Green Emissive Copper(I) Coordination Polymer Supported by the Diethylpyridylphosphine Ligand as a Luminescent Sensor for Overheating Processes

• Published in: Molecules (Basel, Switzerland) Vol. 28; no. 2; p. 706
• Main Authors: Enikeeva, Kamila R., Shamsieva, Aliia V., Strelnik, Anna G., Fayzullin, Robert R., Zakharychev, Dmitry V., Kolesnikov, Ilya E., Dayanova, Irina R., Gerasimova, Tatiana P., Strelnik, Igor D., Musina, Elvira I., Karasik, Andrey A., Sinyashin, Oleg G.
• Format: Journal Article
• Language: English
• Published: Switzerland MDPI AG 10.01.2023; MDPI
• Subjects: Copper; copper(I) complexes; Cu4I4 clusters; Ligands; luminescent complexes; P,N-ligands; phosphines; Polymers; phosphines; copper(I) complexes; luminescent complexes; Cu4I4 clusters; P,N-ligands

Tertiary diethylpyridylphosphine was synthesized by the reaction of pyridylphosphine with bromoethane in a suberbasic medium. The reaction of phosphine with the copper(I) iodide led to the formation of a copper(I) coordination polymer, which, according to the X-ray diffraction data, has an intermedi...