Adamantane-Based Micro- and Ultra-Microporous Frameworks for Efficient Small Gas and Toxic Organic Vapor Adsorption

Microporous organic polymers and related porous materials have been applied in a wide range of practical applications such as adsorption, catalysis, adsorption, and sensing fields. However, some limitations, like wide pore size distribution, may limit their further applications, especially for adsor...

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Published inPolymers Vol. 11; no. 3; p. 486
Main Authors Jiang, Wenzhao, Yue, Hangbo, Shuttleworth, Peter S, Xie, Pengbo, Li, Shanji, Guo, Jianwei
Format Journal Article
LanguageEnglish
Published Switzerland MDPI AG 13.03.2019
MDPI
Subjects
adamantane
Adsorption
Alkynes
Benzene
Carbon dioxide
Coupling (molecular)
Hexanes
Hydrocarbons
organic framework
Outdoor air quality
Polymers
Pore size
Pore size distribution
Porous materials
Scanning electron microscopy
Sonogashira-Hagihara coupling
Surface area
Surface chemistry
Thermal stability
ultra-microporosity
Beijing China
China
Germany
adamantane
adsorption
ultra-microporosity
organic framework
Sonogashira-Hagihara coupling
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Abstract Microporous organic polymers and related porous materials have been applied in a wide range of practical applications such as adsorption, catalysis, adsorption, and sensing fields. However, some limitations, like wide pore size distribution, may limit their further applications, especially for adsorption. Here, micro- and ultra-microporous frameworks (HBPBA-D and TBBPA-D) were designed and synthesized via Sonogashira⁻Hagihara coupling of six/eight-arm bromophenyl adamantane-based "knots" and alkynes-type "rod" monomers. The BET surface area and pore size distribution of these frameworks were in the region of 395⁻488 m² g , 0.9⁻1.1 and 0.42 nm, respectively. The as-made prepared frameworks also showed good chemical ability and high thermal stability up to 350 °C, and at 800 °C only 30% mass loss was observed. Their adsorption capacities for small gas molecules such as CO₂ and CH₄ was 8.9⁻9.0 wt % and 1.43⁻1.63 wt % at 273 K/1 bar, and for the toxic organic vapors n-hexane and benzene, 104⁻172 mg g and 144⁻272 mg g at 298 K/0.8 bar, respectively. These are comparable to many porous polymers with higher BET specific surface areas or after functionalization. These properties make the resulting frameworks efficient absorbent alternatives for small gas or toxic vapor capture, especially in harsh environments.
AbstractList Microporous organic polymers and related porous materials have been applied in a wide range of practical applications such as adsorption, catalysis, adsorption, and sensing fields. However, some limitations, like wide pore size distribution, may limit their further applications, especially for adsorption. Here, micro- and ultra-microporous frameworks (HBPBA-D and TBBPA-D) were designed and synthesized via Sonogashira⁻Hagihara coupling of six/eight-arm bromophenyl adamantane-based "knots" and alkynes-type "rod" monomers. The BET surface area and pore size distribution of these frameworks were in the region of 395⁻488 m² g , 0.9⁻1.1 and 0.42 nm, respectively. The as-made prepared frameworks also showed good chemical ability and high thermal stability up to 350 °C, and at 800 °C only 30% mass loss was observed. Their adsorption capacities for small gas molecules such as CO₂ and CH₄ was 8.9⁻9.0 wt % and 1.43⁻1.63 wt % at 273 K/1 bar, and for the toxic organic vapors n-hexane and benzene, 104⁻172 mg g and 144⁻272 mg g at 298 K/0.8 bar, respectively. These are comparable to many porous polymers with higher BET specific surface areas or after functionalization. These properties make the resulting frameworks efficient absorbent alternatives for small gas or toxic vapor capture, especially in harsh environments.
