Photoinduced Photocatalyst-Free Cascade Cyclization of Alkynes with Sodium Sulfinates for the Synthesis of Benzothiophenes and Thioflavones
The subject of this investigation is a new method for the construction of sulfonylated heterocycles which overcomes the limitations of classical approaches using a cheap feedstock sulfonylating agent, especially under photocatalyst- and metal-free conditions.
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| Published in | Molecules (Basel, Switzerland) Vol. 28; no. 11; p. 4436 |
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| Main Authors | , , , , |
| Format | Journal Article |
| Language | English |
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| Abstract | The subject of this investigation is a new method for the construction of sulfonylated heterocycles which overcomes the limitations of classical approaches using a cheap feedstock sulfonylating agent, especially under photocatalyst- and metal-free conditions. |
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| AbstractList | The subject of this investigation is a new method for the construction of sulfonylated heterocycles which overcomes the limitations of classical approaches using a cheap feedstock sulfonylating agent, especially under photocatalyst- and metal-free conditions.The subject of this investigation is a new method for the construction of sulfonylated heterocycles which overcomes the limitations of classical approaches using a cheap feedstock sulfonylating agent, especially under photocatalyst- and metal-free conditions. The subject of this investigation is a new method for the construction of sulfonylated heterocycles which overcomes the limitations of classical approaches using a cheap feedstock sulfonylating agent, especially under photocatalyst- and metal-free conditions. |
| Author | Zhao, Jinlei Ji, Yigang Dong, Hongqiang Chen, Chunli Yang, Wenchao |
| AuthorAffiliation | 1 The Open Research Fund of the National and Local Joint Engineering Laboratory of High Efficiency and Superior-Quality Cultivation and Fruit Deep Processing Technology of Characteristic Fruit Trees in South Xinjiang, College of Agriculture, Tarim University, Alaer 843300, China; chenchunli1111@163.com 3 Jiangsu Surveying and Design Institute of Water Resources Co., Ltd., Yangzhou 225127, China 5 Guangling College and School of Plant Protection, Yangzhou University, Yangzhou 225009, China 4 Jiangsu Key Laboratory of Biofuctional Molecules, Department of Life Sciences and Chemistry, Jiangsu Second Normal University, Nanjing 210013, China 2 National Engineering Research Center of Low-Carbon Processing and Utilization of Forest Biomass, Nanjing Forestry University, Nanjing 210037, China; hhuzhjl@163.com |
| AuthorAffiliation_xml | – name: 5 Guangling College and School of Plant Protection, Yangzhou University, Yangzhou 225009, China – name: 1 The Open Research Fund of the National and Local Joint Engineering Laboratory of High Efficiency and Superior-Quality Cultivation and Fruit Deep Processing Technology of Characteristic Fruit Trees in South Xinjiang, College of Agriculture, Tarim University, Alaer 843300, China; chenchunli1111@163.com – name: 4 Jiangsu Key Laboratory of Biofuctional Molecules, Department of Life Sciences and Chemistry, Jiangsu Second Normal University, Nanjing 210013, China – name: 3 Jiangsu Surveying and Design Institute of Water Resources Co., Ltd., Yangzhou 225127, China – name: 2 National Engineering Research Center of Low-Carbon Processing and Utilization of Forest Biomass, Nanjing Forestry University, Nanjing 210037, China; hhuzhjl@163.com |
| Author_xml | – sequence: 1 givenname: Hongqiang surname: Dong fullname: Dong, Hongqiang – sequence: 2 givenname: Chunli surname: Chen fullname: Chen, Chunli – sequence: 3 givenname: Jinlei surname: Zhao fullname: Zhao, Jinlei – sequence: 4 givenname: Yigang surname: Ji fullname: Ji, Yigang – sequence: 5 givenname: Wenchao surname: Yang fullname: Yang, Wenchao |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/37298913$$D View this record in MEDLINE/PubMed |
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| CitedBy_id | crossref_primary_10_1002_ejoc_202401059 crossref_primary_10_1021_acs_orglett_4c04230 crossref_primary_10_2174_0115680266313243240624071549 |
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| Keywords | radical sulfonylation cyclization alkynes sodium sulfinates |
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| SubjectTerms | alkynes Chemistry Chromatography cyclization Free radicals Oxidation Photocatalysis radical Sodium sodium sulfinates sulfonylation |
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| Title | Photoinduced Photocatalyst-Free Cascade Cyclization of Alkynes with Sodium Sulfinates for the Synthesis of Benzothiophenes and Thioflavones |
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