Molecular Mobility in Oriented and Unoriented Membranes Based on Poly[2-(Aziridin-1-yl)ethanol]
Unoriented and oriented membranes based on dendronized polymers and copolymers obtained by chemical modification of poly[2-(aziridin-1-yl) ethanol] (PAZE) with the dendron 3,4,5-tris[4-( -dodecan-1-yloxy)benzyloxy]benzoate were considered. DSC, XRD, CP-MAS NMR and DETA, contribute to characterize th...
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Published in | Polymers Vol. 13; no. 7; p. 1060 |
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Language | English |
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Abstract | Unoriented and oriented membranes based on dendronized polymers and copolymers obtained by chemical modification of poly[2-(aziridin-1-yl) ethanol] (PAZE) with the dendron 3,4,5-tris[4-(
-dodecan-1-yloxy)benzyloxy]benzoate were considered. DSC, XRD, CP-MAS NMR and DETA, contribute to characterize the tendency to crystallize, the molecular mobility of the benzyloxy substituent, the dendritic liquid crystalline group and the clearing transition. The orientation of the mesogenic chain somewhat hindered this molecular motion, especially in the full substituted PAZE. The fragility, free volume and thermal expansion coefficients of these membranes near the glass transition are related to the orientation and the addition of the dendritic groups. PAZE-based membranes combine both order and mobility on a supramolecular and macroscopic level, controlled by the dendritic group and the thermal orientation, and open the possibility of preparing membranes with proper channel mobility that promotes selective ionic transport. |
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AbstractList | Unoriented and oriented membranes based on dendronized polymers and copolymers obtained by chemical modification of poly[2-(aziridin-1-yl) ethanol] (PAZE) with the dendron 3,4,5-tris[4-(
-dodecan-1-yloxy)benzyloxy]benzoate were considered. DSC, XRD, CP-MAS NMR and DETA, contribute to characterize the tendency to crystallize, the molecular mobility of the benzyloxy substituent, the dendritic liquid crystalline group and the clearing transition. The orientation of the mesogenic chain somewhat hindered this molecular motion, especially in the full substituted PAZE. The fragility, free volume and thermal expansion coefficients of these membranes near the glass transition are related to the orientation and the addition of the dendritic groups. PAZE-based membranes combine both order and mobility on a supramolecular and macroscopic level, controlled by the dendritic group and the thermal orientation, and open the possibility of preparing membranes with proper channel mobility that promotes selective ionic transport. Unoriented and oriented membranes based on dendronized polymers and copolymers obtained by chemical modification of poly[2-(aziridin-1-yl) ethanol] (PAZE) with the dendron 3,4,5-tris[4-(n-dodecan-1-yloxy)benzyloxy]benzoate were considered. DSC, XRD, CP-MAS NMR and DETA, contribute to characterize the tendency to crystallize, the molecular mobility of the benzyloxy substituent, the dendritic liquid crystalline group and the clearing transition. The orientation of the mesogenic chain somewhat hindered this molecular motion, especially in the full substituted PAZE. The fragility, free volume and thermal expansion coefficients of these membranes near the glass transition are related to the orientation and the addition of the dendritic groups. PAZE-based membranes combine both order and mobility on a supramolecular and macroscopic level, controlled by the dendritic group and the thermal orientation, and open the possibility of preparing membranes with proper channel mobility that promotes selective ionic transport. Unoriented and oriented membranes based on dendronized polymers and copolymers obtained by chemical modification of poly[2-(aziridin-1-yl) ethanol] (PAZE) with the dendron 3,4,5-tris[4-( n -dodecan-1-yloxy)benzyloxy]benzoate were considered. DSC, XRD, CP-MAS NMR and DETA, contribute to characterize the tendency to crystallize, the molecular mobility of the benzyloxy substituent, the dendritic liquid crystalline group and the clearing transition. The orientation of the mesogenic chain somewhat hindered this molecular motion, especially in the full substituted PAZE. The fragility, free volume and thermal expansion coefficients of these membranes near the glass transition are related to the orientation and the addition of the dendritic groups. PAZE-based membranes combine both order and mobility on a supramolecular and macroscopic level, controlled by the dendritic group and the thermal orientation, and open the possibility of preparing membranes with proper channel mobility that promotes selective ionic transport. |
