The Current Status of Heterogeneous Palladium Catalysed Heck and Suzuki Cross-Coupling Reactions

In the last 30 years, C⁻C cross coupling reactions have become a reliable technique in organic synthesis due their versatility and efficiency. While drawbacks have been experienced on an industrial scale with the use of homogenous systems, many attempts have been made to facilitate a heterogeneous r...

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Published inMolecules (Basel, Switzerland) Vol. 23; no. 7; p. 1676
Main Authors Mpungose, Philani P, Vundla, Zanele P, Maguire, Glenn E M, Friedrich, Holger B
Format Journal Article
LanguageEnglish
Published Switzerland MDPI AG 10.07.2018
MDPI
Subjects
Activated carbon
Catalysis
Catalysts
Chemical reactions
Cross coupling
C–C cross coupling
Efficiency
Heck cross-coupling
heterogeneous palladium catalysis
Nanoparticles
Palladium
Pharmaceutical industry
Review
Suzuki cross-coupling
heterogeneous palladium catalysis
Heck cross-coupling
C–C cross coupling
Suzuki cross-coupling
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Abstract In the last 30 years, C⁻C cross coupling reactions have become a reliable technique in organic synthesis due their versatility and efficiency. While drawbacks have been experienced on an industrial scale with the use of homogenous systems, many attempts have been made to facilitate a heterogeneous renaissance. Thus, this review gives an overview of the current status of the use of heterogeneous catalysts particularly in Suzuki and Heck reactions. Most recent developments focus on palladium immobilised or supported on various classes of supports, thus this review highlights and discuss contributions of the last decade.
AbstractList In the last 30 years, C–C cross coupling reactions have become a reliable technique in organic synthesis due their versatility and efficiency. While drawbacks have been experienced on an industrial scale with the use of homogenous systems, many attempts have been made to facilitate a heterogeneous renaissance. Thus, this review gives an overview of the current status of the use of heterogeneous catalysts particularly in Suzuki and Heck reactions. Most recent developments focus on palladium immobilised or supported on various classes of supports, thus this review highlights and discuss contributions of the last decade.
In the last 30 years, C⁻C cross coupling reactions have become a reliable technique in organic synthesis due their versatility and efficiency. While drawbacks have been experienced on an industrial scale with the use of homogenous systems, many attempts have been made to facilitate a heterogeneous renaissance. Thus, this review gives an overview of the current status of the use of heterogeneous catalysts particularly in Suzuki and Heck reactions. Most recent developments focus on palladium immobilised or supported on various classes of supports, thus this review highlights and discuss contributions of the last decade.
Author Friedrich, Holger B
Vundla, Zanele P
Mpungose, Philani P
Maguire, Glenn E M
AuthorAffiliation 1 Catalysis Research Group, School of Chemistry and Physics, University of KwaZulu-Natal, Westville Campus, Durban 4000, South Africa; 207506038@stu.ukzn.ac.za (P.P.M.); sjaejj@gmail.com (Z.P.V.)
2 School of Chemistry and Physics, University of KwaZulu-Natal, Varsity Drive, Durban 4001, South Africa; maguireg@ukzn.ac.za
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– name: 2 School of Chemistry and Physics, University of KwaZulu-Natal, Varsity Drive, Durban 4001, South Africa; maguireg@ukzn.ac.za
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  fullname: Friedrich, Holger B
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  organization: Catalysis Research Group, School of Chemistry and Physics, University of KwaZulu-Natal, Westville Campus, Durban 4000, South Africa. friedric@ukzn.ac.za
BackLink https://www.ncbi.nlm.nih.gov/pubmed/29996491$$D View this record in MEDLINE/PubMed
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Issue 7
Keywords heterogeneous palladium catalysis
Heck cross-coupling
C–C cross coupling
Suzuki cross-coupling
Language English
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Snippet In the last 30 years, C⁻C cross coupling reactions have become a reliable technique in organic synthesis due their versatility and efficiency. While drawbacks...
In the last 30 years, C–C cross coupling reactions have become a reliable technique in organic synthesis due their versatility and efficiency. While drawbacks...
In the last 30 years, C-C cross coupling reactions have become a reliable technique in organic synthesis due their versatility and efficiency. While drawbacks...
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StartPage 1676
SubjectTerms Activated carbon
Catalysis
Catalysts
Chemical reactions
Cross coupling
C–C cross coupling
Efficiency
Heck cross-coupling
heterogeneous palladium catalysis
Nanoparticles
Palladium
Pharmaceutical industry
Review
Suzuki cross-coupling
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Title The Current Status of Heterogeneous Palladium Catalysed Heck and Suzuki Cross-Coupling Reactions
URI https://www.ncbi.nlm.nih.gov/pubmed/29996491
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https://doaj.org/article/38c5cd987a5b43579cc7e208fd2b483d
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