Iridium porphyrin-catalysed asymmetric carbene insertion into primary N-adjacent C–H bonds with TON over 1000000 - Li, Zong-Rui; Zhan, Kun; Wang, Yi-Jie; Wu, Liang-Liang; Lu, Guo-Lin; Wang, Hao-Yang; Wan, Xiao-Long; Xu, Zhen-Jiang; Low, Kam-Hung; Che, Chi-Ming (Nature communications, 2025)
Keywords: 119/118; 140/131; 140/58; 639/638/77/883; 639/638/77/888; Amino acids; Aniline; Asymmetry; Atom economy; Carbenes; Catalysis; Chemical bonds; Chemical synthesis; Chemistry; Efficiency; Enzymes; Humanities and Social Sciences; Hydrogen bonds; Hydrogenation; Insertion; Iridium; multidisciplinary; Organic chemistry; Polymers; Porphyrins; Science; Science (multidisciplinary); Selectivity