Porphyrin-based metal–organic framework thin films for electrochemical nitrite detection

Uniform zirconium-based porphyrin metal–organic framework (MOF-525) thin films are grown on conducting glass substrates by using a solvothermal approach. The obtained MOF-525 thin film is electrochemically addressable in aqueous solution and shows electrocatalytic activity for nitrite oxidation. The...

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Published inElectrochemistry communications Vol. 58; no. C; pp. 51 - 56
Main Authors Kung, Chung-Wei, Chang, Ting-Hsiang, Chou, Li-Yao, Hupp, Joseph T., Farha, Omar K., Ho, Kuo-Chuan
Format Journal Article
LanguageEnglish
Published Netherlands Elsevier B.V 01.09.2015
Elsevier
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Abstract Uniform zirconium-based porphyrin metal–organic framework (MOF-525) thin films are grown on conducting glass substrates by using a solvothermal approach. The obtained MOF-525 thin film is electrochemically addressable in aqueous solution and shows electrocatalytic activity for nitrite oxidation. The mechanism for the electrocatalytic oxidation of nitrite at the MOF-525 thin film is investigated by cyclic voltammetry. The redox mechanism of the MOF-525 thin film in the KCl aqueous solution is studied by amperometry. The MOF-525 thin film is deployed as an amperometric nitrite sensor. The linear range, sensitivity, and limit of detection are 20–800μM, 95μA/mM-cm2, and 2.1μM, respectively. [Display omitted] •Zirconium-based porphyrin MOF thin films are grown on conducting substrates.•The MOF-525 thin film shows electrocatalytic activity for nitrite oxidation.•Redox and electrocatalytic mechanisms of the MOF thin film are investigated.•The amperometric nitrite sensor using MOF-525 thin film is successfully developed.
AbstractList Uniform zirconium-based porphyrin metal–organic framework (MOF-525) thin films are grown on conducting glass substrates by using a solvothermal approach. The obtained MOF-525 thin film is electrochemically addressable in aqueous solution and shows electrocatalytic activity for nitrite oxidation. The mechanism for the electrocatalytic oxidation of nitrite at the MOF-525 thin film is investigated by cyclic voltammetry. The redox mechanism of the MOF-525 thin film in the KCl aqueous solution is studied by amperometry. The MOF-525 thin film is deployed as an amperometric nitrite sensor. The linear range, sensitivity, and limit of detection are 20–800μM, 95μA/mM-cm2, and 2.1μM, respectively. [Display omitted] •Zirconium-based porphyrin MOF thin films are grown on conducting substrates.•The MOF-525 thin film shows electrocatalytic activity for nitrite oxidation.•Redox and electrocatalytic mechanisms of the MOF thin film are investigated.•The amperometric nitrite sensor using MOF-525 thin film is successfully developed.
Author Chou, Li-Yao
Ho, Kuo-Chuan
Chang, Ting-Hsiang
Farha, Omar K.
Kung, Chung-Wei
Hupp, Joseph T.
Author_xml – sequence: 1
  givenname: Chung-Wei
  surname: Kung
  fullname: Kung, Chung-Wei
  organization: Department of Chemical Engineering, National Taiwan University, Taipei 10617, Taiwan
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  givenname: Ting-Hsiang
  surname: Chang
  fullname: Chang, Ting-Hsiang
  organization: Department of Chemical Engineering, National Taiwan University, Taipei 10617, Taiwan
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  givenname: Li-Yao
  surname: Chou
  fullname: Chou, Li-Yao
  organization: Department of Chemical Engineering, National Taiwan University, Taipei 10617, Taiwan
– sequence: 4
  givenname: Joseph T.
  surname: Hupp
  fullname: Hupp, Joseph T.
  organization: Department of Chemistry, Northwestern University, Evanston, IL 60208, United States
– sequence: 5
  givenname: Omar K.
  surname: Farha
  fullname: Farha, Omar K.
  organization: Department of Chemistry, Northwestern University, Evanston, IL 60208, United States
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  givenname: Kuo-Chuan
  surname: Ho
  fullname: Ho, Kuo-Chuan
  email: kcho@ntu.edu.tw
  organization: Department of Chemical Engineering, National Taiwan University, Taipei 10617, Taiwan
BackLink https://www.osti.gov/biblio/1252127$$D View this record in Osti.gov
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Snippet Uniform zirconium-based porphyrin metal–organic framework (MOF-525) thin films are grown on conducting glass substrates by using a solvothermal approach. The...
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SubjectTerms Electroactive metal–organic frameworks
Electrocatalysis
Electrochemical sensor
Solvothermal growth
Zirconium node
Title Porphyrin-based metal–organic framework thin films for electrochemical nitrite detection
URI https://dx.doi.org/10.1016/j.elecom.2015.06.003
https://www.osti.gov/biblio/1252127
Volume 58
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