenname: Guangmin surname: Zhou fullname: Zhou, Guangmin organization: Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, 100016, Shenyang, China – sequence: 7 givenname: Ze-Chao surname: Tao fullname: Tao, Ze-Chao organization: Key Laboratory of Carbon Materials, Institute of Coal Chemistry, Chinese Academy of Sciences, 27 Taoyuan South Road, 030001, Taiyuan, China – sequence: 8 givenname: Xing-Hua surname: Zhang fullname: Zhang, Xing-Hua organization: Key Laboratory of Carbon Materials, Institute of Coal Chemistry, Chinese Academy of Sciences, 27 Taoyuan South Road, 030001, Taiyuan, China – sequence: 9 givenname: Mao-Zhang surname: Wang fullname: Wang, Mao-Zhang organization: Key Laboratory of Carbon Materials, Institute of Coal Chemistry, Chinese Academy of Sciences, 27 Taoyuan South Road, 030001, Taiyuan, China – sequence: 10 givenname: Feng surname: Li fullname: Li, Feng organization: Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, 100016, Shenyang, China – sequence: 11 givenname: Rong surname: Cai fullname: Cai, Rong organization: Key Laboratory of Carbon Materials, Institute of Coal Chemistry, Chinese Academy of Sciences, 27 Taoyuan South Road, 030001, Taiyuan, China |
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| SubjectTerms | Carbon Carbon fibers composites Fiber composites Graphene Heat transfer Spreaders Thermal conductivity |
| Title | Hierarchical Graphene-Carbon Fiber Composite Paper as a Flexible Lateral Heat Spreader |
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