Preparation of core–shell magnetic ion-imprinted polymer for selective extraction of Pb(II) from environmental samples

► Solid phase extraction combined with magnetic ion-imprinted sorbents was used for selective extraction of Pb(II). ► A core–shell magnetic imprinted polymer based on magnetic Fe 3O 4 was synthesized. ► 3-(2-Aminoethylamino)propyltrimethoxysilane was employed as functional monomers in the preparatio...

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Published inChemical engineering journal (Lausanne, Switzerland : 1996) Vol. 178; pp. 443 - 450
Main Authors Zhang, Minglei, Zhang, Zhaohui, Liu, Yunan, Yang, Xiao, Luo, Lijuan, Chen, Jutao, Yao, Shouzhuo
Format Journal Article
LanguageEnglish
Published Oxford Elsevier B.V 15.12.2011
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Abstract ► Solid phase extraction combined with magnetic ion-imprinted sorbents was used for selective extraction of Pb(II). ► A core–shell magnetic imprinted polymer based on magnetic Fe 3O 4 was synthesized. ► 3-(2-Aminoethylamino)propyltrimethoxysilane was employed as functional monomers in the preparation process of Pb(II) ion-imprinted polymer. A novel magnetic ion-imprinted polymer (Fe 3O 4@SiO 2@IIP) was synthesized by using 3-(2-aminoethylamino)propyltrimethoxysilane (AAPTS) as the functional monomer, tetraethylorthosilicate (TEOS) as the cross-linker and Pb(II) as the template and evaluated for selective extraction of Pb(II) from environmental sample by magnetic solid phase extraction (M-SPE) procedure. The factors affecting separation and preconcentration of the target heavy metals involving pH, eluting solvent and sample volume were studied in detail. Under the optimized experimental conditions, the kinetics adsorption and adsorption capacity of the Fe 3O 4@SiO 2@IIP toward Pb(II) were estimated. The results indicated that the adsorption mechanism is corresponding with the second-order adsorption process with correlation coefficient ( r 2 = 0.990), and the maximum adsorption capacity is 19.61 mg g −1. The relative selectivity factor ( β) values of Pb(II)/Cu(II), Pb(II)/Zn(II), Pb(II)/Cd(II) and Pb(II)/Hg(II) are 7.41, 6.76, 3.75 and 6.39, respectively. The Fe 3O 4@SiO 2@IIP was applied for extracting and detecting of Pb(II) in real environmental samples combined with atomic adsorption spectrometer successfully with high recoveries of 98.0%.
AbstractList A novel magnetic ion-imprinted polymer (Fe sub(3O) sub(4)iO sub(2)IIP) was synthesized by using 3-(2-aminoethylamino)propyltrimethoxysilane (AAPTS) as the functional monomer, tetraethylorthosilicate (TEOS) as the cross-linker and Pb(II) as the template and evaluated for selective extraction of Pb(II) from environmental sample by magnetic solid phase extraction (M-SPE) procedure. The factors affecting separation and preconcentration of the target heavy metals involving pH, eluting solvent and sample volume were studied in detail. Under the optimized experimental conditions, the kinetics adsorption and adsorption capacity of the Fe sub(3O) sub(4)iO sub(2)IIP toward Pb(II) were estimated. The results indicated that the adsorption mechanism is corresponding with the second-order adsorption process with correlation coefficient (r super(2 = 0.990), and the maximum adsorption capacity is 19.61 mg g) super(-)1. The relative selectivity factor ( beta ) values of Pb(II)/Cu(II), Pb(II)/Zn(II), Pb(II)/Cd(II) and Pb(II)/Hg(II) are 7.41, 6.76, 3.75 and 6.39, respectively. The Fe sub(3O) sub(4)iO sub(2)IIP was applied for extracting and detecting of Pb(II) in real environmental samples combined with atomic adsorption spectrometer successfully with high recoveries of 98.0%.
► Solid phase extraction combined with magnetic ion-imprinted sorbents was used for selective extraction of Pb(II). ► A core–shell magnetic imprinted polymer based on magnetic Fe 3O 4 was synthesized. ► 3-(2-Aminoethylamino)propyltrimethoxysilane was employed as functional monomers in the preparation process of Pb(II) ion-imprinted polymer. A novel magnetic ion-imprinted polymer (Fe 3O 4@SiO 2@IIP) was synthesized by using 3-(2-aminoethylamino)propyltrimethoxysilane (AAPTS) as the functional monomer, tetraethylorthosilicate (TEOS) as the cross-linker and Pb(II) as the template and evaluated for selective extraction of Pb(II) from environmental sample by magnetic solid phase extraction (M-SPE) procedure. The factors affecting separation and preconcentration of the target heavy metals involving pH, eluting solvent and sample volume were studied in detail. Under the optimized experimental conditions, the kinetics adsorption and adsorption capacity of the Fe 3O 4@SiO 2@IIP toward Pb(II) were estimated. The results indicated that the adsorption mechanism is corresponding with the second-order adsorption process with correlation coefficient ( r 2 = 0.990), and the maximum adsorption capacity is 19.61 mg g −1. The relative selectivity factor ( β) values of Pb(II)/Cu(II), Pb(II)/Zn(II), Pb(II)/Cd(II) and Pb(II)/Hg(II) are 7.41, 6.76, 3.75 and 6.39, respectively. The Fe 3O 4@SiO 2@IIP was applied for extracting and detecting of Pb(II) in real environmental samples combined with atomic adsorption spectrometer successfully with high recoveries of 98.0%.
