High Li-ion conductivity of Al-doped Li7La3Zr2O12 synthesized by solid-state reaction
Li7La3Zr2O12 (LLZO) has cubic garnet type structure and is a promising solid electrolyte for next-generation Li-ion batteries. In this work, Al-doped LLZO was prepared via conventional solid-state reaction. The effects of sintering temperature and Al doping content on the structure and Li-ion conduc...
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| Published in | Ceramics international Vol. 42; no. 10; pp. 12156 - 12160 |
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| Main Authors | , , , , , |
| Format | Journal Article |
| Language | English |
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Elsevier Ltd
01.08.2016
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| Subjects | |
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| Abstract | Li7La3Zr2O12 (LLZO) has cubic garnet type structure and is a promising solid electrolyte for next-generation Li-ion batteries. In this work, Al-doped LLZO was prepared via conventional solid-state reaction. The effects of sintering temperature and Al doping content on the structure and Li-ion conductivity of LLZO were investigated. The phase composition of the products was confirmed to be cubic LLZO via XRD. The morphology and chemical composition of calcined powders were investigated with SEM, EDS, and TEM. The Li-ion conductivity was measured by AC impedance. The results indicated the optimum sintering temperature range is 800–950°C, the appropriate molar ratio of LiOH·H2O, La(OH)3, ZrO2 and Al2O3 is 7.7:3:2:(0.2–0.4), and the Li-ion conductivity of LLZO sintered at 900°C with 0.3mol of Al-doped was 2.11×10−4Scm−1 at 25°C. |
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| AbstractList | Li7La3Zr2O12 (LLZO) has cubic garnet type structure and is a promising solid electrolyte for next-generation Li-ion batteries. In this work, Al-doped LLZO was prepared via conventional solid-state reaction. The effects of sintering temperature and Al doping content on the structure and Li-ion conductivity of LLZO were investigated. The phase composition of the products was confirmed to be cubic LLZO via XRD. The morphology and chemical composition of calcined powders were investigated with SEM, EDS, and TEM. The Li-ion conductivity was measured by AC impedance. The results indicated the optimum sintering temperature range is 800–950°C, the appropriate molar ratio of LiOH·H2O, La(OH)3, ZrO2 and Al2O3 is 7.7:3:2:(0.2–0.4), and the Li-ion conductivity of LLZO sintered at 900°C with 0.3mol of Al-doped was 2.11×10−4Scm−1 at 25°C. |
| Author | Su, Yongyao Hu, Zhongli Ruan, Haibo Hu, Rong Liu, Hongdong Zhang, Lei |
| Author_xml | – sequence: 1 givenname: Zhongli surname: Hu fullname: Hu, Zhongli organization: Research Institute for New Materials Technology, Chongqing University of Arts and Sciences, Chongqing 402160, PR China – sequence: 2 givenname: Hongdong surname: Liu fullname: Liu, Hongdong email: lhd0415@126.com organization: Research Institute for New Materials Technology, Chongqing University of Arts and Sciences, Chongqing 402160, PR China – sequence: 3 givenname: Haibo surname: Ruan fullname: Ruan, Haibo organization: Research Institute for New Materials Technology, Chongqing University of Arts and Sciences, Chongqing 402160, PR China – sequence: 4 givenname: Rong surname: Hu fullname: Hu, Rong organization: Research Institute for New Materials Technology, Chongqing University of Arts and Sciences, Chongqing 402160, PR China – sequence: 5 givenname: Yongyao surname: Su fullname: Su, Yongyao organization: Research Institute for New Materials Technology, Chongqing University of Arts and Sciences, Chongqing 402160, PR China – sequence: 6 givenname: Lei surname: Zhang fullname: Zhang, Lei email: leizhang0215@126.com organization: College of Life Science, Chongqing Normal University, Chongqing 401331, PR China |
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| Snippet | Li7La3Zr2O12 (LLZO) has cubic garnet type structure and is a promising solid electrolyte for next-generation Li-ion batteries. In this work, Al-doped LLZO was... |
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| SubjectTerms | Al-doped content Li-ion conductivity Li7La3Zr2O12 Sintering temperature |
| Title | High Li-ion conductivity of Al-doped Li7La3Zr2O12 synthesized by solid-state reaction |
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