Modified Starch-Based Adhesives: A Review

Consumer trends towards environmentally friendly products are driving plastics industries to investigate more benign alternatives to petroleum-based polymers. In the case of adhesives, one possibility to achieve sustainable production is to use non-toxic, low-cost starches as biodegradable raw mater...

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Published inPolymers Vol. 14; no. 10; p. 2023
Main Authors Watcharakitti, Jidapa, Win, Ei Ei, Nimnuan, Jaturavit, Smith, Siwaporn Meejoo
Format Journal Article
LanguageEnglish
Published Switzerland MDPI AG 16.05.2022
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Abstract Consumer trends towards environmentally friendly products are driving plastics industries to investigate more benign alternatives to petroleum-based polymers. In the case of adhesives, one possibility to achieve sustainable production is to use non-toxic, low-cost starches as biodegradable raw materials for adhesive production. While native starch contains only hydroxyl groups and has limited scope, chemically modified starch shows superior water resistance properties for adhesive applications. Esterified starches, starches with ester substituents, can be feasibly produced and utilized to prepare bio-based adhesives with improved water resistance. Syntheses of esterified starch materials can involve esterification, transesterification, alkylation, acetylation, succinylation, or enzymatic reactions. The main focus of this review is on the production of esterified starches and their utilization in adhesive applications (for paper, plywood, wood composites, fiberboard, and particleboard). The latter part of this review discusses other processes (etherification, crosslinking, grafting, oxidation, or utilizing biobased coupling agents) to prepare modified starches that can be further applied in adhesive production. Further discussion on the characteristics of modified starch materials and required processing methods for adhesive production is also included.
AbstractList Consumer trends towards environmentally friendly products are driving plastics industries to investigate more benign alternatives to petroleum-based polymers. In the case of adhesives, one possibility to achieve sustainable production is to use non-toxic, low-cost starches as biodegradable raw materials for adhesive production. While native starch contains only hydroxyl groups and has limited scope, chemically modified starch shows superior water resistance properties for adhesive applications. Esterified starches, starches with ester substituents, can be feasibly produced and utilized to prepare bio-based adhesives with improved water resistance. Syntheses of esterified starch materials can involve esterification, transesterification, alkylation, acetylation, succinylation, or enzymatic reactions. The main focus of this review is on the production of esterified starches and their utilization in adhesive applications (for paper, plywood, wood composites, fiberboard, and particleboard). The latter part of this review discusses other processes (etherification, crosslinking, grafting, oxidation, or utilizing biobased coupling agents) to prepare modified starches that can be further applied in adhesive production. Further discussion on the characteristics of modified starch materials and required processing methods for adhesive production is also included.
Author Smith, Siwaporn Meejoo
Win, Ei Ei
Watcharakitti, Jidapa
Nimnuan, Jaturavit
AuthorAffiliation Center of Sustainable Energy and Green Materials and Department of Chemistry, Faculty of Science, Mahidol University, 999 Phuttamonthon Sai 4 Road, Salaya 73170, Thailand; bonusjidapa@gmail.com (J.W.); eieiwin.w96@gmail.com (E.E.W.); jaturavit.nim@gmail.com (J.N.)
AuthorAffiliation_xml – name: Center of Sustainable Energy and Green Materials and Department of Chemistry, Faculty of Science, Mahidol University, 999 Phuttamonthon Sai 4 Road, Salaya 73170, Thailand; bonusjidapa@gmail.com (J.W.); eieiwin.w96@gmail.com (E.E.W.); jaturavit.nim@gmail.com (J.N.)
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BackLink https://www.ncbi.nlm.nih.gov/pubmed/35631906$$D View this record in MEDLINE/PubMed
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Keywords synthesis
biopolymer
esterified starch
adhesives
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Snippet Consumer trends towards environmentally friendly products are driving plastics industries to investigate more benign alternatives to petroleum-based polymers....
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SubjectTerms Acetylation
Adhesives
Alcohol
Alkylation
Biodegradability
biopolymer
Bond strength
Catalysis
Cellulose acetate
Chemical reactions
Coupling agents
Crosslinking
Enzymes
Esterification
esterified starch
Fatty acids
Hydrocarbons
Hydroxyl groups
Oxidation
Paper board
Particle board
Phenols
Plywood
Production methods
Raw materials
Review
Starches
synthesis
Transesterification
Water resistance
Wood composites
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Title Modified Starch-Based Adhesives: A Review
URI https://www.ncbi.nlm.nih.gov/pubmed/35631906
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Volume 14
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