Enhancing Li+ Transport in NMC811||Graphite Lithium‐Ion Batteries at Low Temperatures by Using Low‐Polarity‐Solvent Electrolytes
LiNixCoyMnzO2 (x+y+z=1)||graphite lithium‐ion battery (LIB) chemistry promises practical applications. However, its low‐temperature (≤ −20 °C) performance is poor because the increased resistance encountered by Li+ transport in and across the bulk electrolytes and the electrolyte/electrode interphas...
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| Published in | Angewandte Chemie (International ed.) Vol. 61; no. 35; pp. e202205967 - n/a |
|---|---|
| Main Authors | , , , , , , , , , , , , , , , , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Weinheim
Wiley Subscription Services, Inc
26.08.2022
Wiley |
| Edition | International ed. in English |
| Subjects | |
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| Abstract | LiNixCoyMnzO2 (x+y+z=1)||graphite lithium‐ion battery (LIB) chemistry promises practical applications. However, its low‐temperature (≤ −20 °C) performance is poor because the increased resistance encountered by Li+ transport in and across the bulk electrolytes and the electrolyte/electrode interphases induces capacity loss and battery failures. Though tremendous efforts have been made, there is still no effective way to reduce the charge transfer resistance (Rct) which dominates low‐temperature LIBs performance. Herein, we propose a strategy of using low‐polarity‐solvent electrolytes which have weak interactions between the solvents and the Li+ to reduce Rct, achieving facile Li+ transport at sub‐zero temperatures. The exemplary electrolyte enables LiNi0.8Mn0.1Co0.1O2||graphite cells to deliver a capacity of ≈113 mAh g−1 (98 % full‐cell capacity) at 25 °C and to remain 82 % of their room‐temperature capacity at −20 °C without lithium plating at 1/3C. They also retain 84 % of their capacity at −30 °C and 78 % of their capacity at −40 °C and show stable cycling at 50 °C.
Low‐polarity‐solvent electrolytes (LPSEs) 1) enable the formation of the anion‐derived interphases on both electrodes and 2) have weak interactions between the solvent molecules and Li+, which provide fast Li+ transport kinetics and reduced resistance in both charge transfer process and Li+ transport in electrode/electrolyte interphases, achieving excellent battery performance under both fast‐charge and low‐temperature conditions. |
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| AbstractList | LiNixCoyMnzO2 (x+y+z=1)||graphite lithium-ion battery (LIB) chemistry promises practical applications. However, its low-temperature (≤ –20°C) performance is poor because the increased resistance encountered by Li+ transport in and across the bulk electrolytes and the electrolyte/electrode interphases induces capacity loss and battery failures. Though tremendous efforts have been made, there is still no effective way to reduce the charge transfer resistance (Rct) which dominates low-temperature LIBs performance. In this work, we propose a strategy of using low-polarity-solvent electrolytes which have weak interactions between the solvents and the Li+ to reduce Rct, achieving facile Li+ transport at sub-zero temperatures. The exemplary electrolyte enables LiNi0.8Mn0.1Co0.1O2||graphite cells to deliver a capacity of ≈113 mAh g–1 (98% full-cell capacity) at 25°C and to remain 82% of their room-temperature capacity at –20°C without lithium plating at 1/3C. They also retain 84% of their capacity at –30°C and 78% of their capacity at –40°C and show stable cycling at 50°C. LiNi x Co y Mn z O 2 ( x +y+ z =1)||graphite lithium‐ion battery (LIB) chemistry promises practical applications. However, its low‐temperature (≤ −20 °C) performance is poor because the increased resistance encountered by Li + transport in and across the bulk electrolytes and the electrolyte/electrode interphases induces capacity loss and battery failures. Though tremendous efforts have been made, there is still no effective way to reduce the charge transfer resistance ( R ct ) which dominates low‐temperature LIBs performance. Herein, we propose a strategy of using low‐polarity‐solvent electrolytes which have weak interactions between the solvents and the Li + to reduce R ct , achieving facile Li + transport at sub‐zero temperatures. The exemplary electrolyte enables LiNi 0.8 Mn 0.1 Co 0.1 O 2 ||graphite cells to deliver a capacity of ≈113 mAh g −1 (98 % full‐cell capacity) at 25 °C and to remain 82 % of their room‐temperature capacity at −20 °C without lithium plating at 1/3C. They also retain 84 % of their capacity at −30 °C and 78 % of