Flexible Dimensional Control of High-Capacity Li-Ion-Battery Anodes: From 0D Hollow to 3D Porous Germanium Nanoparticle Assemblies

Simple physical blending of SiO2 and ethyl‐capped Ge gels leads to flexible dimensional control of Ge nanoparticles, and an increasing weight fraction of the latter leads to ordered 3D porous nanoparticle assemblies (see figure). The long‐range ordering of the 3D porous Ge nanoparticles and their ve...

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Published inAdvanced materials (Weinheim) Vol. 22; no. 3; pp. 415 - 418
Main Authors Park, Mi-Hee, Kim, Kitae, Kim, Jeyoung, Cho, Jaephil
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag 19.01.2010
WILEY‐VCH Verlag
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Abstract Simple physical blending of SiO2 and ethyl‐capped Ge gels leads to flexible dimensional control of Ge nanoparticles, and an increasing weight fraction of the latter leads to ordered 3D porous nanoparticle assemblies (see figure). The long‐range ordering of the 3D porous Ge nanoparticles and their very thin pore wall thicknesses (<20 nm) induce excellent cycling performance, showing only a 2% capacity decrease after 100 cycles.
AbstractList Simple physical blending of SiO2 and ethyl-capped Ge gels leads to flexible dimensional control of Ge nanoparticles, and an increasing weight fraction of the latter leads to ordered 3D porous nanoparticle assemblies (see figure). The long-range ordering of the 3D porous Ge nanoparticles and their very thin pore wall thicknesses ( < 20 nm) induce excellent cycling performance, showing only a 2% capacity decrease after 100 cycles.
Author Kim, Jeyoung
Park, Mi-Hee
Kim, Kitae
Cho, Jaephil
Author_xml – sequence: 1
  givenname: Mi-Hee
  surname: Park
  fullname: Park, Mi-Hee
  organization: School of Energy Engineering and Converging Research Center for Innovative Battery Technologies Ulsan National Institute of Science & Technology 689-798 Ulsan (Korea)
– sequence: 2
  givenname: Kitae
  surname: Kim
  fullname: Kim, Kitae
  organization: Battery R&D, LG Chem, Ltd. 104-1 Moonji-dong, Yuseong-gu, Daejeon 305-380 (Korea)
– sequence: 3
  givenname: Jeyoung
  surname: Kim
  fullname: Kim, Jeyoung
  organization: Battery R&D, LG Chem, Ltd. 104-1 Moonji-dong, Yuseong-gu, Daejeon 305-380 (Korea)
– sequence: 4
  givenname: Jaephil
  surname: Cho
  fullname: Cho, Jaephil
  email: jpcho@unist.ac.kr
  organization: School of Energy Engineering and Converging Research Center for Innovative Battery Technologies Ulsan National Institute of Science & Technology 689-798 Ulsan (Korea)
BackLink https://www.ncbi.nlm.nih.gov/pubmed/20217731$$D View this record in MEDLINE/PubMed
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Snippet Simple physical blending of SiO2 and ethyl‐capped Ge gels leads to flexible dimensional control of Ge nanoparticles, and an increasing weight fraction of the...
Simple physical blending of SiO2 and ethyl-capped Ge gels leads to flexible dimensional control of Ge nanoparticles, and an increasing weight fraction of the...
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SubjectTerms batteries
Electric Power Supplies
Electrodes
Germanium - chemistry
Lithium - chemistry
nanoparticles
Nanoparticles - chemistry
Nanoparticles - ultrastructure
Porosity
Title Flexible Dimensional Control of High-Capacity Li-Ion-Battery Anodes: From 0D Hollow to 3D Porous Germanium Nanoparticle Assemblies
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