Anti-corrosion of amphoteric metal enhanced by MAO/corrosion inhibitor composite in acid, alkaline and salt solutions

[Display omitted] An anticorrosive composite coating with enhanced corrosion resistance in acid, alkaline and salt solutions was fabricated by compounding micro- and nanoporous inorganic structure and organic corrosion inhibitor, which was used to improve the corrosion resistance of amphoteric metal...

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Published inJournal of colloid and interface science Vol. 554; pp. 488 - 499
Main Authors Sun, Weixiang, Liu, Yupeng, Li, Tinghua, Cui, Siwen, Chen, Shougang, Yu, Qiangliang, Wang, Daoai
Format Journal Article
LanguageEnglish
Published United States Elsevier Inc 15.10.2019
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Abstract [Display omitted] An anticorrosive composite coating with enhanced corrosion resistance in acid, alkaline and salt solutions was fabricated by compounding micro- and nanoporous inorganic structure and organic corrosion inhibitor, which was used to improve the corrosion resistance of amphoteric metal and its oxides in various corrosive medium. Micro- and nanoporous structure was prepared by microarc oxidation (MAO) coatings on 2024 aluminium alloy, which was used both as the inorganic anticorrosion coating and the container for organic corrosion inhibitor (M16). Electrochemical impedance spectroscopy, Tafel plots and salt spray resistance were measured to research the anticorrosion performance of the MAO/M16 composite coating. Enhanced corrosion resistance was observed for the MAO/M16 coating compared to the MAO by itself. When the concentration of corrosion inhibitor M16 is at 2 w%, the best anticorrosive properties of the composite coating were obtained. Moreover, the MAO/M16 composite coating showed better corrosion-resistant performance than pure MAO coating and Al alloy substrate in the corrosion environment of 1 M HCl, 0.1 M NaOH and 3.5 w% NaCl solutions, respectively. The enhancement of corrosion resistance for MAO/M16 composite coating was achieved by a unique synergy between the microarc oxidation layer and the corrosion inhibitor. The composite coating indicates its promising applications in acid, alkaline and salt solutions environments and other harsh environments.
AbstractList [Display omitted] An anticorrosive composite coating with enhanced corrosion resistance in acid, alkaline and salt solutions was fabricated by compounding micro- and nanoporous inorganic structure and organic corrosion inhibitor, which was used to improve the corrosion resistance of amphoteric metal and its oxides in various corrosive medium. Micro- and nanoporous structure was prepared by microarc oxidation (MAO) coatings on 2024 aluminium alloy, which was used both as the inorganic anticorrosion coating and the container for organic corrosion inhibitor (M16). Electrochemical impedance spectroscopy, Tafel plots and salt spray resistance were measured to research the anticorrosion performance of the MAO/M16 composite coating. Enhanced corrosion resistance was observed for the MAO/M16 coating compared to the MAO by itself. When the concentration of corrosion inhibitor M16 is at 2 w%, the best anticorrosive properties of the composite coating were obtained. Moreover, the MAO/M16 composite coating showed better corrosion-resistant performance than pure MAO coating and Al alloy substrate in the corrosion environment of 1 M HCl, 0.1 M NaOH and 3.5 w% NaCl solutions, respectively. The enhancement of corrosion resistance for MAO/M16 composite coating was achieved by a unique synergy between the microarc oxidation layer and the corrosion inhibitor. The composite coating indicates its promising applications in acid, alkaline and salt solutions environments and other harsh environments.
An anticorrosive composite coating with enhanced corrosion resistance in acid, alkaline and salt solutions was fabricated by compounding micro- and nanoporous inorganic structure and organic corrosion inhibitor, which was used to improve the corrosion resistance of amphoteric metal and its oxides in various corrosive medium. Micro- and nanoporous structure was prepared by microarc oxidation (MAO) coatings on 2024 aluminium alloy, which was used both as the inorganic anticorrosion coating and the container for organic corrosion inhibitor (M16). Electrochemical impedance spectroscopy, Tafel plots and salt spray resistance were measured to research the anticorrosion performance of the MAO/M16 composite coating. Enhanced corrosion resistance was observed for the MAO/M16 coating compared to the MAO by itself. When the concentration of corrosion inhibitor M16 is at 2 w%, the best anticorrosive properties of the composite coating were obtained. Moreover, the MAO/M16 composite coating showed better corrosion-resistant performance than pure MAO coating and Al alloy substrate in the corrosion environment of 1 M HCl, 0.1 M NaOH and 3.5 w% NaCl solutions, respectively. The enhancement of corrosion resistance for MAO/M16 composite coating was achieved by a unique synergy between the microarc oxidation layer and the corrosion inhibitor. The composite coating indicates its promising applications in acid, alkaline and salt solutions environments and other harsh environments.