their capacity at −40 °C and show stable cycling at 50 °C. LiNixCoyMnzO2 (x+y+z=1)||graphite lithium‐ion battery (LIB) chemistry promises practical applications. However, its low‐temperature (≤ −20 °C) performance is poor because the increased resistance encountered by Li+ transport in and across the bulk electrolytes and the electrolyte/electrode interphases induces capacity loss and battery failures. Though tremendous efforts have been made, there is still no effective way to reduce the charge transfer resistance (Rct) which dominates low‐temperature LIBs performance. Herein, we propose a strategy of using low‐polarity‐solvent electrolytes which have weak interactions between the solvents and the Li+ to reduce Rct, achieving facile Li+ transport at sub‐zero temperatures. The exemplary electrolyte enables LiNi0.8Mn0.1Co0.1O2||graphite cells to deliver a capacity of ≈113 mAh g−1 (98 % full‐cell capacity) at 25 °C and to remain 82 % of their room‐temperature capacity at −20 °C without lithium plating at 1/3C. They also retain 84 % of their capacity at −30 °C and 78 % of their capacity at −40 °C and show stable cycling at 50 °C. LiNix Coy Mnz O2 (x+y+z=1)||graphite lithium-ion battery (LIB) chemistry promises practical applications. However, its low-temperature (≤ -20 °C) performance is poor because the increased resistance encountered by Li+ transport in and across the bulk electrolytes and the electrolyte/electrode interphases induces capacity loss and battery failures. Though tremendous efforts have been made, there is still no effective way to reduce the charge transfer resistance (Rct ) which dominates low-temperature LIBs performance. Herein, we propose a strategy of using low-polarity-solvent electrolytes which have weak interactions between the solvents and the Li+ to reduce Rct , achieving facile Li+ transport at sub-zero temperatures. The exemplary electrolyte enables LiNi0.8 Mn0.1 Co0.1 O2 ||graphite cells to deliver a capacity of ≈113 mAh g-1 (98 % full-cell capacity) at 25 °C and to remain 82 % of their room-temperature capacity at -20 °C without lithium plating at 1/3C. They also retain 84 % of their capacity at -30 °C and 78 % of their capacity at -40 °C and show stable cycling at 50 °C.LiNix Coy Mnz O2 (x+y+z=1)||graphite lithium-ion battery (LIB) chemistry promises practical applications. However, its low-temperature (≤ -20 °C) performance is poor because the increased resistance encountered by Li+ transport in and across the bulk electrolytes and the electrolyte/electrode interphases induces capacity loss and battery failures. Though tremendous efforts have been made, there is still no effective way to reduce the charge transfer resistance (Rct ) which dominates low-temperature LIBs performance. Herein, we propose a strategy of using low-polarity-solvent electrolytes which have weak interactions between the solvents and the Li+ to reduce Rct , achieving facile Li+ transport at sub-zero temperatures. The exemplary electrolyte enables LiNi0.8 Mn0.1 Co0.1 O2 ||graphite cells to deliver a capacity of ≈113 mAh g-1 (98 % full-cell capacity) at 25 °C and to remain 82 % of their room-temperature capacity at -20 °C without lithium plating at 1/3C. They also retain 84 % of their capacity at -30 °C and 78 % of their capacity at -40 °C and show stable cycling at 50 °C. LiNixCoyMnzO2 (x+y+z=1)||graphite lithium‐ion battery (LIB) chemistry promises practical applications. However, its low‐temperature (≤ −20 °C) performance is poor because the increased resistance encountered by Li+ transport in and across the bulk electrolytes and the electrolyte/electrode interphases induces capacity loss and battery failures. Though tremendous efforts have been made, there is still no effective way to reduce the charge transfer resistance (Rct) which dominates low‐temperature LIBs performance. Herein, we propose a strategy of using low‐polarity‐solvent electrolytes which have weak interactions between the solvents and the Li+ to reduce Rct, achieving facile Li+ transport at sub‐zero temperatures. The exemplary electrolyte enables LiNi0.8Mn0.1Co0.1O2||graphite cells to deliver a capacity of ≈113 mAh g−1 (98 % full‐cell capacity) at 25 °C and to remain 82 % of their room‐temperature capacity at −20 °C without lithium plating at 1/3C. They also retain 84 % of their capacity at −30 °C and 78 % of their capacity at −40 °C and show stable cycling at 50 °C. Low‐polarity‐solvent electrolytes (LPSEs) 1) enable the formation of the anion‐derived interphases on both electrodes and 2) have weak interactions between the solvent molecules and Li+, which provide fast Li+ transport kinetics and reduced resistance in both charge transfer process and Li+ transport in electrode/electrolyte interphases, achieving excellent battery performance under both fast‐charge and low‐temperature conditions. |
