Vanadium in Borosilicate Glass

Understanding the role of V2O5 within borosilicate glass matrices is important for the development of novel matrices toward immobilization of sulfate containing high‐level nuclear wastes. Present investigation shows, within sodium barium borosilicate glass matrix V2O5 can be homogeneously added up t...

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Published inJournal of the American Ceramic Society Vol. 98; no. 1; pp. 88 - 96
Main Authors Sengupta, Pranesh, Dey, Krishna K., Halder, Rumu, Ajithkumar, Thalasseril G., Abraham, Geogy, Mishra, Raman K., Kaushik, Chetan P., Dey, Goutam K.
Format Journal Article
LanguageEnglish
Published Columbus Blackwell Publishing Ltd 01.01.2015
Wiley Subscription Services, Inc
Subjects
Addition polymerization
Borates
Borosilicate glasses
Ceramics
Glass
Networks
NMR
Nuclear magnetic resonance
Polymers
Silica
Silicates
Vanadium
Vanadium pentoxide
Online AccessGet full text
ISSN0002-7820
1551-2916
DOI10.1111/jace.13303

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Abstract Understanding the role of V2O5 within borosilicate glass matrices is important for the development of novel matrices toward immobilization of sulfate containing high‐level nuclear wastes. Present investigation shows, within sodium barium borosilicate glass matrix V2O5 can be homogeneously added up to 5 mol% and beyond which it separates out into three phases, for example, (i) silica (ii) Barium (Ba) – Vanadium (V) oxide, and (iii) glass matrix. 29Si MAS NMR (Nuclear Magnetic Resonance) studies of the samples show that below 5 mol% V2O5 addition, silicate network is dominantly constituted of Q2 and Q3 structural units, whereas above this, the network gets more polymerized through formation of Q3 and Q4 units. In case of borate network, 11B MAS NMR investigations revealed that the concentration of BO4 [(0B, 4Si)] unit increases gradually up to 5 mol% and then it decreases at the cost of BO4 [(1B, 3Si)], BO3 (symmetric) and BO3 (asymmetric) units. Micro‐Raman analyses of the samples showed that with additions of V2O5 in diluted concentrations, amorphous silicate network remained unaltered, whereas some amplification in signals corresponding to ring‐type metaborate and VO5 units exists. It is therefore apparent from both MAS‐NMR and micro‐Raman studies that with V2O5 additions within the solubility limit (≤5 mol%), borate network gets depolymerized leading to decrease in hardness from an average value of 5.0–4.2 GPa.
AbstractList Understanding the role of ... within borosilicate glass matrices is important for the development of novel matrices toward immobilization of sulfate containing high-level nuclear wastes. Present investigation shows, within sodium barium borosilicate glass matrix ... can be homogeneously added up to 5 mol% and beyond which it separates out into three phases, for example, (i) silica (ii) Barium (Ba) -- Vanadium (V) oxide, and (iii) glass matrix. 29Si MAS NMR (Nuclear Magnetic Resonance) studies of the samples show that below 5 mol% ... addition, silicate network is dominantly constituted of Q2 and Q3 structural units, whereas above this, the network gets more polymerized through formation of Q3 and Q4 units. In case of borate network, 11B MAS NMR investigations revealed that the concentration of BO4 [(0B, 4Si)] unit increases gradually up to 5 mol% and then it decreases at the cost of BO4 [(1B, 3Si)], BO3 (symmetric) and BO3 (asymmetric) units. Micro-Raman analyses of the samples showed that with additions of ... in diluted concentrations, amorphous silicate network remained unaltered, whereas some amplification in signals corresponding to ring-type metaborate and VO5 units exists. It is therefore apparent from both MAS-NMR and micro-Raman studies that with ... additions within the solubility limit (≤5 mol%), borate network gets depolymerized leading to decrease in hardness from an average value of 5.0-4.2 GPa. (ProQuest: ... denotes formulae/symbols omitted.)
Understanding the role of V 2 O 5 within borosilicate glass matrices is important for the development of novel matrices toward immobilization of sulfate containing high‐level nuclear wastes. Present investigation shows, within sodium barium borosilicate glass matrix V 2 O 5 can be homogeneously added up to 5 mol% and beyond which it separates out into three phases, for example, (i) silica (ii) Barium (Ba) – Vanadium (V) oxide, and (iii) glass matrix. 29 Si MAS NMR (Nuclear Magnetic Resonance) studies of the samples show that below 5 mol% V 2 O 5 addition, silicate network is dominantly constituted of Q 2 and Q 3 structural units, whereas above this, the network gets more polymerized through formation of Q 3 and Q 4 units. In case of borate network, 11 B MAS NMR investigations revealed that the concentration of BO 4 [(0B, 4Si)] unit increases gradually up to 5 mol% and then it decreases at the cost of BO 4 [(1B, 3Si)], BO 3 (symmetric) and BO 3 (asymmetric) units. Micro‐Raman analyses of the samples showed that with additions of V 2 O 5 in diluted concentrations, amorphous silicate network remained unaltered, whereas some amplification in signals corresponding to ring‐type metaborate and VO 5 units exists. It is therefore apparent from both MAS ‐ NMR and micro‐Raman studies that with V 2 O 5 additions within the solubility limit (≤5 mol%), borate network gets depolymerized leading to decrease in hardness from an average value of 5.0–4.2 GPa.
Understanding the role of V2O5 within borosilicate glass matrices is important for the development of novel matrices toward immobilization of sulfate containing high-level nuclear wastes. Present investigation shows, within sodium barium borosilicate glass matrix V2O5 can be homogeneously added up to 5 mol% and beyond which it separates out into three phases, for example, (i) silica (ii) Barium (Ba) - Vanadium (V) oxide, and (iii) glass matrix. 29Si MAS NMR (Nuclear Magnetic Resonance) studies of the samples show that below 5 mol% V2O5 addition, silicate network is dominantly constituted of Q2 and Q3 structural units, whereas above this, the network gets more polymerized through formation of Q3 and Q4 units. In case of borate network, 11B MAS NMR investigations revealed that the concentration of BO4 [(0B, 4Si)] unit increases gradually up to 5 mol% and then it decreases at the cost of BO4 [(1B, 3Si)], BO3 (symmetric) and BO3 (asymmetric) units. Micro-Raman analyses of the samples showed that with additions of V2O5 in diluted concentrations, amorphous silicate network remained unaltered, whereas some amplification in signals corresponding to ring-type metaborate and VO5 units exists. It is therefore apparent from both MAS-NMR and micro-Raman studies that with V2O5 additions within the solubility limit ( less than or equal to 5 mol%), borate network gets depolymerized leading to decrease in hardness from an average value of 5.0-4.2 GPa.
