Molecular Mobility in Oriented and Unoriented Membranes Based on Poly[2-(Aziridin-1-yl)ethanol]

Unoriented and oriented membranes based on dendronized polymers and copolymers obtained by chemical modification of poly[2-(aziridin-1-yl) ethanol] (PAZE) with the dendron 3,4,5-tris[4-( -dodecan-1-yloxy)benzyloxy]benzoate were considered. DSC, XRD, CP-MAS NMR and DETA, contribute to characterize th...

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Published inPolymers Vol. 13; no. 7; p. 1060
Main Authors Teruel-Juanes, Roberto, Bogdanowicz, Krzysztof Artur, Badia, Jose D, Sáenz de Juano-Arbona, Victor, Graf, Robert, Reina, Jose A, Giamberini, Marta, Ribes-Greus, Amparo
Format Journal Article
LanguageEnglish
Published Switzerland MDPI AG 28.03.2021
MDPI
Subjects
Benzoates
Chain dynamics
Copolymers
Dendritic structure
dendronic liquid crystal membranes
dielectric relaxation spectra
Ethanol
Fragility
Glass transition
Liquid crystals
macromolecular cooperativity
Membranes
Molecular motion
Nitrogen
NMR spectroscopy
Orientation
poly[2-(aziridin-1-yl)ethanol] (PAZE)
Polymers
segmental dynamics
Solvents
Spectrum analysis
Thermal expansion
United States > US
Germany
dielectric relaxation spectra
dendronic liquid crystal membranes
macromolecular cooperativity
poly[2-(aziridin-1-yl)ethanol] (PAZE)
segmental dynamics
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Abstract Unoriented and oriented membranes based on dendronized polymers and copolymers obtained by chemical modification of poly[2-(aziridin-1-yl) ethanol] (PAZE) with the dendron 3,4,5-tris[4-( -dodecan-1-yloxy)benzyloxy]benzoate were considered. DSC, XRD, CP-MAS NMR and DETA, contribute to characterize the tendency to crystallize, the molecular mobility of the benzyloxy substituent, the dendritic liquid crystalline group and the clearing transition. The orientation of the mesogenic chain somewhat hindered this molecular motion, especially in the full substituted PAZE. The fragility, free volume and thermal expansion coefficients of these membranes near the glass transition are related to the orientation and the addition of the dendritic groups. PAZE-based membranes combine both order and mobility on a supramolecular and macroscopic level, controlled by the dendritic group and the thermal orientation, and open the possibility of preparing membranes with proper channel mobility that promotes selective ionic transport.
AbstractList Unoriented and oriented membranes based on dendronized polymers and copolymers obtained by chemical modification of poly[2-(aziridin-1-yl) ethanol] (PAZE) with the dendron 3,4,5-tris[4-( -dodecan-1-yloxy)benzyloxy]benzoate were considered. DSC, XRD, CP-MAS NMR and DETA, contribute to characterize the tendency to crystallize, the molecular mobility of the benzyloxy substituent, the dendritic liquid crystalline group and the clearing transition. The orientation of the mesogenic chain somewhat hindered this molecular motion, especially in the full substituted PAZE. The fragility, free volume and thermal expansion coefficients of these membranes near the glass transition are related to the orientation and the addition of the dendritic groups. PAZE-based membranes combine both order and mobility on a supramolecular and macroscopic level, controlled by the dendritic group and the thermal orientation, and open the possibility of preparing membranes with proper channel mobility that promotes selective ionic transport.
Unoriented and oriented membranes based on dendronized polymers and copolymers obtained by chemical modification of poly[2-(aziridin-1-yl) ethanol] (PAZE) with the dendron 3,4,5-tris[4-(n-dodecan-1-yloxy)benzyloxy]benzoate were considered. DSC, XRD, CP-MAS NMR and DETA, contribute to characterize the tendency to crystallize, the molecular mobility of the benzyloxy substituent, the dendritic liquid crystalline group and the clearing transition. The orientation of the mesogenic chain somewhat hindered this molecular motion, especially in the full substituted PAZE. The fragility, free volume and thermal expansion coefficients of these membranes near the glass transition are related to the orientation and the addition of the dendritic groups. PAZE-based membranes combine both order and mobility on a supramolecular and macroscopic level, controlled by the dendritic group and the thermal orientation, and open the possibility of preparing membranes with proper channel mobility that promotes selective ionic transport.