| Author | Piao, Nan Wang, Chunsheng Xia, Jiale Ma, Lin Wan, Hongli Borodin, Oleg Zhang, Weiran Zhang, Xiyue Nan, Bo Hou, Singyuk Ji, Xiao Pollard, Travis He, Xinzi Chen, Long Liu, Sufu Lucht, Brett Yang, Xiao‐Qing Rodrigo, Nuwanthi D. Xu, Jijian Xu, Kang Hu, Enyuan Zhang, Jiaxun |
| Author_xml | – sequence: 1 givenname: Bo surname: Nan fullname: Nan, Bo organization: University of Maryland – sequence: 2 givenname: Long surname: Chen fullname: Chen, Long organization: University of Maryland – sequence: 3 givenname: Nuwanthi D. surname: Rodrigo fullname: Rodrigo, Nuwanthi D. organization: University of Rhode Island – sequence: 4 givenname: Oleg surname: Borodin fullname: Borodin, Oleg organization: Army Research Laboratory – sequence: 5 givenname: Nan surname: Piao fullname: Piao, Nan organization: University of Maryland – sequence: 6 givenname: Jiale surname: Xia fullname: Xia, Jiale organization: University of Maryland – sequence: 7 givenname: Travis surname: Pollard fullname: Pollard, Travis organization: Army Research Laboratory – sequence: 8 givenname: Singyuk surname: Hou fullname: Hou, Singyuk organization: University of Maryland – sequence: 9 givenname: Jiaxun surname: Zhang fullname: Zhang, Jiaxun organization: University of Maryland – sequence: 10 givenname: Xiao surname: Ji fullname: Ji, Xiao organization: University of Maryland – sequence: 11 givenname: Jijian surname: Xu fullname: Xu, Jijian organization: University of Maryland – sequence: 12 givenname: Xiyue surname: Zhang fullname: Zhang, Xiyue organization: University of Maryland – sequence: 13 givenname: Lin surname: Ma fullname: Ma, Lin organization: The University of North Carolina at Charlotte – sequence: 14 givenname: Xinzi surname: He fullname: He, Xinzi organization: University of Maryland – sequence: 15 givenname: Sufu surname: Liu fullname: Liu, Sufu organization: University of Maryland – sequence: 16 givenname: Hongli surname: Wan fullname: Wan, Hongli organization: University of Maryland – sequence: 17 givenname: Enyuan surname: Hu fullname: Hu, Enyuan organization: Brookhaven National Laboratory – sequence: 18 givenname: Weiran surname: Zhang fullname: Zhang, Weiran organization: University of Maryland – sequence: 19 givenname: Kang surname: Xu fullname: Xu, Kang email: conrad.k.xu.civ@mail.mil organization: Army Research Laboratory – sequence: 20 givenname: Xiao‐Qing surname: Yang fullname: Yang, Xiao‐Qing email: xyang@bnl.gov organization: Brookhaven National Laboratory – sequence: 21 givenname: Brett surname: Lucht fullname: Lucht, Brett email: blucht@uri.edu organization: University of Rhode Island – sequence: 22 givenname: Chunsheng orcidid: 0000-0002-8626-6381 surname: Wang fullname: Wang, Chunsheng email: cswang@umd.edu organization: University of Maryland |
| BackLink | https://www.osti.gov/servlets/purl/1889129$$D View this record in Osti.gov |
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| Copyright | 2022 Wiley‐VCH GmbH 2022 Wiley-VCH GmbH. |
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| CorporateAuthor | Brookhaven National Laboratory (BNL), Upton, NY (United States) |
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| Snippet | LiNixCoyMnzO2 (x+y+z=1)||graphite lithium‐ion battery (LIB) chemistry promises practical applications. However, its low‐temperature (≤ −20 °C) performance is... LiNi x Co y Mn z O 2 ( x +y+ z =1)||graphite lithium‐ion battery (LIB) chemistry promises practical applications. However, its low‐temperature (≤ −20 °C)... LiNix Coy Mnz O2 (x+y+z=1)||graphite lithium-ion battery (LIB) chemistry promises practical applications. However, its low-temperature (≤ -20 °C) performance... LiNixCoyMnzO2 (x+y+z=1)||graphite lithium-ion battery (LIB) chemistry promises practical applications. However, its low-temperature (≤ –20°C) performance is... |
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| SubjectTerms | Charge transfer Electrolytes Electrolytic cells ENERGY STORAGE Graphite Inorganic-Rich EEIs Li-Plating Free Lithium Lithium-ion batteries Low temperature Low-Temperature Electrolyte NMC811llGraphite NMC811||Graphite Polarity Solvents Weak Ion-Dipole Interactions |
| Title | Enhancing Li+ Transport in NMC811||Graphite Lithium‐Ion Batteries at Low Temperatures by Using Low‐Polarity‐Solvent Electrolytes |
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