Understanding the role of V2O5 within borosilicate glass matrices is important for the development of novel matrices toward immobilization of sulfate containing high‐level nuclear wastes. Present investigation shows, within sodium barium borosilicate glass matrix V2O5 can be homogeneously added up to 5 mol% and beyond which it separates out into three phases, for example, (i) silica (ii) Barium (Ba) – Vanadium (V) oxide, and (iii) glass matrix. 29Si MAS NMR (Nuclear Magnetic Resonance) studies of the samples show that below 5 mol% V2O5 addition, silicate network is dominantly constituted of Q2 and Q3 structural units, whereas above this, the network gets more polymerized through formation of Q3 and Q4 units. In case of borate network, 11B MAS NMR investigations revealed that the concentration of BO4 [(0B, 4Si)] unit increases gradually up to 5 mol% and then it decreases at the cost of BO4 [(1B, 3Si)], BO3 (symmetric) and BO3 (asymmetric) units. Micro‐Raman analyses of the samples showed that with additions of V2O5 in diluted concentrations, amorphous silicate network remained unaltered, whereas some amplification in signals corresponding to ring‐type metaborate and VO5 units exists. It is therefore apparent from both MAS‐NMR and micro‐Raman studies that with V2O5 additions within the solubility limit (≤5 mol%), borate network gets depolymerized leading to decrease in hardness from an average value of 5.0–4.2 GPa.
Author Sengupta, Pranesh
Dey, Goutam K.
Dey, Krishna K.
Halder, Rumu
Mishra, Raman K.
Kaushik, Chetan P.
Abraham, Geogy
Ajithkumar, Thalasseril G.
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  organization: Materials Science Division, Bhabha Atomic Research Centre, 400 085, Mumbai, India
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Cites_doi 10.1016/S0016-7037(01)00775-X
10.1016/j.jnucmat.2005.11.012
10.1021/ja00310a004
10.1515/9781501509384-008
10.1016/S0022-3093(96)00596-0
10.1016/S0926-2040(00)00050-3
10.1021/ic3016832
10.1016/S0022-3093(02)00945-6
10.1016/j.jnoncrysol.2007.02.013
10.1016/0022-3093(83)90032-7
10.1016/0022-3697(93)90242-J
10.1016/0191-815X(84)90045-7
10.1021/ic010305u
10.1111/j.1551-2916.2008.02773.x
10.1080/01418619108204878
10.1007/BF02402831
10.1016/j.jhazmat.2011.03.031
10.1016/S0022-3093(99)00693-6
10.1016/j.jnucmat.2006.07.004
10.1016/j.jnoncrysol.2009.05.015
10.1016/0038-1098(82)90329-5
10.1016/j.jnoncrysol.2006.09.041
10.1016/0022-3093(75)90137-4
10.2138/rmg.2011.73.6
10.1021/jp961439
10.2172/890179
10.1179/174367606X81669
10.1016/j.jnoncrysol.2007.04.029
10.1016/0025-5408(94)90004-3
10.1021/jp100530m
10.1016/0022-2860(93)80349-Z
10.1515/9781501509384-007
10.1016/0022-3093(76)90132-0
10.1002/jrs.2763
10.1021/ja00109a026
10.1016/S0022-3115(01)00591-8
10.1016/0167-577X(95)00148-4
10.1016/S0022-3093(99)00352-X
10.1007/s11661-005-0201-5
10.1111/j.1551-2916.2007.01853.x
10.1016/j.jnucmat.2006.09.012
10.1088/0953-8984/14/25/322
10.1016/j.gca.2004.08.029
10.1007/978-3-642-32917-3_2
10.1016/0022-3093(90)90823-5
10.1021/cm1006058
10.1016/j.jhazmat.2012.07.039
10.1016/j.chemgeo.2008.07.002
10.1016/j.jnoncrysol.2006.02.085
10.1080/13642818908209739
10.1016/j.jnucmat.2012.08.012
10.1002/jrs.1250120110
10.1016/j.jnucmat.2011.01.122
10.2172/219300
10.1016/j.jnoncrysol.2003.08.070
10.1023/A:1018646507438
10.1021/jp034048l
10.1016/S0022-3093(97)00491-2
10.1021/jp993416b
10.1016/B978-0-08-056033-5.00107-5
10.2172/145022
10.1007/978-1-4615-9107-8_7
10.1016/S0022-3093(01)00624-X
10.1016/j.jnucmat.2008.07.046
10.1016/S0022-2860(96)09674-3
10.1016/j.jnucmat.2007.08.005
10.1016/0025-5408(78)90173-3
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References C. P. Kaushik, R. K. Mishra, P. Sengupta, D. Das, G. B. Kale, and K. Raj, "Barium Borosilicate Glass: A Potential Matrix for Immobilization of Sulfate Bearing High Level Radioactive Waste," J. Nucl. Mater., 358, 129-38 (2006).
R. S. Dutta, C. Yusufali, B. Paul, S. Majumdar, P. Sengupta, R. K. Mishra, C. P. Kaushik, R. J. Kshirsagar, U. D. Kulkarni, and G. K. Dey, "Formation of Diffusion Barrier Coating on Superalloy 690 Substrate and its Stability in Borosilicate Melt at Elevated Temperature," J. Nucl. Mater., 432, 72-7 (2013).
B. A. Moyer, R. Custelcean, B. P. Hay, J. L. Sessler, K. B. James, V. W. Day, and S. O. Kang, "A Case for Molecular Recognition in Nuclear Separations: Sulphate Separation from Nuclear Wastes," Inorg. Chem., 52, 3473-90 (2013).
N. Janes and E. Oldfield, "Prediction of Silicon-29 Nuclear Magnetic Resonance Chemical Shifts Using a Group Electronegativity Approach: Applications to Silicate and Aluminosilicate Structures," J. Am. Chem. Soc., 107, 6769-75 (1985).
C. Martineau, V. K. Michaelis, S. Schiller, and S. Kroeker, "Liquid−Liquid Phase Separation in Model Nuclear Waste Glasses: A Solid-State Double-Resonance NMR Study," Chem. Mater., 22, 4896-903 (2010).
D. Maniu, I. Ardelean, and T. Iliescu, "Raman Spectroscopic Investigations of the Structure of XV2O5 1−x [3B2O3 -K2O] Glasses," Mater. Lett., 25 [3-4] 147-9 (1995).
V. Pirlet, "Overview of Actinides Np, Pu, Am and Tc Release from Waste Glasses: Influence of Solution Composition," J. Nucl. Mater., 298, 47-54 (2001).
D. W. Matson, S. K. Sharma, and J. A. Philpotts, "The Structure of High-Silica Alkali-Silicate Glasses. A Raman Spectroscopic Investigation," J. Non-Cryst. Solids, 58 [2-3] 323-52 (1983).
P. Sengupta, C. P. Kaushik, R. K. Mishra, and G. B. Kale, "Microstructural Characterization and Role of Glassy Layer Developed on Process Pot Wall During Nuclear High Level Waste Vitrification Process," J. Amer. Ceram. Soc., 90, 3085-90 (2007).
