Pore structure evolution and geological controls in lacustrine shale systems with implications for marine shale reservoir characterization

Understanding pore structure evolution in lacustrine shale systems provides critical insights for marine shale reservoir characterization. This study presents an integrated petrological and petrophysical analysis of a representative lacustrine shale succession, employing low temperature nitrogen ads...

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Published inScientific reports Vol. 15; no. 1; pp. 17702 - 14
Main Authors Li, Hu, Xu, Ziqiang, Gao, Xiaodan, Xie, Jiatong, Qin, Qirong, Wang, Haijun, He, Shun
Format Journal Article
LanguageEnglish
Published London Nature Publishing Group UK 21.05.2025
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Abstract Understanding pore structure evolution in lacustrine shale systems provides critical insights for marine shale reservoir characterization. This study presents an integrated petrological and petrophysical analysis of a representative lacustrine shale succession, employing low temperature nitrogen adsorption (LTNA), whole rock X-ray diffraction (XRD), and scanning electron microscopy (SEM). The study shows that (1) Clay-dominated pore systems evolve through distinct pathways compared to marine shales, with illite/smectite mixed-layer minerals generating abundant mesopores through diagenetic transformation. (2) Organic matter- dominated pores display limited connectivity due to Type III kerogen characteristics and hydrocarbon generation-induced pore occlusion, contrasting with marine shale systems dominated by Type II kerogen. (3) Comparative analysis demonstrates that lacustrine shales preserve 30–40% higher micro-mesopore volumes than their marine counterparts under similar thermal maturity conditions, attributed to enhanced clay mineral diagenesis in freshwater environments. These findings provide a new framework for understanding pore structure development in non-marine depositional systems and provide valuable analogs for marine shale reservoir evaluation, particularly in transitional marine-lacustrine basins.
AbstractList Understanding pore structure evolution in lacustrine shale systems provides critical insights for marine shale reservoir characterization. This study presents an integrated petrological and petrophysical analysis of a representative lacustrine shale succession, employing low temperature nitrogen adsorption (LTNA), whole rock X-ray diffraction (XRD), and scanning electron microscopy (SEM). The study shows that (1) Clay-dominated pore systems evolve through distinct pathways compared to marine shales, with illite/smectite mixed-layer minerals generating abundant mesopores through diagenetic transformation. (2) Organic matter- dominated pores display limited connectivity due to Type III kerogen characteristics and hydrocarbon generation-induced pore occlusion, contrasting with marine shale systems dominated by Type II kerogen. (3) Comparative analysis demonstrates that lacustrine shales preserve 30–40% higher micro-mesopore volumes than their marine counterparts under similar thermal maturity conditions, attributed to enhanced clay mineral diagenesis in freshwater environments. These findings provide a new framework for understanding pore structure development in non-marine depositional systems and provide valuable analogs for marine shale reservoir evaluation, particularly in transitional marine-lacustrine basins.
Understanding pore structure evolution in lacustrine shale systems provides critical insights for marine shale reservoir characterization. This study presents an integrated petrological and petrophysical analysis of a representative lacustrine shale succession, employing low temperature nitrogen adsorption (LTNA), whole rock X-ray diffraction (XRD), and scanning electron microscopy (SEM). The study shows that (1) Clay-dominated pore systems evolve through distinct pathways compared to marine shales, with illite/smectite mixed-layer minerals generating abundant mesopores through diagenetic transformation. (2) Organic matter- dominated pores display limited connectivity due to Type III kerogen characteristics and hydrocarbon generation-induced pore occlusion, contrasting with marine shale systems dominated by Type II kerogen. (3) Comparative analysis demonstrates that lacustrine shales preserve 30-40% higher micro-mesopore volumes than their marine counterparts under similar thermal maturity conditions, attributed to enhanced clay mineral diagenesis in freshwater environments. These findings provide a new framework for understanding pore structure development in non-marine depositional systems and provide valuable analogs for marine shale reservoir evaluation, particularly in transitional marine-lacustrine basins.Understanding pore structure evolution in lacustrine shale systems provides critical insights for marine shale reservoir characterization. This study presents an integrated petrological and petrophysical analysis of a representative lacustrine shale succession, employing low temperature nitrogen adsorption (LTNA), whole rock X-ray diffraction (XRD), and scanning electron microscopy (SEM). The study shows that (1) Clay-dominated pore systems evolve through distinct pathways compared to marine shales, with illite/smectite mixed-layer minerals generating abundant mesopores through diagenetic transformation. (2) Organic matter- dominated pores display limited connectivity due to Type III kerogen characteristics and hydrocarbon generation-induced pore occlusion, contrasting with marine shale systems dominated by Type II kerogen. (3) Comparative analysis demonstrates that lacustrine shales preserve 30-40% higher micro-mesopore volumes than their marine counterparts under similar thermal maturity conditions, attributed to enhanced clay mineral diagenesis in freshwater environments. These findings provide a new framework for understanding pore structure development in non-marine depositional systems and provide valuable analogs for marine shale reservoir evaluation, particularly in transitional marine-lacustrine basins.
