Preparation of core–shell magnetic ion-imprinted polymer for selective extraction of Pb(II) from environmental samples
► Solid phase extraction combined with magnetic ion-imprinted sorbents was used for selective extraction of Pb(II). ► A core–shell magnetic imprinted polymer based on magnetic Fe 3O 4 was synthesized. ► 3-(2-Aminoethylamino)propyltrimethoxysilane was employed as functional monomers in the preparatio...
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Published in | Chemical engineering journal (Lausanne, Switzerland : 1996) Vol. 178; pp. 443 - 450 |
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Main Authors | , , , , , , |
Format | Journal Article |
Language | English |
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Oxford
Elsevier B.V
15.12.2011
Elsevier |
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Abstract | ► Solid phase extraction combined with magnetic ion-imprinted sorbents was used for selective extraction of Pb(II). ► A core–shell magnetic imprinted polymer based on magnetic Fe
3O
4 was synthesized. ► 3-(2-Aminoethylamino)propyltrimethoxysilane was employed as functional monomers in the preparation process of Pb(II) ion-imprinted polymer.
A novel magnetic ion-imprinted polymer (Fe
3O
4@SiO
2@IIP) was synthesized by using 3-(2-aminoethylamino)propyltrimethoxysilane (AAPTS) as the functional monomer, tetraethylorthosilicate (TEOS) as the cross-linker and Pb(II) as the template and evaluated for selective extraction of Pb(II) from environmental sample by magnetic solid phase extraction (M-SPE) procedure. The factors affecting separation and preconcentration of the target heavy metals involving pH, eluting solvent and sample volume were studied in detail. Under the optimized experimental conditions, the kinetics adsorption and adsorption capacity of the Fe
3O
4@SiO
2@IIP toward Pb(II) were estimated. The results indicated that the adsorption mechanism is corresponding with the second-order adsorption process with correlation coefficient (
r
2
=
0.990), and the maximum adsorption capacity is 19.61
mg
g
−1. The relative selectivity factor (
β) values of Pb(II)/Cu(II), Pb(II)/Zn(II), Pb(II)/Cd(II) and Pb(II)/Hg(II) are 7.41, 6.76, 3.75 and 6.39, respectively. The Fe
3O
4@SiO
2@IIP was applied for extracting and detecting of Pb(II) in real environmental samples combined with atomic adsorption spectrometer successfully with high recoveries of 98.0%. |
---|---|
AbstractList | A novel magnetic ion-imprinted polymer (Fe sub(3O) sub(4)iO sub(2)IIP) was synthesized by using 3-(2-aminoethylamino)propyltrimethoxysilane (AAPTS) as the functional monomer, tetraethylorthosilicate (TEOS) as the cross-linker and Pb(II) as the template and evaluated for selective extraction of Pb(II) from environmental sample by magnetic solid phase extraction (M-SPE) procedure. The factors affecting separation and preconcentration of the target heavy metals involving pH, eluting solvent and sample volume were studied in detail. Under the optimized experimental conditions, the kinetics adsorption and adsorption capacity of the Fe sub(3O) sub(4)iO sub(2)IIP toward Pb(II) were estimated. The results indicated that the adsorption mechanism is corresponding with the second-order adsorption process with correlation coefficient (r super(2 = 0.990), and the maximum adsorption capacity is 19.61 mg g) super(-)1. The relative selectivity factor ( beta ) values of Pb(II)/Cu(II), Pb(II)/Zn(II), Pb(II)/Cd(II) and Pb(II)/Hg(II) are 7.41, 6.76, 3.75 and 6.39, respectively. The Fe sub(3O) sub(4)iO sub(2)IIP was applied for extracting and detecting of Pb(II) in real environmental samples combined with atomic adsorption spectrometer successfully with high recoveries of 98.0%. ► Solid phase extraction combined with magnetic ion-imprinted sorbents was used for selective extraction of Pb(II). ► A core–shell magnetic imprinted polymer based on magnetic Fe 3O 4 was synthesized. ► 3-(2-Aminoethylamino)propyltrimethoxysilane was employed as functional monomers in the preparation process of Pb(II) ion-imprinted polymer. A novel magnetic ion-imprinted polymer (Fe 3O 4@SiO 2@IIP) was synthesized by using 3-(2-aminoethylamino)propyltrimethoxysilane (AAPTS) as the functional monomer, tetraethylorthosilicate (TEOS) as the cross-linker and Pb(II) as the template and evaluated for selective extraction of Pb(II) from environmental sample by magnetic solid phase extraction (M-SPE) procedure. The factors affecting separation and preconcentration of the target heavy metals involving pH, eluting solvent and sample volume were studied in detail. Under