Hydrolytic Conversion of a Metal-Organic Polyhedron into a Metal-Organic Framework

Twist and release: The metal–organic polyhedron 1 synthesized from 5‐(prop‐2‐ynyloxy)isophthalic acid and Cu(NO3)2⋅ 3 H2O has a hydrophobic outer surface and a hydrophilic inner core. In an aqueous medium, the resulting polarity gradient led to the transformation of 1 into the 2D metal–organic frame...

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Published inAngewandte Chemie International Edition Vol. 52; no. 51; pp. 13755 - 13759
Main Authors Mallick, Arijit, Garai, Bikash, Díaz, David Díaz, Banerjee, Rahul
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag 16.12.2013
WILEY‐VCH Verlag
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Abstract Twist and release: The metal–organic polyhedron 1 synthesized from 5‐(prop‐2‐ynyloxy)isophthalic acid and Cu(NO3)2⋅ 3 H2O has a hydrophobic outer surface and a hydrophilic inner core. In an aqueous medium, the resulting polarity gradient led to the transformation of 1 into the 2D metal–organic framework 2. This unique phenomenon enabled the gradual release of entrapped drug molecules.
AbstractList Twist and release: The metal-organic polyhedron 1 synthesized from 5-(prop-2-ynyloxy)isophthalic acid and Cu(NO3 )2 ⋅ 3 H2 O has a hydrophobic outer surface and a hydrophilic inner core. In an aqueous medium, the resulting polarity gradient led to the transformation of 1 into the 2D metal-organic framework 2. This unique phenomenon enabled the gradual release of entrapped drug molecules.Twist and release: The metal-organic polyhedron 1 synthesized from 5-(prop-2-ynyloxy)isophthalic acid and Cu(NO3 )2 ⋅ 3 H2 O has a hydrophobic outer surface and a hydrophilic inner core. In an aqueous medium, the resulting polarity gradient led to the transformation of 1 into the 2D metal-organic framework 2. This unique phenomenon enabled the gradual release of entrapped drug molecules.
Twist and release: The metal-organic polyhedron 1 synthesized from 5-(prop-2-ynyloxy)isophthalic acid and Cu(NO3 )2 ⋅ 3 H2 O has a hydrophobic outer surface and a hydrophilic inner core. In an aqueous medium, the resulting polarity gradient led to the transformation of 1 into the 2D metal-organic framework 2. This unique phenomenon enabled the gradual release of entrapped drug molecules.
Twist and release: The metal-organic polyhedron 1 synthesized from 5-(prop-2-ynyloxy)isophthalic acid and Cu(NO3 )2 3H2 O has a hydrophobic outer surface and a hydrophilic inner core. In an aqueous medium, the resulting polarity gradient led to the transformation of 1 into the 2D metal-organic framework 2. This unique phenomenon enabled the gradual release of entrapped drug molecules.
Twist and release: The metal–organic polyhedron 1 synthesized from 5‐(prop‐2‐ynyloxy)isophthalic acid and Cu(NO3)2⋅ 3 H2O has a hydrophobic outer surface and a hydrophilic inner core. In an aqueous medium, the resulting polarity gradient led to the transformation of 1 into the 2D metal–organic framework 2. This unique phenomenon enabled the gradual release of entrapped drug molecules.
Twist and release: The metal-organic polyhedron 1 synthesized from 5-(prop-2-ynyloxy)isophthalic acid and Cu(NO sub(3)) sub(2) 3H sub(2)O has a hydrophobic outer surface and a hydrophilic inner core. In an aqueous medium, the resulting polarity gradient led to the transformation of 1 into the 2D metal-organic framework 2. This unique phenomenon enabled the gradual release of entrapped drug molecules.
Author Díaz, David Díaz
Mallick, Arijit
Banerjee, Rahul
Garai, Bikash
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  givenname: David Díaz
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Issue 51
Keywords self-assembly
cage compounds
crystal engineering
hydrophobic effect
metal-organic frameworks
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Notes BRNS - No. 2011/37C/44/BRNS
A.M. acknowledges the CSIR, New Delhi, India for a SRF, and B.G. acknowledges the UGC, New Delhi, India for a JRF. R.B. acknowledges the CSIR Five Year Plan (CSC0122 and CSC0102) for funding. Financial assistance from the BRNS (2011/37C/44/BRNS) is acknowledged.
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These authors contributed equally.
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Snippet Twist and release: The metal–organic polyhedron 1 synthesized from 5‐(prop‐2‐ynyloxy)isophthalic acid and Cu(NO3)2⋅ 3 H2O has a hydrophobic outer surface and a...
Twist and release: The metal-organic polyhedron 1 synthesized from 5-(prop-2-ynyloxy)isophthalic acid and Cu(NO3 )2 ⋅ 3 H2 O has a hydrophobic outer surface...
Twist and release: The metal-organic polyhedron 1 synthesized from 5-(prop-2-ynyloxy)isophthalic acid and Cu(NO3 )2 3H2 O has a hydrophobic outer surface and a...
Twist and release: The metal-organic polyhedron 1 synthesized from 5-(prop-2-ynyloxy)isophthalic acid and Cu(NO sub(3)) sub(2) 3H sub(2)O has a hydrophobic...
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SubjectTerms cage compounds
Conversion
crystal engineering
Drugs
hydrophobic effect
Metal-organic frameworks
Metals
Polarity
Polyhedrons
self-assembly
Transformations
Two dimensional
Title Hydrolytic Conversion of a Metal-Organic Polyhedron into a Metal-Organic Framework
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