Abstract Understanding pore structure evolution in lacustrine shale systems provides critical insights for marine shale reservoir characterization. This study presents an integrated petrological and petrophysical analysis of a representative lacustrine shale succession, employing low temperature nitrogen adsorption (LTNA), whole rock X-ray diffraction (XRD), and scanning electron microscopy (SEM). The study shows that (1) Clay-dominated pore systems evolve through distinct pathways compared to marine shales, with illite/smectite mixed-layer minerals generating abundant mesopores through diagenetic transformation. (2) Organic matter- dominated pores display limited connectivity due to Type III kerogen characteristics and hydrocarbon generation-induced pore occlusion, contrasting with marine shale systems dominated by Type II kerogen. (3) Comparative analysis demonstrates that lacustrine shales preserve 30–40% higher micro-mesopore volumes than their marine counterparts under similar thermal maturity conditions, attributed to enhanced clay mineral diagenesis in freshwater environments. These findings provide a new framework for understanding pore structure development in non-marine depositional systems and provide valuable analogs for marine shale reservoir evaluation, particularly in transitional marine-lacustrine basins.
ArticleNumber 17702
Author Gao, Xiaodan
Li, Hu
Wang, Haijun
He, Shun
Xie, Jiatong
Xu, Ziqiang
Qin, Qirong
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Issue 1
Keywords Unconventional reservoirs
Lacustrine shale
Nitrogen adsorption analysis
Pore structure evolution
Diagenetic controls
Language English
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Snippet Understanding pore structure evolution in lacustrine shale systems provides critical insights for marine shale reservoir characterization. This study presents...
Abstract Understanding pore structure evolution in lacustrine shale systems provides critical insights for marine shale reservoir characterization. This study...
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SubjectTerms 704/2151/213
704/2151/3930
704/2151/431
Adsorption
Clay
Comparative analysis
Connectivity
Diagenesis
Diagenetic controls
Engineering
Evolution
Experiments
Freshwater environments
Gases
Geology
Humanities and Social Sciences
Illite
Kerogen
Lacustrine shale
Lithology
Low temperature
multidisciplinary
Nitrogen adsorption analysis
Oil shale
Organic matter
Oxidation
Pore structure evolution
Reservoirs
Scanning electron microscopy
Science
Science (multidisciplinary)
Sedimentation & deposition
Shale
Shale gas
Shale oil
Shales
Unconventional reservoirs
X-ray diffraction
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Title Pore structure evolution and geological controls in lacustrine shale systems with implications for marine shale reservoir characterization
URI https://link.springer.com/article/10.1038/s41598-025-02415-y
https://www.ncbi.nlm.nih.gov/pubmed/40399384
https://www.proquest.com/docview/3207704574
https://www.proquest.com/docview/3206592038
https://pubmed.ncbi.nlm.nih.gov/PMC12095546
https://doaj.org/article/1fac532183634db5a9fd415a7141f89c
Volume 15
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