the optimized experimental conditions, the kinetics adsorption and adsorption capacity of the Fe 3O 4@SiO 2@IIP toward Pb(II) were estimated. The results indicated that the adsorption mechanism is corresponding with the second-order adsorption process with correlation coefficient ( r 2 = 0.990), and the maximum adsorption capacity is 19.61 mg g −1. The relative selectivity factor ( β) values of Pb(II)/Cu(II), Pb(II)/Zn(II), Pb(II)/Cd(II) and Pb(II)/Hg(II) are 7.41, 6.76, 3.75 and 6.39, respectively. The Fe 3O 4@SiO 2@IIP was applied for extracting and detecting of Pb(II) in real environmental samples combined with atomic adsorption spectrometer successfully with high recoveries of 98.0%. A novel magnetic ion-imprinted polymer (Fe₃O₄@SiO₂@IIP) was synthesized by using 3-(2-aminoethylamino)propyltrimethoxysilane (AAPTS) as the functional monomer, tetraethylorthosilicate (TEOS) as the cross-linker and Pb(II) as the template and evaluated for selective extraction of Pb(II) from environmental sample by magnetic solid phase extraction (M-SPE) procedure. The factors affecting separation and preconcentration of the target heavy metals involving pH, eluting solvent and sample volume were studied in detail. Under the optimized experimental conditions, the kinetics adsorption and adsorption capacity of the Fe₃O₄@SiO₂@IIP toward Pb(II) were estimated. The results indicated that the adsorption mechanism is corresponding with the second-order adsorption process with correlation coefficient (r²=0.990), and the maximum adsorption capacity is 19.61mgg⁻¹. The relative selectivity factor (β) values of Pb(II)/Cu(II), Pb(II)/Zn(II), Pb(II)/Cd(II) and Pb(II)/Hg(II) are 7.41, 6.76, 3.75 and 6.39, respectively. The Fe₃O₄@SiO₂@IIP was applied for extracting and detecting of Pb(II) in real environmental samples combined with atomic adsorption spectrometer successfully with high recoveries of 98.0%. |
Author | Zhang, Zhaohui Liu, Yunan Zhang, Minglei Luo, Lijuan Chen, Jutao Yang, Xiao Yao, Shouzhuo |
Author_xml | – sequence: 1 givenname: Minglei surname: Zhang fullname: Zhang, Minglei organization: College of Chemistry and Chemical Engineering, Jishou University, Jishou 416000, China – sequence: 2 givenname: Zhaohui surname: Zhang fullname: Zhang, Zhaohui email: zhaohuizhang77@163.com organization: College of Chemistry and Chemical Engineering, Jishou University, Jishou 416000, China – sequence: 3 givenname: Yunan surname: Liu fullname: Liu, Yunan organization: College of Chemistry and Chemical Engineering, Jishou University, Jishou 416000, China – sequence: 4 givenname: Xiao surname: Yang fullname: Yang, Xiao organization: College of Chemistry and Chemical Engineering, Jishou University, Jishou 416000, China – sequence: 5 givenname: Lijuan surname: Luo fullname: Luo, Lijuan organization: College of Chemistry and Chemical Engineering, Jishou University, Jishou 416000, China – sequence: 6 givenname: Jutao surname: Chen fullname: Chen, Jutao organization: College of Chemistry and Chemical Engineering, Jishou University, Jishou 416000, China – sequence: 7 givenname: Shouzhuo surname: Yao fullname: Yao, Shouzhuo organization: State Key Laboratory of Chemo/Biosensing and Chemometrics, Hunan University, Changsha 410082, China |
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Keywords | Pb(II) Core–shell M-SPE Fe 3O 4@SiO 2@IIP Correlation coefficient Selective extraction Solid phase extraction Second order Fe3O4@SiO2@IIP Adsorption capacity Core-shell Operating conditions Heavy metal Adsorption Preparation Preconcentration pH Kinetics |
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Snippet | ► Solid phase extraction combined with magnetic ion-imprinted sorbents was used for selective extraction of Pb(II). ► A core–shell magnetic imprinted polymer... A novel magnetic ion-imprinted polymer (Fe sub(3O) sub(4)iO sub(2)IIP) was synthesized by using 3-(2-aminoethylamino)propyltrimethoxysilane (AAPTS) as the... A novel magnetic ion-imprinted polymer (Fe₃O₄@SiO₂@IIP) was synthesized by using 3-(2-aminoethylamino)propyltrimethoxysilane (AAPTS) as the functional monomer,... |
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SubjectTerms | Adsorption Applied sciences Chemical engineering Core–shell correlation Crosslinking Exact sciences and technology Extraction Fe 3O 4@SiO 2@IIP Heavy metals M-SPE Monomers Pb(II) polymers solid phase extraction Solid phases Solvents |
Title | Preparation of core–shell magnetic ion-imprinted polymer for selective extraction of Pb(II) from environmental samples |
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