Modified Starch-Based Adhesives: A Review
Consumer trends towards environmentally friendly products are driving plastics industries to investigate more benign alternatives to petroleum-based polymers. In the case of adhesives, one possibility to achieve sustainable production is to use non-toxic, low-cost starches as biodegradable raw mater...
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Published in | Polymers Vol. 14; no. 10; p. 2023 |
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Main Authors | , , , |
Format | Journal Article |
Language | English |
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16.05.2022
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Abstract | Consumer trends towards environmentally friendly products are driving plastics industries to investigate more benign alternatives to petroleum-based polymers. In the case of adhesives, one possibility to achieve sustainable production is to use non-toxic, low-cost starches as biodegradable raw materials for adhesive production. While native starch contains only hydroxyl groups and has limited scope, chemically modified starch shows superior water resistance properties for adhesive applications. Esterified starches, starches with ester substituents, can be feasibly produced and utilized to prepare bio-based adhesives with improved water resistance. Syntheses of esterified starch materials can involve esterification, transesterification, alkylation, acetylation, succinylation, or enzymatic reactions. The main focus of this review is on the production of esterified starches and their utilization in adhesive applications (for paper, plywood, wood composites, fiberboard, and particleboard). The latter part of this review discusses other processes (etherification, crosslinking, grafting, oxidation, or utilizing biobased coupling agents) to prepare modified starches that can be further applied in adhesive production. Further discussion on the characteristics of modified starch materials and required processing methods for adhesive production is also included. |
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AbstractList | Consumer trends towards environmentally friendly products are driving plastics industries to investigate more benign alternatives to petroleum-based polymers. In the case of adhesives, one possibility to achieve sustainable production is to use non-toxic, low-cost starches as biodegradable raw materials for adhesive production. While native starch contains only hydroxyl groups and has limited scope, chemically modified starch shows superior water resistance properties for adhesive applications. Esterified starches, starches with ester substituents, can be feasibly produced and utilized to prepare bio-based adhesives with improved water resistance. Syntheses of esterified starch materials can involve esterification, transesterification, alkylation, acetylation, succinylation, or enzymatic reactions. The main focus of this review is on the production of esterified starches and their utilization in adhesive applications (for paper, plywood, wood composites, fiberboard, and particleboard). The latter part of this review discusses other processes (etherification, crosslinking, grafting, oxidation, or utilizing biobased coupling agents) to prepare modified starches that can be further applied in adhesive production. Further discussion on the characteristics of modified starch materials and required processing methods for adhesive production is also included. |
Author | Smith, Siwaporn Meejoo Win, Ei Ei Watcharakitti, Jidapa Nimnuan, Jaturavit |
AuthorAffiliation | Center of Sustainable Energy and Green Materials and Department of Chemistry, Faculty of Science, Mahidol University, 999 Phuttamonthon Sai 4 Road, Salaya 73170, Thailand; bonusjidapa@gmail.com (J.W.); eieiwin.w96@gmail.com (E.E.W.); jaturavit.nim@gmail.com (J.N.) |
AuthorAffiliation_xml | – name: Center of Sustainable Energy and Green Materials and Department of Chemistry, Faculty of Science, Mahidol University, 999 Phuttamonthon Sai 4 Road, Salaya 73170, Thailand; bonusjidapa@gmail.com (J.W.); eieiwin.w96@gmail.com (E.E.W.); jaturavit.nim@gmail.com (J.N.) |
Author_xml | – sequence: 1 givenname: Jidapa surname: Watcharakitti fullname: Watcharakitti, Jidapa organization: Center of Sustainable Energy and Green Materials and Department of Chemistry, Faculty of Science, Mahidol University, 999 Phuttamonthon Sai 4 Road, Salaya 73170, Thailand – sequence: 2 givenname: Ei Ei orcidid: 0000-0002-6181-5073 surname: Win fullname: Win, Ei Ei organization: Center of Sustainable Energy and Green Materials and Department of Chemistry, Faculty of Science, Mahidol University, 999 Phuttamonthon Sai 4 Road, Salaya 73170, Thailand – sequence: 3 givenname: Jaturavit surname: Nimnuan fullname: Nimnuan, Jaturavit organization: Center of Sustainable Energy and Green Materials and Department of Chemistry, Faculty of Science, Mahidol University, 999 Phuttamonthon Sai 4 Road, Salaya 73170, Thailand – sequence: 4 givenname: Siwaporn Meejoo orcidid: 0000-0001-7571-3636 surname: Smith fullname: Smith, Siwaporn Meejoo organization: Center of Sustainable Energy and Green Materials and Department of Chemistry, Faculty of Science, Mahidol University, 999 Phuttamonthon Sai 4 Road, Salaya 73170, Thailand |
BackLink | https://www.ncbi.nlm.nih.gov/pubmed/35631906$$D View this record in MEDLINE/PubMed |
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SubjectTerms | Acetylation Adhesives Alcohol Alkylation Biodegradability biopolymer Bond strength Catalysis Cellulose acetate Chemical reactions Coupling agents Crosslinking Enzymes Esterification esterified starch Fatty acids Hydrocarbons Hydroxyl groups Oxidation Paper board Particle board Phenols Plywood Production methods Raw materials Review Starches synthesis Transesterification Water resistance Wood composites |
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Title | Modified Starch-Based Adhesives: A Review |
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