Author | Graf, Robert Badia, Jose D Sáenz de Juano-Arbona, Victor Giamberini, Marta Teruel-Juanes, Roberto Reina, Jose A Bogdanowicz, Krzysztof Artur Ribes-Greus, Amparo |
AuthorAffiliation | 4 Max Planck Institute for Polymer Research, Ackermannweg 10, 55021 Mainz, Germany; graf@mpip-mainz.mpg.de 1 Institute of Technology of Materials (ITM), Universitat Politècnica de València (UPV), Camí de Vera s/n, 46022 València, Spain; r.teruel@upvnet.upv.es (R.T.-J.); vsaenzdejuano@gmail.com (V.S.d.J.-A.) 3 Polymer Technology and Sustainability Group, Department of Chemical Engineering, School of Engineering, Universitat de València (UVEG), Avinguda de la Universitat s/n, 46100 Burjassot, Spain; jose.badia@uv.es 2 Department of Chemical Engineering, Universitat Rovira i Virgili (URV), Av. Països Catalans, 26, 43007 Tarragona, Spain; bogdanowicz@witi.wroc.pl (K.A.B.); marta.giamberini@urv.cat (M.G.) 5 Department of Analytical Chemistry and Organic Chemistry, Universitat Rovira i Virgili (URV), C/Marcel·lí Domingo s/n, 43007 Tarragona, Spain; joseantonio.reina@urv.cat |
AuthorAffiliation_xml | – name: 4 Max Planck Institute for Polymer Research, Ackermannweg 10, 55021 Mainz, Germany; graf@mpip-mainz.mpg.de – name: 3 Polymer Technology and Sustainability Group, Department of Chemical Engineering, School of Engineering, Universitat de València (UVEG), Avinguda de la Universitat s/n, 46100 Burjassot, Spain; jose.badia@uv.es – name: 1 Institute of Technology of Materials (ITM), Universitat Politècnica de València (UPV), Camí de Vera s/n, 46022 València, Spain; r.teruel@upvnet.upv.es (R.T.-J.); vsaenzdejuano@gmail.com (V.S.d.J.-A.) – name: 5 Department of Analytical Chemistry and Organic Chemistry, Universitat Rovira i Virgili (URV), C/Marcel·lí Domingo s/n, 43007 Tarragona, Spain; joseantonio.reina@urv.cat – name: 2 Department of Chemical Engineering, Universitat Rovira i Virgili (URV), Av. Països Catalans, 26, 43007 Tarragona, Spain; bogdanowicz@witi.wroc.pl (K.A.B.); marta.giamberini@urv.cat (M.G.) |
Author_xml | – sequence: 1 givenname: Roberto surname: Teruel-Juanes fullname: Teruel-Juanes, Roberto organization: Institute of Technology of Materials (ITM), Universitat Politècnica de València (UPV), Camí de Vera s/n, 46022 València, Spain – sequence: 2 givenname: Krzysztof Artur orcidid: 0000-0001-8526-626X surname: Bogdanowicz fullname: Bogdanowicz, Krzysztof Artur organization: Department of Chemical Engineering, Universitat Rovira i Virgili (URV), Av. Països Catalans, 26, 43007 Tarragona, Spain – sequence: 3 givenname: Jose D orcidid: 0000-0001-8477-1459 surname: Badia fullname: Badia, Jose D organization: Polymer Technology and Sustainability Group, Department of Chemical Engineering, School of Engineering, Universitat de València (UVEG), Avinguda de la Universitat s/n, 46100 Burjassot, Spain – sequence: 4 givenname: Victor surname: Sáenz de Juano-Arbona fullname: Sáenz de Juano-Arbona, Victor organization: Institute of Technology of Materials (ITM), Universitat Politècnica de València (UPV), Camí de Vera s/n, 46022 València, Spain – sequence: 5 givenname: Robert surname: Graf fullname: Graf, Robert organization: Max Planck Institute for Polymer Research, Ackermannweg 10, 55021 Mainz, Germany – sequence: 6 givenname: Jose A surname: Reina fullname: Reina, Jose A organization: Department of Analytical Chemistry and Organic Chemistry, Universitat Rovira i Virgili (URV), C/Marcel·lí Domingo s/n, 43007 Tarragona, Spain – sequence: 7 givenname: Marta orcidid: 0000-0001-8278-3552 surname: Giamberini fullname: Giamberini, Marta organization: Department of Chemical Engineering, Universitat Rovira i Virgili (URV), Av. Països Catalans, 26, 43007 Tarragona, Spain – sequence: 8 givenname: Amparo surname: Ribes-Greus fullname: Ribes-Greus, Amparo organization: Institute of Technology of Materials (ITM), Universitat Politècnica de València (UPV), Camí de Vera s/n, 46022 València, Spain |
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Keywords | dielectric relaxation spectra dendronic liquid crystal membranes macromolecular cooperativity poly[2-(aziridin-1-yl)ethanol] (PAZE) segmental dynamics |
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SubjectTerms | Benzoates Chain dynamics Copolymers Dendritic structure dendronic liquid crystal membranes dielectric relaxation spectra Ethanol Fragility Glass transition Liquid crystals macromolecular cooperativity Membranes Molecular motion Nitrogen NMR spectroscopy Orientation poly[2-(aziridin-1-yl)ethanol] (PAZE) Polymers segmental dynamics Solvents Spectrum analysis Thermal expansion |
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Title | Molecular Mobility in Oriented and Unoriented Membranes Based on Poly[2-(Aziridin-1-yl)ethanol] |
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