Acylation Reactions over Zeolites and Mesoporous Catalysts
Sievilized chemistry: Molecular sieves are highly active and selective catalysts with industrial potential for acylation reactions. Zeolites are the catalysts of choice when shape‐selectivity influences the preferential formation of some products, while high conversions are achieved over mesoporous...
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Published in | ChemSusChem Vol. 2; no. 6; pp. 486 - 499 |
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Main Authors | , , |
Format | Journal Article |
Language | English |
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Weinheim
WILEY-VCH Verlag
01.01.2009
WILEY‐VCH Verlag |
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Abstract | Sievilized chemistry: Molecular sieves are highly active and selective catalysts with industrial potential for acylation reactions. Zeolites are the catalysts of choice when shape‐selectivity influences the preferential formation of some products, while high conversions are achieved over mesoporous catalysts with enhanced diffusion rates of reactants and products.
Friedel–Crafts acylation reactions play an important role in the manufacture of aromatic ketones, which are used as intermediates or products in fine‐chemical synthesis. Molecular sieves are highly active and selective catalysts with industrial potential for acylation reactions. Zeolites are the catalysts of choice when shape selectivity influences the preferential formation of some products, while high conversions are achieved over mesoporous catalysts with enhanced diffusion rates of reactants and products. In this Minireview, we focus on the understanding of the relationship among the structure of molecular sieve, type and concentration of acid sites and activity/selectivity in various acylations of aromatic and olefinic hydrocarbons. The products of these acylation reactions are important compounds for the pharmaceutical industry, fragrance and flavor materials, dyes, polymers, agrochemicals, and other applications.
Sievilized chemistry: Molecular sieves are highly active and selective catalysts with industrial potential for acylation reactions. Zeolites are the catalysts of choice when shape‐selectivity influences the preferential formation of some products, while high conversions are achieved over mesoporous catalysts with enhanced diffusion rates of reactants and products. |
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AbstractList | Abstract
Sievilized chemistry
: Molecular sieves are highly active and selective catalysts with industrial potential for acylation reactions. Zeolites are the catalysts of choice when shape‐selectivity influences the preferential formation of some products, while high conversions are achieved over mesoporous catalysts with enhanced diffusion rates of reactants and products.
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Friedel–Crafts acylation reactions play an important role in the manufacture of aromatic ketones, which are used as intermediates or products in fine‐chemical synthesis. Molecular sieves are highly active and selective catalysts with industrial potential for acylation reactions. Zeolites are the catalysts of choice when shape selectivity influences the preferential formation of some products, while high conversions are achieved over mesoporous catalysts with enhanced diffusion rates of reactants and products. In this Minireview, we focus on the understanding of the relationship among the structure of molecular sieve, type and concentration of acid sites and activity/selectivity in various acylations of aromatic and olefinic hydrocarbons. The products of these acylation reactions are important compounds for the pharmaceutical industry, fragrance and flavor materials, dyes, polymers, agrochemicals, and other applications. Molecular sieves are highly active and selective catalysts with industrial potential for acylation reactions. Zeolites are the catalysts of choice when shape selectivity influences the preferential formation of some products, while high conversions are achieved over mesoporous catalysts with enhanced diffusion rates of reactants and products. In this Minireview, we focus on the understanding of the relationship among the structure of molecular sieve, type and concentration of acid sites and activity/selectivity in various acylations of aromatic and olefinic hydrocarbons. The products of these acylation reactions are important compounds for the pharmaceutical industry, fragrance and flavor materials, dyes, polymers, agrochemicals, and other applications. Sievilized chemistry: Molecular sieves are highly active and selective catalysts with industrial potential for acylation reactions. Zeolites are the catalysts of choice when shape‐selectivity influences the preferential formation of some products, while high conversions are achieved over mesoporous catalysts with enhanced diffusion rates of reactants and products. Friedel–Crafts acylation reactions play an important role in the manufacture of aromatic ketones, which are used as intermediates or products in fine‐chemical synthesis. Molecular sieves are highly active and selective catalysts with industrial potential for acylation reactions. Zeolites are the catalysts of choice when shape selectivity influences the preferential formation of some products, while high conversions are achieved over mesoporous catalysts with enhanced diffusion rates of reactants and products. In this Minireview, we focus on the understanding of the relationship among the structure of molecular sieve, type and concentration of acid sites and activity/selectivity in various acylations of aromatic and olefinic hydrocarbons. The products of these acylation reactions are important compounds for the pharmaceutical industry, fragrance and flavor materials, dyes, polymers, agrochemicals, and other applications. Sievilized chemistry: Molecular sieves are highly active and selective catalysts with industrial potential for acylation reactions. Zeolites are the catalysts of choice when shape‐selectivity influences the preferential formation of some products, while high conversions are achieved over mesoporous catalysts with enhanced diffusion rates of reactants and products. |
Author | Bejblová, Martina Procházková, Dana Čejka, Jiří |
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BackLink | https://www.ncbi.nlm.nih.gov/pubmed/19350610$$D View this record in MEDLINE/PubMed |
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(e_1_2_12_15_2) 2001 e_1_2_12_102_2 e_1_2_12_52_2 e_1_2_12_75_2 e_1_2_12_98_2 e_1_2_12_33_2 e_1_2_12_56_2 e_1_2_12_79_2 e_1_2_12_14_2 e_1_2_12_90_2 e_1_2_12_10_2 e_1_2_12_71_2 e_1_2_12_94_2 Kouwenhoven H. W. (e_1_2_12_4_2) 2008 e_1_2_12_8_2 e_1_2_12_5_2 e_1_2_12_1_2 e_1_2_12_16_2 e_1_2_12_65_2 e_1_2_12_42_2 e_1_2_12_84_2 e_1_2_12_23_2 e_1_2_12_69_2 e_1_2_12_46_2 e_1_2_12_88_2 e_1_2_12_61_2 e_1_2_12_80_2 Bekkum H. van (e_1_2_12_6_2) 2008 e_1_2_12_27_2 e_1_2_12_101_2 e_1_2_12_30_2 e_1_2_12_76_2 e_1_2_12_53_2 e_1_2_12_95_2 e_1_2_12_34_2 e_1_2_12_57_2 e_1_2_12_99_2 e_1_2_12_72_2 e_1_2_12_9_2 e_1_2_12_91_2 |
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Snippet | Sievilized chemistry: Molecular sieves are highly active and selective catalysts with industrial potential for acylation reactions. Zeolites are the catalysts... Molecular sieves are highly active and selective catalysts with industrial potential for acylation reactions. Zeolites are the catalysts of choice when shape... Abstract Sievilized chemistry : Molecular sieves are highly active and selective catalysts with industrial potential for acylation reactions. Zeolites are the... |
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SubjectTerms | Acylation Calcium Compounds Catalysis Green Chemistry Technology - methods ketones mesoporous materials Organic Chemistry Phenomena shape-selectivity Silicates Zeolites |
Title | Acylation Reactions over Zeolites and Mesoporous Catalysts |
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