P. Sengupta, "Interaction Study Between Nuclear Waste Glass Melt and Ceramic Melter Bellow Liner Materials," J. Nucl. Mater., 411, 181-4 (2011).
E. Vernaz, S. Gin, and C. Veyer, "Waste Glass," Comprehensive Nucl.Mater, 5, 451-83 (2012).
M. Lenoir, A. Grandjean, S. Poissonnet, and D. R. Neuville, "Quantitation of Sulfate Solubility in Borosilicate Glasses Using Raman Spectroscopy," J. Non Crys. Solids, 355, 1468-73 (2009).
T. Yazawa, K. Kuraoka, T. Akai, N. Umesaki, and W. F. Du, "Clarification of Phase Separation Mechanism of Sodium Borosilicate Glasses in Early Stage by Nuclear Magnetic Resonance," J. Phys. Chem. B, 104 [9] 2109-16 (2000).
S. Prasad, T. M. Clark, T. H. Sefzik, H. T. Kwak, Z. Gan, and P. J. Grandinetti, "Solid State Multinuclear Magnetic Resonance Investigation of Pyrex," J. Non-Cryst. Solids, 352, 2834-40 (2006).
P. M. Aguiar and S. Kroeker, "Boron Speciation and Non-Bridging Oxygens in High-Alkali Borate Glasses," J. Non-Cryst. Solids, 353 [18-21] 1834-9 (2007).
T. Iliescu, S. Simon, D. Maniu, and I. Ardelean, "Raman Spectroscopy of Oxide Glass System 1−x [YB2O3.ZLi2O].XGd2O3," J. Mol. Struct., 294, 201-3 (1992).
D. Maniu, I. Ardelean, T. Iliescu, S. Cinta, and O. Cozar, "Raman Spectroscopic Investigations of the Oxide Glass System 1−x 3B2O3·K2O xMO MO = V2O5 or Cu," J. Mol. Struct., 410-411, 291-4 (1997).
P. Sengupta, N. Soudamini, C. P. Kaushik, Jagannath, R. K. Mishra, G. B. Kale, K. Raj, D. Das, and B. P. Sharma, "Corrosion of Alloy 690 Process Pot by Sulfate Containing High Level Radioactive Waste at Feed Stage," J. Nucl. Mater., 374, 185-91 (2008).
B. N. Meera, A. K. Sood, N. Chandrabhas, and J. Ramakrishna, "Raman Study of Lead Borate Glasses," J. Non-Cryst. Solids, 126 [3] 224-30 (1990).
K. Raj and C. P. Kaushik, "Glass Matrices for Vitrification of Radioactive Waste- An Update on R&D Efforts," ISSTGM-2009. IOP Conf Series: Mater. Sci. Engg., 2, 1-6 (2009).
K. A. Smith, R. J. Kirkpatrick, E. Oldfield, and D. M. Henderson, "High Resolution Si NMR Spectroscopic Study of Rock Forming Silicates," Am. Miner., 68, 1206-15 (1983).
P. Sengupta, D. Rogalla, H. W. Becker, G. K. Dey, and S. Chakraborty, "Development of Graded Ni-YSZ Composite Coating on Alloy 690 by Pulsed Laser Deposition Technique to Reduce Hazardous Metallic Nuclear Waste Inventory," J. Hazar. Mater., 192, 208-21 (2011).
A. D. Pelton and P. Wu, "Thermodynamic Modelling of Glass Forming Melts," J. Non-Cryst. Solids, 253, 178-91 (1999).
M. Lenoir, A. Grandjean, Y. Linard, B. Cochain, and D. R. Neuville, "The Influence of Si, B Substitution and the Nature of Network Modifying Cations on the Properties and Structure of Borosilicate Glasses and Melts," Chem. Geo., 256, 316-25 (2008).
B. P. Dwivedi, M. H. Rahman, Y. Kumar, and B. N. Khanna, "Raman Scattering Study of Lithium Borate Glasses," J. Phys. Chem. Solids, 54 [5] 621-8 (1993).
G. L. Turner, K. Smith, R. J. Kirkpatrick, and E. Oldfield, "Boron-11 Nuclear Magnetic Resonance Spectroscopic Study of Borate and Borosilicate Minerals and a Borosilicate Glass," J. Magn. Reson., 67 [3] 544-50 (1986).
D. Manara, A. Grandjean, O. Pinet, J. L. Dussossoy, and D. R. Neuville, "Sulfur Behavior in Silicate Glasses and Melts: Implications for Sulfate Incorporation in Nuclear Waste Glasses as a Function of Alkali Cation and V2O5 Content," J. Non-Cryst. Solids, 353, 12-23 (2007).
C. Sanchez, J. Livage, and G. Lucazeau, "Infrared and Raman Study of Amorphous V2O5," J. Raman Spectrosc., 12 [1] 68-72 (1982).
D. de Waal and C. Huter, "Vibrational Spectra of Two Phases of Copper Pyrovanadate and Some Solid Solutions of Copper and Magnesium Pyrovanadate," Mater. Res. Bull., 29 [8] 843-9 (1994).
P. Sengupta, "A Review on Immobilization of Phosphate Containing High Level Nuclear Wastes Within Glass Matrix - Present Status and Future Challenges," J. Hazar. Mater., 235-236, 17-28 (2012).
B. C. Bunker, D. R. Tellant, R. J. Kirkpatrick, and G. I. Turner, "Multinuclear Nuclear Magnetic Resonance and Raman Investigation of Sodium Borosilicate Glass Structures," Phys. Chem. Glasses, 31 [1] 30-41 (1990).
I. W. Donald, B. L. Metcalfe, and J. R. N. Taylor, "Review: The Immobilization of High Level Radioactive Wastes Using Ceramics and Glasses," J. Mater. Sci., 32 851-87 (1997).
V. K. Michaelis, P. M. Aguiar, and S. Kroeker, "Probing Alkali Coordination Environments in Alkali Borate Glasses by Multinuclear Magnetic Resonance," J. Non-Cryst. Solids, 353 [26] 2582-90 (2007).
J. F. Stebbins, P. Zhao, and S. Kroeker, "Non-Bridging Oxygens in Borate Glasses: Characterization by 11B and 17O MAS and 3QMAS NMR," Solid State Nucl. Magn. Reson., 16 [1-2] 9-19 (2000).
V. Sudarsan, V. K. Shrikhande, G. P. Kothiyal, and S. K. Kulshreshtha, "Structural Aspects of B2O3-Substituted (PbO)0.5(SiO2)0.5 Glasses," J. Phys.: Condens. Matter, 14, 6553-65 (2002).
L. Backnaes and J. Deubener, "Experimental Studies on Sulfur Solubility in Silicate Melts at Near Atmospheric Pressure," Rev. Miner. Geochem., 73, 143-65 (2011).
