Hydrolytic Conversion of a Metal-Organic Polyhedron into a Metal-Organic Framework
Twist and release: The metal–organic polyhedron 1 synthesized from 5‐(prop‐2‐ynyloxy)isophthalic acid and Cu(NO3)2⋅ 3 H2O has a hydrophobic outer surface and a hydrophilic inner core. In an aqueous medium, the resulting polarity gradient led to the transformation of 1 into the 2D metal–organic frame...
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Published in | Angewandte Chemie International Edition Vol. 52; no. 51; pp. 13755 - 13759 |
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Main Authors | , , , |
Format | Journal Article |
Language | English |
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Weinheim
WILEY-VCH Verlag
16.12.2013
WILEY‐VCH Verlag Wiley Subscription Services, Inc |
Edition | International ed. in English |
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Abstract | Twist and release: The metal–organic polyhedron 1 synthesized from 5‐(prop‐2‐ynyloxy)isophthalic acid and Cu(NO3)2⋅ 3 H2O has a hydrophobic outer surface and a hydrophilic inner core. In an aqueous medium, the resulting polarity gradient led to the transformation of 1 into the 2D metal–organic framework 2. This unique phenomenon enabled the gradual release of entrapped drug molecules. |
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AbstractList | Twist and release: The metal-organic polyhedron 1 synthesized from 5-(prop-2-ynyloxy)isophthalic acid and Cu(NO3 )2 ⋅ 3 H2 O has a hydrophobic outer surface and a hydrophilic inner core. In an aqueous medium, the resulting polarity gradient led to the transformation of 1 into the 2D metal-organic framework 2. This unique phenomenon enabled the gradual release of entrapped drug molecules.Twist and release: The metal-organic polyhedron 1 synthesized from 5-(prop-2-ynyloxy)isophthalic acid and Cu(NO3 )2 ⋅ 3 H2 O has a hydrophobic outer surface and a hydrophilic inner core. In an aqueous medium, the resulting polarity gradient led to the transformation of 1 into the 2D metal-organic framework 2. This unique phenomenon enabled the gradual release of entrapped drug molecules. Twist and release: The metal-organic polyhedron 1 synthesized from 5-(prop-2-ynyloxy)isophthalic acid and Cu(NO3 )2 ⋅ 3 H2 O has a hydrophobic outer surface and a hydrophilic inner core. In an aqueous medium, the resulting polarity gradient led to the transformation of 1 into the 2D metal-organic framework 2. This unique phenomenon enabled the gradual release of entrapped drug molecules. Twist and release: The metal-organic polyhedron 1 synthesized from 5-(prop-2-ynyloxy)isophthalic acid and Cu(NO3 )2 3H2 O has a hydrophobic outer surface and a hydrophilic inner core. In an aqueous medium, the resulting polarity gradient led to the transformation of 1 into the 2D metal-organic framework 2. This unique phenomenon enabled the gradual release of entrapped drug molecules. Twist and release: The metal–organic polyhedron 1 synthesized from 5‐(prop‐2‐ynyloxy)isophthalic acid and Cu(NO3)2⋅ 3 H2O has a hydrophobic outer surface and a hydrophilic inner core. In an aqueous medium, the resulting polarity gradient led to the transformation of 1 into the 2D metal–organic framework 2. This unique phenomenon enabled the gradual release of entrapped drug molecules. Twist and release: The metal-organic polyhedron 1 synthesized from 5-(prop-2-ynyloxy)isophthalic acid and Cu(NO sub(3)) sub(2) 3H sub(2)O has a hydrophobic outer surface and a hydrophilic inner core. In an aqueous medium, the resulting polarity gradient led to the transformation of 1 into the 2D metal-organic framework 2. This unique phenomenon enabled the gradual release of entrapped drug molecules. |
Author | Díaz, David Díaz Mallick, Arijit Banerjee, Rahul Garai, Bikash |
Author_xml | – sequence: 1 givenname: Arijit surname: Mallick fullname: Mallick, Arijit organization: Physical/Materials Chemistry Division, CSIR-National Chemical Laboratory, Dr. Homi Bhabha Road, Pune-411008 (India) – sequence: 2 givenname: Bikash surname: Garai fullname: Garai, Bikash organization: Physical/Materials Chemistry Division, CSIR-National Chemical Laboratory, Dr. Homi Bhabha Road, Pune-411008 (India) – sequence: 3 givenname: David Díaz surname: Díaz fullname: Díaz, David Díaz organization: Institut für Organische Chemie, Universität Regensburg, Universitätsstrasse 31, 93040 Regensburg (Germany) – sequence: 4 givenname: Rahul surname: Banerjee fullname: Banerjee, Rahul email: r.banerjee@ncl.res.in organization: Physical/Materials Chemistry Division, CSIR-National Chemical Laboratory, Dr. Homi Bhabha Road, Pune-411008 (India) |
BackLink | https://www.ncbi.nlm.nih.gov/pubmed/24346950$$D View this record in MEDLINE/PubMed |
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Copyright | Copyright © 2013 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim |
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Keywords | self-assembly cage compounds crystal engineering hydrophobic effect metal-organic frameworks |
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Notes | BRNS - No. 2011/37C/44/BRNS A.M. acknowledges the CSIR, New Delhi, India for a SRF, and B.G. acknowledges the UGC, New Delhi, India for a JRF. R.B. acknowledges the CSIR Five Year Plan (CSC0122 and CSC0102) for funding. Financial assistance from the BRNS (2011/37C/44/BRNS) is acknowledged. ArticleID:ANIE201307486 CSIR, New Delhi, India ark:/67375/WNG-GTTTHTBW-S istex:07EE59C69CA4AEB033914C6BF46ACF975AE6B0A2 UGC, New Delhi, India These authors contributed equally. ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 14 content type line 23 |
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Snippet | Twist and release: The metal–organic polyhedron 1 synthesized from 5‐(prop‐2‐ynyloxy)isophthalic acid and Cu(NO3)2⋅ 3 H2O has a hydrophobic outer surface and a... Twist and release: The metal-organic polyhedron 1 synthesized from 5-(prop-2-ynyloxy)isophthalic acid and Cu(NO3 )2 ⋅ 3 H2 O has a hydrophobic outer surface... Twist and release: The metal-organic polyhedron 1 synthesized from 5-(prop-2-ynyloxy)isophthalic acid and Cu(NO3 )2 3H2 O has a hydrophobic outer surface and a... Twist and release: The metal-organic polyhedron 1 synthesized from 5-(prop-2-ynyloxy)isophthalic acid and Cu(NO sub(3)) sub(2) 3H sub(2)O has a hydrophobic... |
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SubjectTerms | cage compounds Conversion crystal engineering Drugs hydrophobic effect Metal-organic frameworks Metals Polarity Polyhedrons self-assembly Transformations Two dimensional |
Title | Hydrolytic Conversion of a Metal-Organic Polyhedron into a Metal-Organic Framework |
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