Cycloaddition reactions of enoldiazo compounds

• Published in: Chemical Society reviews Vol. 46; no. 17; pp. 5425 - 5443
• Main Authors: Cheng, Qing-Qing, Deng, Yongming, Lankelma, Marianne, Doyle, Michael P
• Format: Journal Article
• Language: English
• Published: England 29.08.2017
• Subjects: amides; catalysts; copper; cycloaddition reactions; diazo compounds; enols; esters; extrusion; moieties; nitrogen

Enoldiazo esters and amides have proven to be versatile reagents for cycloaddition reactions that allow highly efficient construction of various carbocycles and heterocycles. Their versatility is exemplified by (1) [2+ n ]-cycloadditions ( n = 3, 4) by the enol silyl ether units of enoldiazo compoun...