M. D. Ingram, "Ionic Conductivity and Glass Structure," Philos. Mag. B, 60 [6] 729-40 (1989).
R. G. C. Beerkens and K. Kahl, "Chemistry of Sulphur in Soda-Lime-Silica Glass Melts," Phys. Chem. Glasses, 43 [4] 189-98 (2002).
P. Sengupta, J. Mittra, and G. B. Kale, "Interaction Between Borosilicate Melt and Inconel," J. Nucl. Mater., 350, 66-73 (2006).
L. S. Du and J. F. Stebbins, "Nature of Silicon−Boron Mixing in Sodium Borosilicate Glasses:  A High-Resolution 11B and 17O NMR Study," J. Phys. Chem. B, 107 [37] 10063-76 (2003).
R. Martens and W. Muller-Warmuth, "Structural Groups and Their Mixing in Borosilicate Glasses of Various Compositions - An NMR Study," J. Non-Cryst. Solids, 265, 167-75 (2000).
S. Kroeker and J. F. Stebbins, "Three-Coordinated Boron-11 Chemical Shifts in Borates," Inorg. Chem., 40, 6239-46 (2001).
Y. Dimitrev and V. Dimitrov, "X-Ray Diffraction Studies of Glasses in the TeO2-V2O5 System," Mater. Res. Bull., 13, 1071-5 (1978).
W. E. Lee, M. I. Ojovan, and M. C. Stennett, "Immobilization of Radioactive Waste in Glasses, Glass Composite," Mater. Ceram. Adv. Appl. Ceram., 105, 3-12 (2006).
O. Attos, M. Massot, M. Balkanski, E. Haro-Poniatowski, and M. Asomoza, "Structure of Borovandate Glasses Studied by Raman Spectroscopy," J. Non-Cryst. Solids, 210 [2-3] 163-70 (1997).
F. I. Galeneer, "Planar Rings in Glasses," Solid State Commun., 44 [7] 1037-40 (1982).
R. K. Mishra, P. Sengupta, C. P. Kaushik, A. K. Tyagi, G. B. Kale, and K. Raj, "Studies on Immobilization of Thorium in Barium Borosilicate Glass," J. Nucl. Mater., 360, 143-50 (2007).
T. Furukawa and W. B. White, "Raman Spectroscopic Investigation of Sodium Borosilicate Glass Structure," J. Mat. Sci., 16, 2689-700 (1981).
M. I. Ojovan and W. E. Lee, An Introduction to Nuclear Waste Immobilization. Elseiver, Amsterdam, the Netherlands, 2005.
V. Kain, P. Sengupta, P. K. De, and S. Banerjee, "Case Reviews on the Effect of Microstructure on the Corrosion Behavior of Austenitic Alloys for Processing and Storage of Nuclear Waste," Metall. Mater. Trans. A, 36A, 1075-84 (2005).
D. A. McKeown, I. S. Muller, H. Gan, I. L. Pegg, and C. A. Kendizora, "Raman Studies of Sulfur in Borosilicate Waste Glasses: Sulfate Environments," J. Non-Cryst. Solids, 288 [1-3] 191-9 (2001).
S. Sen, Z. Xu, and J. F. Stebbins, "Temperature Dependent Structural Changes in Borate, Borosilicate and Boroaluminate Liquids: High-Resolution 11B, 29Si and 27Al NMR Studies," J. Non-Cryst. Solids, 226 [1-2] 29-40 (1998).
T. Tsujimura, X. Xue, M. Kanzaki, and M. J. Walker, "Sulfur Speciation and Network Structural Changes in Sodium Silicate Glasses: Constraints from NMR and Raman Spectroscopy," Geochim. Cosmochim. Acta, 68 [24] 5081-101 (2004).
T. W. Bril, "Raman Spectroscopy of Crystalline and Vitreous Borates," Philips Res. Rept. Suppl, 2, 117-23 (1976).
R. K. Mishra, V. Sudarsan, P. Sengupta, R. K. Vatsa, A. K. Tyagi, C. P. Kaushik, D. Das, and K. Raj, "Role of Sulphate in Structural Modifications of Sodium Barium Borosilicate Glasses Developed for Nuclear Waste Immobilization," J. Am. Ceram. Soc., 91, 3903-7 (2008).
S. K. Le
1982; 12
1976; 20
2002; 14
1995; 32
2004; 68
1975; 18
1997; 410–411
2009; 355
2011; 192
2009; 392
1996; 100
2011; 190
1994; 29
2001; 40
1979
1983; 58
2001; 298
2010; 22
1989; 31
2000; 16
1995; 25
2010; 114
2011; 73
2002; 43
2013; 52
1986
1999; 253
2013; 432
2012; 235–236
1983; 68
2011; 411
1989; 60
1990; 31
2001; 288
1990; 126
2007; 360
2002; 298
1997; 210
2006; 350
1995; 117
1976; 2
2007; 90
2007
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2006; 352
1995
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2004
1985; 107
1978; 13
2006; 358
2003; 331
2008; 91
2003; 107
1992; 294
1997; 32
2000; 104
1986; 67
1999; 38
2007; 353
1991; 64
1993; 54
1984; 5
2002; 66
1982; 44
2011; 42
1981; 16
2005; 36A
2000; 265
2013
1998; 226
2008; 256
2006; 105
2009; 2
2008; 374
2012; 5
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Navrotsky A. (e_1_2_5_49_1) 1995
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Janetzen C. (e_1_2_5_7_1) 1986
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e_1_2_5_40_1
Ojovan M. I. (e_1_2_5_6_1) 2007
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Stefanovskii S. V. (e_1_2_5_37_1) 1995
e_1_2_5_55_1
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e_1_2_5_3_1
Bunker B. C. (e_1_2_5_72_1) 1990; 31
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Jantzen C. M. (e_1_2_5_38_1) 1986
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Ewing R. C. (e_1_2_5_10_1) 1999
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Ojovan M. I. (e_1_2_5_5_1) 2005
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Beerkens R. G. C. (e_1_2_5_41_1) 2002; 43
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Sengupta P. (e_1_2_5_18_1) 2011; 192
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Turner G. L. (e_1_2_5_63_1) 1986; 67
Smith K. A. (e_1_2_5_43_1) 1983; 68
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References_xml – reference: V. Sudarsan, V. K. Shrikhande, G. P. Kothiyal, and S. K. Kulshreshtha, "Structural Aspects of B2O3-Substituted (PbO)0.5(SiO2)0.5 Glasses," J. Phys.: Condens. Matter, 14, 6553-65 (2002).
– reference: R. G. C. Beerkens and K. Kahl, "Chemistry of Sulphur in Soda-Lime-Silica Glass Melts," Phys. Chem. Glasses, 43 [4] 189-98 (2002).
– reference: T. Yazawa, K. Kuraoka, T. Akai, N. Umesaki, and W. F. Du, "Clarification of Phase Separation Mechanism of Sodium Borosilicate Glasses in Early Stage by Nuclear Magnetic Resonance," J. Phys. Chem. B, 104 [9] 2109-16 (2000).
