Accelerated crystallization of zeolites via hydroxyl free radicals
In the hydrothermal crystallization of zeolites from basic media, hydroxide ions (OH⁻) catalyze the depolymerization of the aluminosilicate gel by breaking the Si,AI–O–Si,AI bonds and catalyze the polymerization of the aluminosilicate anions around the hydrated cation species by remaking the Si,AI–O...
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| Published in | Science (American Association for the Advancement of Science) Vol. 351; no. 6278; pp. 1188 - 1191 |
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| Main Authors | , , , , , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
United States
American Association for the Advancement of Science
11.03.2016
The American Association for the Advancement of Science |
| Subjects | |
| Online Access | Get full text |
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| Abstract | In the hydrothermal crystallization of zeolites from basic media, hydroxide ions (OH⁻) catalyze the depolymerization of the aluminosilicate gel by breaking the Si,AI–O–Si,AI bonds and catalyze the polymerization of the aluminosilicate anions around the hydrated cation species by remaking the Si,AI–O–Si,AI bonds. We report that hydroxyl free radicals (•OH) are involved in the zeolite crystallization under hydrothermal conditions. The crystallization processes of zeolites—such as Na–A, Na–X, NaZ–21, and silicalite-1—can be accelerated with hydroxyl free radicals generated by ultraviolet irradiation or Fenton's reagent. |
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| AbstractList | In the hydrothermal crystallization of zeolites from basic media, hydroxide ions (OH(-)) catalyze the depolymerization of the aluminosilicate gel by breaking the Si,Al-O-Si,Al bonds and catalyze the polymerization of the aluminosilicate anions around the hydrated cation species by remaking the Si,Al-O-Si,Al bonds. We report that hydroxyl free radicals (•OH) are involved in the zeolite crystallization under hydrothermal conditions. The crystallization processes of zeolites-such as Na-A, Na-X, NaZ-21, and silicalite-1-can be accelerated with hydroxyl free radicals generated by ultraviolet irradiation or Fenton's reagent.In the hydrothermal crystallization of zeolites from basic media, hydroxide ions (OH(-)) catalyze the depolymerization of the aluminosilicate gel by breaking the Si,Al-O-Si,Al bonds and catalyze the polymerization of the aluminosilicate anions around the hydrated cation species by remaking the Si,Al-O-Si,Al bonds. We report that hydroxyl free radicals (•OH) are involved in the zeolite crystallization under hydrothermal conditions. The crystallization processes of zeolites-such as Na-A, Na-X, NaZ-21, and silicalite-1-can be accelerated with hydroxyl free radicals generated by ultraviolet irradiation or Fenton's reagent. Zeolite synthesis normally proceeds under basic conditions that allow the oxide bridges between aluminum and silicon atoms to break and reform. Feng et al. show that the formation of hydroxyl radicals, either by irradiation with ultraviolet light or with the Fenton reagent, can speed up the formation of the crystallized zeolite by about a factor of 2. Science, this issue p. 1188 In the hydrothermal crystallization of zeolites from basic media, hydroxide ions (OH-) catalyze the depolymerization of the aluminosilicate gel by breaking the Si,Al-O-Si,Al bonds and catalyze the polymerization of the aluminosilicate anions around the hydrated cation species by remaking the Si,Al-O-Si,Al bonds. We report that hydroxyl free radicals (*OH) are involved in the zeolite crystallization under hydrothermal conditions. The crystallization processes of zeolites--such as Na-A, Na-X, NaZ-21, and silicalite-1--can be accelerated with hydroxyl free radicals generated by ultraviolet irradiation or Fenton's reagent. In the hydrothermal crystallization of zeolites from basic media, hydroxide ions (OH⁻) catalyze the depolymerization of the aluminosilicate gel by breaking the Si,AI–O–Si,AI bonds and catalyze the polymerization of the aluminosilicate anions around the hydrated cation species by remaking the Si,AI–O–Si,AI bonds. We report that hydroxyl free radicals (•OH) are involved in the zeolite crystallization under hydrothermal conditions. The crystallization