Microporous organic polymers and related porous materials have been applied in a wide range of practical applications such as adsorption, catalysis, adsorption, and sensing fields. However, some limitations, like wide pore size distribution, may limit their further applications, especially for adsorption. Here, micro- and ultra-microporous frameworks (HBPBA-D and TBBPA-D) were designed and synthesized via Sonogashira–Hagihara coupling of six/eight-arm bromophenyl adamantane-based “knots” and alkynes-type “rod” monomers. The BET surface area and pore size distribution of these frameworks were in the region of 395–488 m 2 g −1 , 0.9–1.1 and 0.42 nm, respectively. The as-made prepared frameworks also showed good chemical ability and high thermal stability up to 350 °C, and at 800 °C only 30% mass loss was observed. Their adsorption capacities for small gas molecules such as CO 2 and CH 4 was 8.9–9.0 wt % and 1.43–1.63 wt % at 273 K/1 bar, and for the toxic organic vapors n-hexane and benzene, 104–172 mg g −1 and 144–272 mg g −1 at 298 K/0.8 bar, respectively. These are comparable to many porous polymers with higher BET specific surface areas or after functionalization. These properties make the resulting frameworks efficient absorbent alternatives for small gas or toxic vapor capture, especially in harsh environments.
Microporous organic polymers and related porous materials have been applied in a wide range of practical applications such as adsorption, catalysis, adsorption, and sensing fields. However, some limitations, like wide pore size distribution, may limit their further applications, especially for adsorption. Here, micro- and ultra-microporous frameworks (HBPBA-D and TBBPA-D) were designed and synthesized via Sonogashira-Hagihara coupling of six/eight-arm bromophenyl adamantane-based "knots" and alkynes-type "rod" monomers. The BET surface area and pore size distribution of these frameworks were in the region of 395-488 m2 g−1, 0.9-1.1 and 0.42 nm, respectively. The as-made prepared frameworks also showed good chemical ability and high thermal stability up to 350 °C, and at 800 °C only 30% mass loss was observed. Their adsorption capacities for small gas molecules such as CO2 and CH4 was 8.9-9.0 wt % and 1.43-1.63 wt % at 273 K/1 bar, and for the toxic organic vapors n-hexane and benzene, 104-172 mg g−1 and 144-272 mg g−1 at 298 K/0.8 bar, respectively. These are comparable to many porous polymers with higher BET specific surface areas or after functionalization. These properties make the resulting frameworks efficient absorbent alternatives for small gas or toxic vapor capture, especially in harsh environments.
Author Li, Shanji
Yue, Hangbo
Shuttleworth, Peter S
Guo, Jianwei
Xie, Pengbo
Jiang, Wenzhao
AuthorAffiliation 2 Department of Polymer Physics, Elastomers and Energy, Institute of Polymer Science and Technology, CSIC, 28006 Madrid, Spain; peter@ictp.csic.es
1 School of Chemical Engineering & Light Industry, Guangdong University of Technology, Guangzhou 510006, China; jwz.max@foxmail.com
3 Guangzhou Institute of Technology, Guangzhou 510075, China; xpbty@21cn.com (P.X.); hnlsj2004@163.com (S.L.)
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BackLink https://www.ncbi.nlm.nih.gov/pubmed/30960470$$D View this record in MEDLINE/PubMed
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Cites_doi 10.1016/j.cej.2017.10.133
10.1039/c3cs60160a
10.1039/C6PY02050J
10.1021/acs.jpcc.5b02806
10.1039/C5PY01900A
10.1007/s11426-017-9084-7
10.1002/mawe.200600055
10.1039/C6RA28833B
10.1021/acs.macromol.7b02515
10.1039/c0jm03483e
10.1021/ja9015765
10.1039/C3SC52010B
10.1002/anie.201800218