– reference: R. K. Mishra, P. Sengupta, C. P. Kaushik, A. K. Tyagi, G. B. Kale, and K. Raj, "Studies on Immobilization of Thorium in Barium Borosilicate Glass," J. Nucl. Mater., 360, 143-50 (2007).
– reference: K. A. Smith, R. J. Kirkpatrick, E. Oldfield, and D. M. Henderson, "High Resolution Si NMR Spectroscopic Study of Rock Forming Silicates," Am. Miner., 68, 1206-15 (1983).
– reference: D. Maniu, I. Ardelean, T. Iliescu, S. Cinta, and O. Cozar, "Raman Spectroscopic Investigations of the Oxide Glass System 1−x 3B2O3·K2O xMO MO = V2O5 or Cu," J. Mol. Struct., 410-411, 291-4 (1997).
– reference: E. Vernaz, S. Gin, and C. Veyer, "Waste Glass," Comprehensive Nucl.Mater, 5, 451-83 (2012).
– reference: V. K. Michaelis, P. M. Aguiar, and S. Kroeker, "Probing Alkali Coordination Environments in Alkali Borate Glasses by Multinuclear Magnetic Resonance," J. Non-Cryst. Solids, 353 [26] 2582-90 (2007).
– reference: D. A. McKeown, I. S. Muller, H. Gan, I. L. Pegg, and C. A. Kendizora, "Raman Studies of Sulfur in Borosilicate Waste Glasses: Sulfate Environments," J. Non-Cryst. Solids, 288 [1-3] 191-9 (2001).
– reference: L. S. Du and J. F. Stebbins, "Nature of Silicon−Boron Mixing in Sodium Borosilicate Glasses:  A High-Resolution 11B and 17O NMR Study," J. Phys. Chem. B, 107 [37] 10063-76 (2003).
– reference: B. C. Bunker, D. R. Tellant, R. J. Kirkpatrick, and G. I. Turner, "Multinuclear Nuclear Magnetic Resonance and Raman Investigation of Sodium Borosilicate Glass Structures," Phys. Chem. Glasses, 31 [1] 30-41 (1990).
– reference: V. Pirlet, "Overview of Actinides Np, Pu, Am and Tc Release from Waste Glasses: Influence of Solution Composition," J. Nucl. Mater., 298, 47-54 (2001).
– reference: R. E. Youngman and J. W. Zwanziger, "On the Formation of Tetracoordinate Boron in Rubidium Borate Glasses," J. Am. Chem. Soc., 117 [4] 1397-402 (1995).
– reference: C. P. Kaushik, R. K. Mishra, P. Sengupta, D. Das, G. B. Kale, and K. Raj, "Barium Borosilicate Glass: A Potential Matrix for Immobilization of Sulfate Bearing High Level Radioactive Waste," J. Nucl. Mater., 358, 129-38 (2006).
– reference: D. Maniu, I. Ardelean, and T. Iliescu, "Raman Spectroscopic Investigations of the Structure of XV2O5 1−x [3B2O3 -K2O] Glasses," Mater. Lett., 25 [3-4] 147-9 (1995).
– reference: W. L. Konijnendijk and J. M. Stevels, "The Structure of Borosilicate Glasses Studied by Raman Scattering," J. Non-Cryst. Solids, 20 [2] 193-224 (1976).
– reference: T. Furukawa and W. B. White, "Raman Spectroscopic Investigation of Sodium Borosilicate Glass Structure," J. Mat. Sci., 16, 2689-700 (1981).
– reference: D. A. McKeown, I. S. Muller, H. Gan, and I. L. Pegg, "X-Ray Absorption Studies of Vanadium Valence and Local Environment in Borosilicate Waste Glasses Using Vanadium Sulfide, Silicate, and Oxide Standards," J. Non-Cryst. Solids, 298, 160-75 (2002).
– reference: M. C. Davis, D. C. Kaseman, S. M. Parvani, K. J. Sanders, P. J. Grandinetti, D. Massiot, and P. Florian, "Q n Species Distribution in K2O·2SiO2 Glass by 29Si Magic Angle Flipping NMR," J. Phys. Chem. A, 114 [17] 5503-8 (2010).
– reference: P. Sengupta, "A Review on Immobilization of Phosphate Containing High Level Nuclear Wastes Within Glass Matrix - Present Status and Future Challenges," J. Hazar. Mater., 235-236, 17-28 (2012).
– reference: W. E. Lee, M. I. Ojovan, and M. C. Stennett, "Immobilization of Radioactive Waste in Glasses, Glass Composite," Mater. Ceram. Adv. Appl. Ceram., 105, 3-12 (2006).
– reference: M. I. Ojovan and W. E. Lee, An Introduction to Nuclear Waste Immobilization. Elseiver, Amsterdam, the Netherlands, 2005.
– reference: P. Sengupta, "Interaction Study Between Nuclear Waste Glass Melt and Ceramic Melter Bellow Liner Materials," J. Nucl. Mater., 411, 181-4 (2011).
– reference: C. Sanchez, J. Livage, and G. Lucazeau, "Infrared and Raman Study of Amorphous V2O5," J. Raman Spectrosc., 12 [1] 68-72 (1982).
– reference: P. Sengupta, D. Rogalla, H. W. Becker, G. K. Dey, and S. Chakraborty, "Development of Graded Ni-YSZ Composite Coating on Alloy 690 by Pulsed Laser Deposition Technique to Reduce Hazardous Metallic Nuclear Waste Inventory," J. Hazar. Mater., 192, 208-21 (2011).
– reference: G. N. Greaves, S. J. Gurman, C. R. A. Catlow, A. V. Chadwick, S. Houde-Walter, C. M. B. Henderson, and B. R. Dobson, "A Structural Basis for Ionic Diffusion in Oxide Glasses," Philos. Mag. A, 64, 1059-72 (1991).
– reference: S. V. Stefanovskii, F. A. Livanov, and A. N. Gulin, Scientific Basis for Nuclear Waste Management, vol. XVIII, pp. 101-6. Materials Research Society, Pittsburgh, PA, 1995.
– reference: D. W. Matson, S. K. Sharma, and J. A. Philpotts, "The Structure of High-Silica Alkali-Silicate Glasses. A Raman Spectroscopic Investigation," J. Non-Cryst. Solids, 58 [2-3] 323-52 (1983).
– reference: I. W. Donald, B. L. Metcalfe, and J. R. N. Taylor, "Review: The Immobilization of High Level Radioactive Wastes Using Ceramics and Glasses," J. Mater. Sci., 32 851-87 (1997).
– reference: R. Martens and W. Muller-Warmuth, "Structural Groups and Their Mixing in Borosilicate Glasses of Various Compositions - An NMR Study," J. Non-Cryst. Solids, 265, 167-75 (2000).
– reference: M. I. Ojovan and W. E. Lee, New Developments in Glassy Nuclear Wasteforms. Nova Science Pub Inc., New York, 2007.