A novel magnetic ion-imprinted polymer (Fe₃O₄@SiO₂@IIP) was synthesized by using 3-(2-aminoethylamino)propyltrimethoxysilane (AAPTS) as the functional monomer, tetraethylorthosilicate (TEOS) as the cross-linker and Pb(II) as the template and evaluated for selective extraction of Pb(II) from environmental sample by magnetic solid phase extraction (M-SPE) procedure. The factors affecting separation and preconcentration of the target heavy metals involving pH, eluting solvent and sample volume were studied in detail. Under the optimized experimental conditions, the kinetics adsorption and adsorption capacity of the Fe₃O₄@SiO₂@IIP toward Pb(II) were estimated. The results indicated that the adsorption mechanism is corresponding with the second-order adsorption process with correlation coefficient (r²=0.990), and the maximum adsorption capacity is 19.61mgg⁻¹. The relative selectivity factor (β) values of Pb(II)/Cu(II), Pb(II)/Zn(II), Pb(II)/Cd(II) and Pb(II)/Hg(II) are 7.41, 6.76, 3.75 and 6.39, respectively. The Fe₃O₄@SiO₂@IIP was applied for extracting and detecting of Pb(II) in real environmental samples combined with atomic adsorption spectrometer successfully with high recoveries of 98.0%.
Author Zhang, Zhaohui
Liu, Yunan
Zhang, Minglei
Luo, Lijuan
Chen, Jutao
Yang, Xiao
Yao, Shouzhuo
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  givenname: Zhaohui
  surname: Zhang
  fullname: Zhang, Zhaohui
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  organization: College of Chemistry and Chemical Engineering, Jishou University, Jishou 416000, China
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  givenname: Yunan
  surname: Liu
  fullname: Liu, Yunan
  organization: College of Chemistry and Chemical Engineering, Jishou University, Jishou 416000, China
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  givenname: Xiao
  surname: Yang
  fullname: Yang, Xiao
  organization: College of Chemistry and Chemical Engineering, Jishou University, Jishou 416000, China
– sequence: 5
  givenname: Lijuan
  surname: Luo
  fullname: Luo, Lijuan
  organization: College of Chemistry and Chemical Engineering, Jishou University, Jishou 416000, China
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  surname: Chen
  fullname: Chen, Jutao
  organization: College of Chemistry and Chemical Engineering, Jishou University, Jishou 416000, China
– sequence: 7
  givenname: Shouzhuo
  surname: Yao
  fullname: Yao, Shouzhuo
  organization: State Key Laboratory of Chemo/Biosensing and Chemometrics, Hunan University, Changsha 410082, China
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Keywords Pb(II)
Core–shell
M-SPE
Fe 3O 4@SiO 2@IIP
Correlation coefficient
Selective extraction
Solid phase extraction
Second order
Fe3O4@SiO2@IIP
Adsorption capacity
Core-shell
Operating conditions
Heavy metal
Adsorption
Preparation
Preconcentration
pH
Kinetics
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SSID ssj0006919
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Snippet ► Solid phase extraction combined with magnetic ion-imprinted sorbents was used for selective extraction of Pb(II). ► A core–shell magnetic imprinted polymer...
A novel magnetic ion-imprinted polymer (Fe sub(3O) sub(4)iO sub(2)IIP) was synthesized by using 3-(2-aminoethylamino)propyltrimethoxysilane (AAPTS) as the...
A novel magnetic ion-imprinted polymer (Fe₃O₄@SiO₂@IIP) was synthesized by using 3-(2-aminoethylamino)propyltrimethoxysilane (AAPTS) as the functional monomer,...
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SubjectTerms Adsorption
Applied sciences
Chemical engineering
Core–shell
correlation
Crosslinking
Exact sciences and technology
Extraction
Fe 3O 4@SiO 2@IIP
Heavy metals
M-SPE
Monomers
Pb(II)
polymers
solid phase extraction
Solid phases
Solvents
Title Preparation of core–shell magnetic ion-imprinted polymer for selective extraction of Pb(II) from environmental samples
URI https://dx.doi.org/10.1016/j.cej.2011.10.035
https://www.proquest.com/docview/1010876633
https://www.proquest.com/docview/1663610792
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