Unoriented and oriented membranes based on dendronized polymers and copolymers obtained by chemical modification of poly[2-(aziridin-1-yl) ethanol] (PAZE) with the dendron 3,4,5-tris[4-( n -dodecan-1-yloxy)benzyloxy]benzoate were considered. DSC, XRD, CP-MAS NMR and DETA, contribute to characterize the tendency to crystallize, the molecular mobility of the benzyloxy substituent, the dendritic liquid crystalline group and the clearing transition. The orientation of the mesogenic chain somewhat hindered this molecular motion, especially in the full substituted PAZE. The fragility, free volume and thermal expansion coefficients of these membranes near the glass transition are related to the orientation and the addition of the dendritic groups. PAZE-based membranes combine both order and mobility on a supramolecular and macroscopic level, controlled by the dendritic group and the thermal orientation, and open the possibility of preparing membranes with proper channel mobility that promotes selective ionic transport.
Author Graf, Robert
Badia, Jose D
Sáenz de Juano-Arbona, Victor
Giamberini, Marta
Teruel-Juanes, Roberto
Reina, Jose A
Bogdanowicz, Krzysztof Artur
Ribes-Greus, Amparo
AuthorAffiliation 4 Max Planck Institute for Polymer Research, Ackermannweg 10, 55021 Mainz, Germany; graf@mpip-mainz.mpg.de
1 Institute of Technology of Materials (ITM), Universitat Politècnica de València (UPV), Camí de Vera s/n, 46022 València, Spain; r.teruel@upvnet.upv.es (R.T.-J.); vsaenzdejuano@gmail.com (V.S.d.J.-A.)
3 Polymer Technology and Sustainability Group, Department of Chemical Engineering, School of Engineering, Universitat de València (UVEG), Avinguda de la Universitat s/n, 46100 Burjassot, Spain; jose.badia@uv.es
2 Department of Chemical Engineering, Universitat Rovira i Virgili (URV), Av. Països Catalans, 26, 43007 Tarragona, Spain; bogdanowicz@witi.wroc.pl (K.A.B.); marta.giamberini@urv.cat (M.G.)
5 Department of Analytical Chemistry and Organic Chemistry, Universitat Rovira i Virgili (URV), C/Marcel·lí Domingo s/n, 43007 Tarragona, Spain; joseantonio.reina@urv.cat
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Issue 7
Keywords dielectric relaxation spectra
dendronic liquid crystal membranes
macromolecular cooperativity
poly[2-(aziridin-1-yl)ethanol] (PAZE)
segmental dynamics
Language English
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Snippet Unoriented and oriented membranes based on dendronized polymers and copolymers obtained by chemical modification of poly[2-(aziridin-1-yl) ethanol] (PAZE) with...
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SubjectTerms Benzoates
Chain dynamics
Copolymers
Dendritic structure
dendronic liquid crystal membranes
dielectric relaxation spectra
Ethanol
Fragility
Glass transition
Liquid crystals
macromolecular cooperativity
Membranes
Molecular motion
Nitrogen
NMR spectroscopy
Orientation
poly[2-(aziridin-1-yl)ethanol] (PAZE)
Polymers
segmental dynamics
Solvents
Spectrum analysis
Thermal expansion
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Title Molecular Mobility in Oriented and Unoriented Membranes Based on Poly[2-(Aziridin-1-yl)ethanol]
URI https://www.ncbi.nlm.nih.gov/pubmed/33800553
https://www.proquest.com/docview/2550252797
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Volume 13
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