– reference: P. Sengupta, J. Mittra, and G. B. Kale, "Interaction Between Borosilicate Melt and Inconel," J. Nucl. Mater., 350, 66-73 (2006).
– reference: N. Trcera, S. Rossano, and M. Tarrida, "Structural Study of Mg-Bearing Sodosilicate Glasses by Raman Spectroscopy," J. Raman Spect., 42, 765-72 (2011).
– reference: G. L. Turner, K. Smith, R. J. Kirkpatrick, and E. Oldfield, "Boron-11 Nuclear Magnetic Resonance Spectroscopic Study of Borate and Borosilicate Minerals and a Borosilicate Glass," J. Magn. Reson., 67 [3] 544-50 (1986).
– reference: T. Iliescu, S. Simon, D. Maniu, and I. Ardelean, "Raman Spectroscopy of Oxide Glass System 1−x [YB2O3.ZLi2O].XGd2O3," J. Mol. Struct., 294, 201-3 (1992).
– reference: D. Manara, A. Grandjean, O. Pinet, J. L. Dussossoy, and D. R. Neuville, "Sulfur Behavior in Silicate Glasses and Melts: Implications for Sulfate Incorporation in Nuclear Waste Glasses as a Function of Alkali Cation and V2O5 Content," J. Non-Cryst. Solids, 353, 12-23 (2007).
– reference: R. S. Dutta, C. Yusufali, B. Paul, S. Majumdar, P. Sengupta, R. K. Mishra, C. P. Kaushik, R. J. Kshirsagar, U. D. Kulkarni, and G. K. Dey, "Formation of Diffusion Barrier Coating on Superalloy 690 Substrate and its Stability in Borosilicate Melt at Elevated Temperature," J. Nucl. Mater., 432, 72-7 (2013).
– reference: V. Kain, P. Sengupta, P. K. De, and S. Banerjee, "Case Reviews on the Effect of Microstructure on the Corrosion Behavior of Austenitic Alloys for Processing and Storage of Nuclear Waste," Metall. Mater. Trans. A, 36A, 1075-84 (2005).
– reference: S. V. Stefanovskii and F. A. Livanov, "Glasses for Immobilization of Sulfate Containing Radioactive Wastes," Radiokhimiya, 31, 129-34 (1989).
– reference: W. L. Konijnendijk and J. M. Stevels, "The Structure of Borate Glasses Studied by Raman Scattering," J. Non-Cryst. Solids, 18 [3] 307-31 (1975).
– reference: S. Sen, Z. Xu, and J. F. Stebbins, "Temperature Dependent Structural Changes in Borate, Borosilicate and Boroaluminate Liquids: High-Resolution 11B, 29Si and 27Al NMR Studies," J. Non-Cryst. Solids, 226 [1-2] 29-40 (1998).
– reference: D. de Waal and C. Huter, "Vibrational Spectra of Two Phases of Copper Pyrovanadate and Some Solid Solutions of Copper and Magnesium Pyrovanadate," Mater. Res. Bull., 29 [8] 843-9 (1994).
– reference: P. Sengupta, C. P. Kaushik, R. K. Mishra, and G. B. Kale, "Microstructural Characterization and Role of Glassy Layer Developed on Process Pot Wall During Nuclear High Level Waste Vitrification Process," J. Amer. Ceram. Soc., 90, 3085-90 (2007).
– reference: P. Sengupta, N. Soudamini, C. P. Kaushik, Jagannath, R. K. Mishra, G. B. Kale, K. Raj, D. Das, and B. P. Sharma, "Corrosion of Alloy 690 Process Pot by Sulfate Containing High Level Radioactive Waste at Feed Stage," J. Nucl. Mater., 374, 185-91 (2008).
– reference: M. D. Ingram, "Ionic Conductivity and Glass Structure," Philos. Mag. B, 60 [6] 729-40 (1989).
– reference: M. Lenoir, A. Grandjean, S. Poissonnet, and D. R. Neuville, "Quantitation of Sulfate Solubility in Borosilicate Glasses Using Raman Spectroscopy," J. Non Crys. Solids, 355, 1468-73 (2009).
– reference: P. Sengupta, S. Fanara, and S. Chakraborty, "Preliminary Study on Calcium Aluminosilicate Glass as a Potential Host Matrix for Radioactive 90Sr - An Approach Based on Natural Analogue Study," J. Hazar. Mater., 190, 229-39 (2011).
– reference: P. M. Aguiar and S. Kroeker, "Boron Speciation and Non-Bridging Oxygens in High-Alkali Borate Glasses," J. Non-Cryst. Solids, 353 [18-21] 1834-9 (2007).
– reference: F. I. Galeneer, "Planar Rings in Glasses," Solid State Commun., 44 [7] 1037-40 (1982).
– reference: S. K. Lee and J. F. Stebbins, "Extent of Intermixing Among Framework Units in Silicate Glasses and Melts," Geochim. Cosmochim. Acta, 66 [2] 303-9 (2002).
– reference: T. Tsujimura, X. Xue, M. Kanzaki, and M. J. Walker, "Sulfur Speciation and Network Structural Changes in Sodium Silicate Glasses: Constraints from NMR and Raman Spectroscopy," Geochim. Cosmochim. Acta, 68 [24] 5081-101 (2004).
– reference: L. L. Hench, D. E. Clark, and J. Campbell, "High Level Waste Immobilization Forms," Nucl. Chem. Waste Mgt., 5 149-73 (1984).
– reference: Y. Dimitrev and V. Dimitrov, "X-Ray Diffraction Studies of Glasses in the TeO2-V2O5 System," Mater. Res. Bull., 13, 1071-5 (1978).
– reference: K. Raj and C. P. Kaushik, "Glass Matrices for Vitrification of Radioactive Waste- An Update on R&D Efforts," ISSTGM-2009. IOP Conf Series: Mater. Sci. Engg., 2, 1-6 (2009).
– reference: S. Kroeker and J. F. Stebbins, "Three-Coordinated Boron-11 Chemical Shifts in Borates," Inorg. Chem., 40, 6239-46 (2001).
– reference: L. Backnaes and J. Deubener, "Experimental Studies on Sulfur Solubility in Silicate Melts at Near Atmospheric Pressure," Rev. Miner. Geochem., 73, 143-65 (2011).
– reference: C. W. Kim and D. E. Day, "Immobilization of Hanford LAW in Iron Phosphate Glasses," J. Non-Cryst. Solids, 331 [1-3] 20-31 (2003).
– reference: M. Lenoir, A. Grandjean, Y. Linard, B. Cochain, and D. R. Neuville, "The Influence of Si, B Substitution and the Nature of Network Modifying Cations on the Properties and Structure of Borosilicate Glasses and Melts," Chem. Geo., 256, 316-25 (2008).
– reference: R. E. Youngman and J. W. Zwanziger, "Network Modification in Potassium Borate Glasses: Structural Studies with NMR and Raman Spectroscopies," J. Phys. Chem., 100 [41] 16720-8 (1996).
