Gamma radiolysis of hydrophilic diglycolamide ligands in concentrated aqueous nitrate solution

• Published in: Dalton transactions : an international journal of inorganic chemistry Vol. 48; no. 45; pp. 175 - 1713
• Main Authors: Horne, Gregory P, Wilden, Andreas, Mezyk, Stephen P, Twight, Liam, Hupert, Michelle, Stärk, Andrea, Verboom, Willem, Mincher, Bruce J, Modolo, Giuseppe
• Format: Journal Article
• Language: English
• Published: Cambridge Royal Society of Chemistry 19.11.2019; Royal Society of Chemistry (RSC)
• Subjects: Adducts; Degradation; Electron irradiation; Hydrophilicity; Multiscale analysis; Nitrates; Organic chemistry; Oxidation; Radiation chemistry; Radiolysis; Reaction kinetics; Scavenging

The radiation chemistry of a series of hydrophilic diglycolamides (DGAs: TEDGA, Me-TEDGA, Me 2 -TEDGA, and TPDGA) has been investigated under neutral pH, concentrated aqueous nitrate solution conditions. A combination of steady-state gamma and time-resolved pulsed electron irradiation experiments, s...