Reactive elastomeric composites: When rubber meets cement
This paper describes a novel reactive composite material comprised of hydrogenated nitrile butadiene rubber (HNBR) compounded with slag cement. The composite initially looks and behaves like rubber, but when exposed to water it simultaneously swells and stiffens due to hydration of the cement compon...
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Published in | Composites science and technology Vol. 75; pp. 77 - 83 |
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Main Authors | , , , , , , , |
Format | Journal Article |
Language | English |
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11.02.2013
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Abstract | This paper describes a novel reactive composite material comprised of hydrogenated nitrile butadiene rubber (HNBR) compounded with slag cement. The composite initially looks and behaves like rubber, but when exposed to water it simultaneously swells and stiffens due to hydration of the cement component. The material eventually reaches a stiffness that is intermediate between that of HNBR and hydrated cement, while maintaining a relatively large ductility that is more characteristic of rubber. This behavior, which is ideal for sealing applications, differentiates this material from conventional swellable materials that become less stiff upon swelling. The development of this new type of material was motivated by the requirements of oilfield zonal isolation, where alternatives to cement are needed for some challenging sealing applications. A mechanism for the swelling and stiffening of the reactive composite is proposed: water diffuses into the HNBR matrix and is converted to bound water through hydration reactions with the cement, causing the effective solid filler content of the composite to increase. A model is proposed that treats the composite as a cellular solid with a continuous filler phase (hydrated cement). This model is able to reproduce the observed increase in the elastic modulus with time during exposure to water. |
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AbstractList | This paper describes a novel reactive composite material comprised of hydrogenated nitrile butadiene rubber (HNBR) compounded with slag cement. The composite initially looks and behaves like rubber, but when exposed to water it simultaneously swells and stiffens due to hydration of the cement component. The material eventually reaches a stiffness that is intermediate between that of HNBR and hydrated cement, while maintaining a relatively large ductility that is more characteristic of rubber. This behavior, which is ideal for sealing applications, differentiates this material from conventional swellable materials that become less stiff upon swelling. The development of this new type of material was motivated by the requirements of oilfield zonal isolation, where alternatives to cement are needed for some challenging sealing applications. A mechanism for the swelling and stiffening of the reactive composite is proposed: water diffuses into the HNBR matrix and is converted to bound water through hydration reactions with the cement, causing the effective solid filler content of the composite to increase. A model is proposed that treats the composite as a cellular solid with a continuous filler phase (hydrated cement). This model is able to reproduce the observed increase in the elastic modulus with time during exposure to water. |
Author | Maheshwari, Sudeep Musso, Simone Robisson, Agathe Ulm, Franz-Josef Auzerais, Francois M. Thomas, Jeffrey J. Han, Dingzhi Qu, Meng |
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Cites_doi | 10.1021/bk-2007-0959.ch015 10.1038/484289a 10.2118/105781-MS 10.1007/s10853-006-0873-2 10.1016/j.engfailanal.2006.11.061 10.1103/PhysRevLett.104.195502 10.1017/CBO9781139878326 10.1051/jp2:1993138 10.1002/adma.200800534 10.1021/ma00090a012 10.1016/j.mechmat.2010.08.001 10.1063/1.3428461 10.1016/S0927-0256(00)00157-9 10.1063/1.1723792 10.1016/S8756-3282(99)00146-5 10.2118/128226-MS 10.1002/jbm.b.31066 |
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Keywords | A. Particle-reinforced composites B. Mechanical properties A. Oxides C. Elastic properties D. Dynamic mechanical thermal analysis (DMTA) Elastic modulus Slag cement Swelling Mechanical properties Dispersion reinforced material Experimental study Modeling Composite material Molecule scattering Hydrogenated nitrile rubber Aqueous medium Sealing material |
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Snippet | This paper describes a novel reactive composite material comprised of hydrogenated nitrile butadiene rubber (HNBR) compounded with slag cement. The composite... |
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SubjectTerms | A. Oxides A. Particle-reinforced composites Applied sciences B. Mechanical properties Butadiene C. Elastic properties Cellular Cements Composites D. Dynamic mechanical thermal analysis (DMTA) Exact sciences and technology Fillers Forms of application and semi-finished materials Hydration Polymer industry, paints, wood Rubber Sealing Swelling Technology of polymers |
Title | Reactive elastomeric composites: When rubber meets cement |
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