– reference: A. D. Pelton and P. Wu, "Thermodynamic Modelling of Glass Forming Melts," J. Non-Cryst. Solids, 253, 178-91 (1999).
– reference: N. Janes and E. Oldfield, "Prediction of Silicon-29 Nuclear Magnetic Resonance Chemical Shifts Using a Group Electronegativity Approach: Applications to Silicate and Aluminosilicate Structures," J. Am. Chem. Soc., 107, 6769-75 (1985).
– reference: B. N. Meera, A. K. Sood, N. Chandrabhas, and J. Ramakrishna, "Raman Study of Lead Borate Glasses," J. Non-Cryst. Solids, 126 [3] 224-30 (1990).
– reference: B. A. Moyer, R. Custelcean, B. P. Hay, J. L. Sessler, K. B. James, V. W. Day, and S. O. Kang, "A Case for Molecular Recognition in Nuclear Separations: Sulphate Separation from Nuclear Wastes," Inorg. Chem., 52, 3473-90 (2013).
– reference: R. K. Mishra, V. Sudarsan, P. Sengupta, R. K. Vatsa, A. K. Tyagi, C. P. Kaushik, D. Das, and K. Raj, "Role of Sulphate in Structural Modifications of Sodium Barium Borosilicate Glasses Developed for Nuclear Waste Immobilization," J. Am. Ceram. Soc., 91, 3903-7 (2008).
– reference: O. Attos, M. Massot, M. Balkanski, E. Haro-Poniatowski, and M. Asomoza, "Structure of Borovandate Glasses Studied by Raman Spectroscopy," J. Non-Cryst. Solids, 210 [2-3] 163-70 (1997).
– reference: C. Martineau, V. K. Michaelis, S. Schiller, and S. Kroeker, "Liquid−Liquid Phase Separation in Model Nuclear Waste Glasses: A Solid-State Double-Resonance NMR Study," Chem. Mater., 22, 4896-903 (2010).
– reference: P. Sengupta, C. P. Kaushik, G. B. Kale, D. Das, K. Raj, and B. P. Sharma, "Evaluation of Alloy 690 Process Pot at the Contact with Borosilicate Melt Pool During Vitrification of High Level Nuclear Waste," J. Nucl. Mater., 392, 379-85 (2009).
– reference: B. P. Dwivedi, M. H. Rahman, Y. Kumar, and B. N. Khanna, "Raman Scattering Study of Lithium Borate Glasses," J. Phys. Chem. Solids, 54 [5] 621-8 (1993).
– reference: J. F. Stebbins, P. Zhao, and S. Kroeker, "Non-Bridging Oxygens in Borate Glasses: Characterization by 11B and 17O MAS and 3QMAS NMR," Solid State Nucl. Magn. Reson., 16 [1-2] 9-19 (2000).
– reference: S. Prasad, T. M. Clark, T. H. Sefzik, H. T. Kwak, Z. Gan, and P. J. Grandinetti, "Solid State Multinuclear Magnetic Resonance Investigation of Pyrex," J. Non-Cryst. Solids, 352, 2834-40 (2006).
– reference: T. W. Bril, "Raman Spectroscopy of Crystalline and Vitreous Borates," Philips Res. Rept. Suppl, 2, 117-23 (1976).
– volume: 353
  start-page: 1834
  issue: 18–21
  year: 2007
  end-page: 9
  article-title: Boron Speciation and Non‐Bridging Oxygens in High‐Alkali Borate Glasses
  publication-title: J. Non‐Cryst. Solids
– volume: 331
  start-page: 20
  issue: 1–3
  year: 2003
  end-page: 31
  article-title: Immobilization of Hanford LAW in Iron Phosphate Glasses
  publication-title: J. Non‐Cryst. Solids
– volume: 60
  start-page: 729
  issue: 6
  year: 1989
  end-page: 40
  article-title: Ionic Conductivity and Glass Structure
  publication-title: Philos. Mag. B
– volume: 29
  start-page: 843
  issue: 8
  year: 1994
  end-page: 9
  article-title: Vibrational Spectra of Two Phases of Copper Pyrovanadate and Some Solid Solutions of Copper and Magnesium Pyrovanadate
  publication-title: Mater. Res. Bull.
– volume: 117
  start-page: 1397
  issue: 4
  year: 1995
  end-page: 402
  article-title: On the Formation of Tetracoordinate Boron in Rubidium Borate Glasses
  publication-title: J. Am. Chem. Soc.
– start-page: 57
  year: 1979
  end-page: 68
– volume: 353
  start-page: 12
  year: 2007
  end-page: 23
  article-title: Sulfur Behavior in Silicate Glasses and Melts: Implications for Sulfate Incorporation in Nuclear Waste Glasses as a Function of Alkali Cation and V O Content
  publication-title: J. Non‐Cryst. Solids
– year: 2005
– volume: 32
  start-page: 121
  year: 1995
  end-page: 43
– volume: 105
  start-page: 3
  year: 2006
  end-page: 12
  article-title: Immobilization of Radioactive Waste in Glasses, Glass Composite
  publication-title: Mater. Ceram. Adv. Appl. Ceram.
– volume: 73
  start-page: 143
  year: 2011
  end-page: 65
  article-title: Experimental Studies on Sulfur Solubility in Silicate Melts at Near Atmospheric Pressure
  publication-title: Rev. Miner. Geochem.
– volume: 32
  start-page: 851
  year: 1997
  end-page: 87
  article-title: Review: The Immobilization of High Level Radioactive Wastes Using Ceramics and Glasses
  publication-title: J. Mater. Sci.
– volume: 58
  start-page: 323
  issue: 2–3
  year: 1983
  end-page: 52
  article-title: The Structure of High‐Silica Alkali‐Silicate Glasses. A Raman Spectroscopic Investigation
  publication-title: J. Non‐Cryst. Solids
– volume: 38
  start-page: 1
  year: 1999
  end-page: 22
– volume: 42
  start-page: 765
  year: 2011
  end-page: 72
  article-title: Structural Study of Mg‐Bearing Sodosilicate Glasses by Raman Spectroscopy
  publication-title: J. Raman Spect.
– volume: 90
  start-page: 3085
  year: 2007
  end-page: 90
  article-title: Microstructural Characterization and Role of Glassy Layer Developed on Process Pot Wall During Nuclear High Level Waste Vitrification Process
  publication-title: J. Amer. Ceram. Soc.
– volume: 32
  start-page: 145
  year: 1995
  end-page: 90
– volume: 256
  start-page: 316
  year: 2008
  end-page: 25
  article-title: The Influence of Si, B Substitution and the Nature of Network Modifying Cations on the Properties and Structure of Borosilicate Glasses and Melts
  publication-title: Chem. Geo.
