Porphyrin-based metal–organic framework thin films for electrochemical nitrite detection
Uniform zirconium-based porphyrin metal–organic framework (MOF-525) thin films are grown on conducting glass substrates by using a solvothermal approach. The obtained MOF-525 thin film is electrochemically addressable in aqueous solution and shows electrocatalytic activity for nitrite oxidation. The...
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Published in | Electrochemistry communications Vol. 58; no. C; pp. 51 - 56 |
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Main Authors | , , , , , |
Format | Journal Article |
Language | English |
Published |
Netherlands
Elsevier B.V
01.09.2015
Elsevier |
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Abstract | Uniform zirconium-based porphyrin metal–organic framework (MOF-525) thin films are grown on conducting glass substrates by using a solvothermal approach. The obtained MOF-525 thin film is electrochemically addressable in aqueous solution and shows electrocatalytic activity for nitrite oxidation. The mechanism for the electrocatalytic oxidation of nitrite at the MOF-525 thin film is investigated by cyclic voltammetry. The redox mechanism of the MOF-525 thin film in the KCl aqueous solution is studied by amperometry. The MOF-525 thin film is deployed as an amperometric nitrite sensor. The linear range, sensitivity, and limit of detection are 20–800μM, 95μA/mM-cm2, and 2.1μM, respectively.
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•Zirconium-based porphyrin MOF thin films are grown on conducting substrates.•The MOF-525 thin film shows electrocatalytic activity for nitrite oxidation.•Redox and electrocatalytic mechanisms of the MOF thin film are investigated.•The amperometric nitrite sensor using MOF-525 thin film is successfully developed. |
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AbstractList | Uniform zirconium-based porphyrin metal–organic framework (MOF-525) thin films are grown on conducting glass substrates by using a solvothermal approach. The obtained MOF-525 thin film is electrochemically addressable in aqueous solution and shows electrocatalytic activity for nitrite oxidation. The mechanism for the electrocatalytic oxidation of nitrite at the MOF-525 thin film is investigated by cyclic voltammetry. The redox mechanism of the MOF-525 thin film in the KCl aqueous solution is studied by amperometry. The MOF-525 thin film is deployed as an amperometric nitrite sensor. The linear range, sensitivity, and limit of detection are 20–800μM, 95μA/mM-cm2, and 2.1μM, respectively.
[Display omitted]
•Zirconium-based porphyrin MOF thin films are grown on conducting substrates.•The MOF-525 thin film shows electrocatalytic activity for nitrite oxidation.•Redox and electrocatalytic mechanisms of the MOF thin film are investigated.•The amperometric nitrite sensor using MOF-525 thin film is successfully developed. |
Author | Chou, Li-Yao Ho, Kuo-Chuan Chang, Ting-Hsiang Farha, Omar K. Kung, Chung-Wei Hupp, Joseph T. |
Author_xml | – sequence: 1 givenname: Chung-Wei surname: Kung fullname: Kung, Chung-Wei organization: Department of Chemical Engineering, National Taiwan University, Taipei 10617, Taiwan – sequence: 2 givenname: Ting-Hsiang surname: Chang fullname: Chang, Ting-Hsiang organization: Department of Chemical Engineering, National Taiwan University, Taipei 10617, Taiwan – sequence: 3 givenname: Li-Yao surname: Chou fullname: Chou, Li-Yao organization: Department of Chemical Engineering, National Taiwan University, Taipei 10617, Taiwan – sequence: 4 givenname: Joseph T. surname: Hupp fullname: Hupp, Joseph T. organization: Department of Chemistry, Northwestern University, Evanston, IL 60208, United States – sequence: 5 givenname: Omar K. surname: Farha fullname: Farha, Omar K. organization: Department of Chemistry, Northwestern University, Evanston, IL 60208, United States – sequence: 6 givenname: Kuo-Chuan surname: Ho fullname: Ho, Kuo-Chuan email: kcho@ntu.edu.tw organization: Department of Chemical Engineering, National Taiwan University, Taipei 10617, Taiwan |
BackLink | https://www.osti.gov/biblio/1252127$$D View this record in Osti.gov |
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Snippet | Uniform zirconium-based porphyrin metal–organic framework (MOF-525) thin films are grown on conducting glass substrates by using a solvothermal approach. The... |
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SubjectTerms | Electroactive metal–organic frameworks Electrocatalysis Electrochemical sensor Solvothermal growth Zirconium node |
Title | Porphyrin-based metal–organic framework thin films for electrochemical nitrite detection |
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