Aerobic copper/TEMPO-catalyzed oxidation of primary alcohols to aldehydes using a microbubble strategy to increase gas concentration in liquid phase reactions

An efficient method for the synthesis of aldehydes was achieved by using air-microbubble techniques in aerobic copper/TEMPO-catalyzed oxidation of primary alcohols. Use of air-microbubbles to improve gas absorption into liquid phase is proven to be highly beneficial for gas/liquid phase reactions.

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Bibliographic Details
Published inChemical communications (Cambridge, England) Vol. 47; no. 7; pp. 2086 - 2088
Main Authors Mase, Nobuyuki, Mizumori, Tomoya, Tatemoto, Yuji
Format Journal Article
LanguageEnglish
Published England 01.01.2011
Subjects
Alcohols
Aldehydes
Copper
Liquid phases
Microorganisms
Oxidation
Strategy
Synthesis
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Summary:An efficient method for the synthesis of aldehydes was achieved by using air-microbubble techniques in aerobic copper/TEMPO-catalyzed oxidation of primary alcohols. Use of air-microbubbles to improve gas absorption into liquid phase is proven to be highly beneficial for gas/liquid phase reactions.
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ISSN:1359-7345
1364-548X
DOI:10.1039/c0cc04377j