processes of zeolites—such as Na–A, Na–X, NaZ–21, and silicalite-1—can be accelerated with hydroxyl free radicals generated by ultraviolet irradiation or Fenton's reagent. In the hydrothermal crystallization of zeolites from basic media, hydroxide ions (OH(-)) catalyze the depolymerization of the aluminosilicate gel by breaking the Si,Al-O-Si,Al bonds and catalyze the polymerization of the aluminosilicate anions around the hydrated cation species by remaking the Si,Al-O-Si,Al bonds. We report that hydroxyl free radicals (•OH) are involved in the zeolite crystallization under hydrothermal conditions. The crystallization processes of zeolites-such as Na-A, Na-X, NaZ-21, and silicalite-1-can be accelerated with hydroxyl free radicals generated by ultraviolet irradiation or Fenton's reagent. Zeolite synthesis normally proceeds under basic conditions that allow the oxide bridges between aluminum and silicon atoms to break and reform. Feng et al. show that the formation of hydroxyl radicals, either by irradiation with ultraviolet light or with the Fenton reagent, can speed up the formation of the crystallized zeolite by about a factor of 2. Science , this issue p. 1188 Hydroxyl radicals generated with ultraviolet light or Fenton reagents can approximately double the rate of zeolite synthesis. In the hydrothermal crystallization of zeolites from basic media, hydroxide ions (OH – ) catalyze the depolymerization of the aluminosilicate gel by breaking the Si,Al–O–Si,Al bonds and catalyze the polymerization of the aluminosilicate anions around the hydrated cation species by remaking the Si,Al–O–Si,Al bonds. We report that hydroxyl free radicals (•OH) are involved in the zeolite crystallization under hydrothermal conditions. The crystallization processes of zeolites—such as Na–A, Na–X, NaZ–21, and silicalite-1—can be accelerated with hydroxyl free radicals generated by ultraviolet irradiation or Fenton’s reagent. |
| Author | Xu, Ruren Li, Xu Corma, Avelino Yu, Jihong Feng, Guodong Cheng, Peng Wang, Jianyu Yan, Wenfu Su, Ji-Hu Li, Yi Boronat, Mercedes |
| Author_xml | – sequence: 1 givenname: Guodong surname: Feng fullname: Feng, Guodong – sequence: 2 givenname: Peng surname: Cheng fullname: Cheng, Peng – sequence: 3 givenname: Wenfu surname: Yan fullname: Yan, Wenfu – sequence: 4 givenname: Mercedes surname: Boronat fullname: Boronat, Mercedes – sequence: 5 givenname: Xu surname: Li fullname: Li, Xu – sequence: 6 givenname: Ji-Hu surname: Su fullname: Su, Ji-Hu – sequence: 7 givenname: Jianyu surname: Wang fullname: Wang, Jianyu – sequence: 8 givenname: Yi surname: Li fullname: Li, Yi – sequence: 9 givenname: Avelino surname: Corma fullname: Corma, Avelino – sequence: 10 givenname: Ruren surname: Xu fullname: Xu, Ruren – sequence: 11 givenname: Jihong surname: Yu fullname: Yu, Jihong |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/26965626$$D View this record in MEDLINE/PubMed |
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| Cites_doi | 10.1016/0022-3093(91)90130-X 10.1063/1.464913 10.1002/9783527630295 10.1002/anie.200702986 10.1021/cr0682047 10.1126/science.1250984 10.1021/cr020060i 10.1063/1.460447 10.1016/j.micromeso.2005.02.016 10.1093/oso/9780198502418.001.0001 10.1016/S0022-3093(87)80047-9 10.1021/cr500010r 10.1016/B978-008044288-4/50028-5 10.1016/0016-7037(96)00101-9 10.1021/ct700248k 10.1021/ja304907c 10.1021/jp010752v 10.1016/S0891-5849(87)80033-3 10.1039/c3cc42732c |
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| Snippet | In the hydrothermal crystallization of zeolites from basic media, hydroxide ions (OH⁻) catalyze the depolymerization of the aluminosilicate gel by breaking the... Zeolite synthesis normally proceeds under basic conditions that allow the oxide bridges between aluminum and silicon atoms to break and reform. Feng et al.... In the hydrothermal crystallization of zeolites from basic media, hydroxide ions (OH(-)) catalyze the depolymerization of the aluminosilicate gel by breaking... Zeolite synthesis normally proceeds under basic conditions that allow the oxide bridges between aluminum and silicon atoms to break and reform. Feng et al.... |
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| Title | Accelerated crystallization of zeolites via hydroxyl free radicals |
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