10.1039/c1ee01971f
10.1021/cm400019f
10.1007/s10853-015-9191-x
10.1002/anie.201607375
10.1016/j.matlet.2016.10.072
10.1039/C5RA11359H
10.1039/C2EE21935B
10.1021/ma1006396
10.1039/C6CS00135A
10.1021/ma101361b
10.1021/jp406918d
10.1016/j.polymer.2015.11.042
10.1021/ma501497c
10.1039/C5PY00295H
10.1002/adma.201101759
10.1016/j.cej.2017.10.160
10.1126/science.aal1585
10.1039/c2py00511e
10.1039/c6py01734g
10.1039/c3ta12324c
10.1039/C6CS00851H
10.1002/adma.201603006
10.1039/C6TA00638H
10.1039/C6RA20765K
10.1039/C4TA04429K
10.1007/128_2009_5
10.1002/marc.201300864
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Keywords adamantane
adsorption
ultra-microporosity
organic framework
Sonogashira-Hagihara coupling
Language English
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References ref13
ref35
ref12
ref34
ref15
ref37
ref14
ref36
ref31
ref30
ref11
ref33
ref10
ref32
ref2
ref1
ref17
ref39
ref16
ref38
ref19
ref18
ref24
ref23
ref26
ref25
ref20
ref22
ref21
ref28
ref27
ref29
ref8
ref7
ref9
ref4
ref3
ref6
ref5
ref40
References_xml – ident: ref27
  doi: 10.1016/j.cej.2017.10.133
– ident: ref9
  doi: 10.1039/c3cs60160a
– ident: ref34
  doi: 10.1039/C6PY02050J
– ident: ref12
  doi: 10.1021/acs.jpcc.5b02806
– ident: ref31
  doi: 10.1039/C5PY01900A
– ident: ref2
  doi: 10.1007/s11426-017-9084-7
– ident: ref25
  doi: 10.1002/mawe.200600055
– ident: ref20
  doi: 10.1039/C6RA28833B
– ident: ref38
  doi: 10.1021/acs.macromol.7b02515
– ident: ref14
  doi: 10.1039/c0jm03483e
– ident: ref11
  doi: 10.1021/ja9015765
– ident: ref15
  doi: 10.1039/C3SC52010B
– ident: ref23
  doi: 10.1002/anie.201800218
– ident: ref13
  doi: 10.1039/c1ee01971f
– ident: ref33
  doi: 10.1021/cm400019f
– ident: ref26
  doi: 10.1007/s10853-015-9191-x
– ident: ref3
  doi: 10.1002/anie.201607375
– ident: ref21
  doi: 10.1016/j.matlet.2016.10.072
– ident: ref32
  doi: 10.1039/C5RA11359H
– ident: ref29
  doi: 10.1039/C2EE21935B
– ident: ref8
  doi: 10.1021/ma1006396
– ident: ref4
  doi: 10.1039/C6CS00135A
– ident: ref17
  doi: 10.1021/ma101361b
– ident: ref28
  doi: 10.1021/jp406918d
– ident: ref30
  doi: 10.1016/j.polymer.2015.11.042
– ident: ref39
  doi: 10.1021/ma501497c
– ident: ref35
  doi: 10.1039/C5PY00295H
– ident: ref19
  doi: 10.1002/adma.201101759
– ident: ref22
  doi: 10.1016/j.cej.2017.10.160
– ident: ref6
  doi: 10.1126/science.aal1585
– ident: ref18
  doi: 10.1039/c2py00511e
– ident: ref24
  doi: 10.1039/c6py01734g
– ident: ref16
  doi: 10.1039/c3ta12324c
– ident: ref7
  doi: 10.1039/C6CS00851H
– ident: ref5
  doi: 10.1002/adma.201603006
– ident: ref10
  doi: 10.1039/C6TA00638H
– ident: ref36
  doi: 10.1039/C6RA20765K
– ident: ref40
  doi: 10.1039/C4TA04429K
– ident: ref1
  doi: 10.1007/128_2009_5
– ident: ref37
  doi: 10.1002/marc.201300864
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StartPage 486
SubjectTerms adamantane
Adsorption
Alkynes
Benzene
Carbon dioxide
Coupling (molecular)
Hexanes
Hydrocarbons
organic framework
Outdoor air quality
Polymers
Pore size
Pore size distribution
Porous materials
Scanning electron microscopy
Sonogashira-Hagihara coupling
Surface area
Surface chemistry
Thermal stability
ultra-microporosity
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Title Adamantane-Based Micro- and Ultra-Microporous Frameworks for Efficient Small Gas and Toxic Organic Vapor Adsorption
URI https://www.ncbi.nlm.nih.gov/pubmed/30960470
https://www.proquest.com/docview/2557230262/abstract/
https://search.proquest.com/docview/2206227959
https://pubmed.ncbi.nlm.nih.gov/PMC6473574
https://doaj.org/article/a9b1a6de771b43dba3fb6b151962141c
Volume 11
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