An anticorrosive composite coating with enhanced corrosion resistance in acid, alkaline and salt solutions was fabricated by compounding micro- and nanoporous inorganic structure and organic corrosion inhibitor, which was used to improve the corrosion resistance of amphoteric metal and its oxides in various corrosive medium. Micro- and nanoporous structure was prepared by microarc oxidation (MAO) coatings on 2024 aluminium alloy, which was used both as the inorganic anticorrosion coating and the container for organic corrosion inhibitor (M16). Electrochemical impedance spectroscopy, Tafel plots and salt spray resistance were measured to research the anticorrosion performance of the MAO/M16 composite coating. Enhanced corrosion resistance was observed for the MAO/M16 coating compared to the MAO by itself. When the concentration of corrosion inhibitor M16 is at 2 w%, the best anticorrosive properties of the composite coating were obtained. Moreover, the MAO/M16 composite coating showed better corrosion-resistant performance than pure MAO coating and Al alloy substrate in the corrosion environment of 1 M HCl, 0.1 M NaOH and 3.5 w% NaCl solutions, respectively. The enhancement of corrosion resistance for MAO/M16 composite coating was achieved by a unique synergy between the microarc oxidation layer and the corrosion inhibitor. The composite coating indicates its promising applications in acid, alkaline and salt solutions environments and other harsh environments.An anticorrosive composite coating with enhanced corrosion resistance in acid, alkaline and salt solutions was fabricated by compounding micro- and nanoporous inorganic structure and organic corrosion inhibitor, which was used to improve the corrosion resistance of amphoteric metal and its oxides in various corrosive medium. Micro- and nanoporous structure was prepared by microarc oxidation (MAO) coatings on 2024 aluminium alloy, which was used both as the inorganic anticorrosion coating and the container for organic corrosion inhibitor (M16). Electrochemical impedance spectroscopy, Tafel plots and salt spray resistance were measured to research the anticorrosion performance of the MAO/M16 composite coating. Enhanced corrosion resistance was observed for the MAO/M16 coating compared to the MAO by itself. When the concentration of corrosion inhibitor M16 is at 2 w%, the best anticorrosive properties of the composite coating were obtained. Moreover, the MAO/M16 composite coating showed better corrosion-resistant performance than pure MAO coating and Al alloy substrate in the corrosion environment of 1 M HCl, 0.1 M NaOH and 3.5 w% NaCl solutions, respectively. The enhancement of corrosion resistance for MAO/M16 composite coating was achieved by a unique synergy between the microarc oxidation layer and the corrosion inhibitor. The composite coating indicates its promising applications in acid, alkaline and salt solutions environments and other harsh environments.
Author Chen, Shougang
Cui, Siwen
Yu, Qiangliang
Wang, Daoai
Li, Tinghua
Sun, Weixiang
Liu, Yupeng
Author_xml – sequence: 1
  givenname: Weixiang
  surname: Sun
  fullname: Sun, Weixiang
  organization: State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China
– sequence: 2
  givenname: Yupeng
  surname: Liu
  fullname: Liu, Yupeng
  organization: State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China
– sequence: 3
  givenname: Tinghua
  surname: Li
  fullname: Li, Tinghua
  organization: Technical Center of China Tobacco Yunnan Industrial Co., Ltd., Kunming 650231, China
– sequence: 4
  givenname: Siwen
  surname: Cui
  fullname: Cui, Siwen
  organization: State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China
– sequence: 5
  givenname: Shougang
  orcidid: 0000-0002-0059-5708
  surname: Chen
  fullname: Chen, Shougang
  organization: Institute of Materials Science and Engineering, Ocean University of China, Qingdao 266100, China
– sequence: 6
  givenname: Qiangliang
  surname: Yu
  fullname: Yu, Qiangliang
  organization: State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China
– sequence: 7
  givenname: Daoai
  surname: Wang
  fullname: Wang, Daoai
  email: wangda@licp.cas.cn
  organization: State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China
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Keywords Microarc oxidation
Composite coating
Corrosion inhibitor
Amphoteric anticorrosion
Language English
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Snippet [Display omitted] An anticorrosive composite coating with enhanced corrosion resistance in acid, alkaline and salt solutions was fabricated by compounding...
An anticorrosive composite coating with enhanced corrosion resistance in acid, alkaline and salt solutions was fabricated by compounding micro- and nanoporous...
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SubjectTerms aluminum
aluminum alloys
Amphoteric anticorrosion
coatings
Composite coating
corrosion
Corrosion inhibitor
dielectric spectroscopy
hydrochloric acid
Microarc oxidation
nanopores
oxidation
oxides
sodium chloride
sodium hydroxide
Title Anti-corrosion of amphoteric metal enhanced by MAO/corrosion inhibitor composite in acid, alkaline and salt solutions
URI https://dx.doi.org/10.1016/j.jcis.2019.07.035
https://www.ncbi.nlm.nih.gov/pubmed/31326782
https://www.proquest.com/docview/2261968623
https://www.proquest.com/docview/2286851098
Volume 554
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