Using alkaline-earth metal ions to tune structural variations of 1,3,5-benzenetricarboxylate coordination polymers

• Published in: Dalton transactions : an international journal of inorganic chemistry Vol. 42; no. 6; pp. 2294 - 2301
• Main Authors: Zhang, Xin, Huang, Yuan-Yuan, Lin, Qi-Pu, Zhang, Jian, Yao, Yuan-Gen
• Format: Journal Article
• Language: English
• Published: England 01.01.2013
• Subjects: Cadmium; Chains; Corners; Hydrates; Metal ions; Polyhedrons; Three dimensional; X-rays
• ISSN: 1477-9226; 1477-9234; 1477-9234
• DOI: 10.1039/C2DT31536J

Alkaline-earth metal ions were used to tune four new heterometallic frameworks, {[Cd(2.07)Mg(0.93)(BTC)(2)(H(2)O)(4)]·2H(2)O}(n) (1), {[Cd(2)Ca(BTC)(2)(H(2)O)(4)]·2H(2)O}(n) (2), {[Cd(2)Sr(BTC)(2)(H(2)O)(5)]·H(2)O}(n) (3) and [Cd(6)Ba(3)(BTC)(3)(H(2)O)(10)](n) (4) (H(3)BTC = 1,3,5-benzenetricarboxyl...