– start-page: 157
  year: 1986
  end-page: 65
– year: 1994
– volume: 192
  start-page: 208
  year: 2011
  end-page: 21
  article-title: Development of Graded Ni‐YSZ Composite Coating on Alloy 690 by Pulsed Laser Deposition Technique to Reduce Hazardous Metallic Nuclear Waste Inventory
  publication-title: J. Hazar. Mater.
– volume: 410–411
  start-page: 291
  year: 1997
  end-page: 4
  article-title: Raman Spectroscopic Investigations of the Oxide Glass System 1− 3B O ·K O MO MO = V O or Cu
  publication-title: J. Mol. Struct.
– volume: 68
  start-page: 1206
  year: 1983
  end-page: 15
  article-title: High Resolution Si NMR Spectroscopic Study of Rock Forming Silicates
  publication-title: Am. Miner.
– volume: 114
  start-page: 5503
  issue: 17
  year: 2010
  end-page: 8
  article-title: Species Distribution in K O·2SiO Glass by Si Magic Angle Flipping NMR
  publication-title: J. Phys. Chem. A
– volume: 432
  start-page: 72
  year: 2013
  end-page: 7
  article-title: Formation of Diffusion Barrier Coating on Superalloy 690 Substrate and its Stability in Borosilicate Melt at Elevated Temperature
  publication-title: J. Nucl. Mater.
– start-page: 25
  year: 2013
  end-page: 51
– year: 2004
– volume: 288
  start-page: 191
  issue: 1–3
  year: 2001
  end-page: 9
  article-title: Raman Studies of Sulfur in Borosilicate Waste Glasses: Sulfate Environments
  publication-title: J. Non‐Cryst. Solids
– volume: 360
  start-page: 143
  year: 2007
  end-page: 50
  article-title: Studies on Immobilization of Thorium in Barium Borosilicate Glass
  publication-title: J. Nucl. Mater.
– volume: 52
  start-page: 3473
  year: 2013
  end-page: 90
  article-title: A Case for Molecular Recognition in Nuclear Separations: Sulphate Separation from Nuclear Wastes
  publication-title: Inorg. Chem.
– volume: 353
  start-page: 2582
  issue: 26
  year: 2007
  end-page: 90
  article-title: Probing Alkali Coordination Environments in Alkali Borate Glasses by Multinuclear Magnetic Resonance
  publication-title: J. Non‐Cryst. Solids
– volume: 5
  start-page: 451
  year: 2012
  end-page: 83
  article-title: Waste Glass
  publication-title: Comprehensive Nucl.Mater
– volume: 67
  start-page: 544
  issue: 3
  year: 1986
  end-page: 50
  article-title: Boron‐11 Nuclear Magnetic Resonance Spectroscopic Study of Borate and Borosilicate Minerals and a Borosilicate Glass
  publication-title: J. Magn. Reson.
– volume: 20
  start-page: 193
  issue: 2
  year: 1976
  end-page: 224
  article-title: The Structure of Borosilicate Glasses Studied by Raman Scattering
  publication-title: J. Non‐Cryst. Solids
– volume: 235–236
  start-page: 17
  year: 2012
  end-page: 28
  article-title: A Review on Immobilization of Phosphate Containing High Level Nuclear Wastes Within Glass Matrix ‐ Present Status and Future Challenges
  publication-title: J. Hazar. Mater.
– volume: 22
  start-page: 4896
  year: 2010
  end-page: 903
  article-title: Liquid−Liquid Phase Separation in Model Nuclear Waste Glasses: A Solid‐State Double‐Resonance NMR Study
  publication-title: Chem. Mater.
– volume: 265
  start-page: 167
  year: 2000
  end-page: 75
  article-title: Structural Groups and Their Mixing in Borosilicate Glasses of Various Compositions – An NMR Study
  publication-title: J. Non‐Cryst. Solids
– volume: 355
  start-page: 1468
  year: 2009
  end-page: 73
  article-title: Quantitation of Sulfate Solubility in Borosilicate Glasses Using Raman Spectroscopy
  publication-title: J. Non Crys. Solids
– volume: 12
  start-page: 68
  issue: 1
  year: 1982
  end-page: 72
  article-title: Infrared and Raman Study of Amorphous V O
  publication-title: J. Raman Spectrosc.
– volume: 91
  start-page: 3903
  year: 2008
  end-page: 7
  article-title: Role of Sulphate in Structural Modifications of Sodium Barium Borosilicate Glasses Developed for Nuclear Waste Immobilization
  publication-title: J. Am. Ceram. Soc.
– volume: 392
  start-page: 379
  year: 2009
  end-page: 85
  article-title: Evaluation of Alloy 690 Process Pot at the Contact with Borosilicate Melt Pool During Vitrification of High Level Nuclear Waste
  publication-title: J. Nucl. Mater.
– volume: 36A
  start-page: 1075
  year: 2005
  end-page: 84
  article-title: Case Reviews on the Effect of Microstructure on the Corrosion Behavior of Austenitic Alloys for Processing and Storage of Nuclear Waste
  publication-title: Metall. Mater. Trans. A
– volume: 358
  start-page: 129
  year: 2006
  end-page: 38
  article-title: Barium Borosilicate Glass: A Potential Matrix for Immobilization of Sulfate Bearing High Level Radioactive Waste
  publication-title: J. Nucl. Mater.
– volume: 25
  start-page: 147
  issue: 3–4
  year: 1995
  end-page: 9
  article-title: Raman Spectroscopic Investigations of the Structure of V O 1− [3B O ‐K O] Glasses
  publication-title: Mater. Lett.
– year: 2007
– volume: 100
  start-page: 16720
  issue: 41
  year: 1996
  end-page: 8
  article-title: Network Modification in Potassium Borate Glasses: Structural Studies with NMR and Raman Spectroscopies
  publication-title: J. Phys. Chem.
– volume: 16
  start-page: 9
  issue: 1–2
  year: 2000
  end-page: 19
  article-title: Non‐Bridging Oxygens in Borate Glasses: Characterization by B and O MAS and 3QMAS NMR
  publication-title: Solid State Nucl. Magn. Reson.
– year: 1996
– volume: 5
  start-page: 149
  year: 1984
  end-page: 73
  article-title: High Level Waste Immobilization Forms
  publication-title: Nucl. Chem. Waste Mgt.
– volume: 16
  start-page: 2689
  year: 1981
  end-page: 700
  article-title: Raman Spectroscopic Investigation of Sodium Borosilicate Glass Structure
  publication-title: J. Mat. Sci.
– volume: 66
  start-page: 303
  issue: 2
  year: 2002
  end-page: 9
  article-title: Extent of Intermixing Among Framework Units in Silicate Glasses and Melts
  publication-title: Geochim. Cosmochim. Acta
– volume: 226
  start-page: 29
  issue: 1–2
  year: 1998
  end-page: 40
  article-title: Temperature Dependent Structural Changes in Borate, Borosilicate and Boroaluminate Liquids: High‐Resolution B, Si and Al NMR Studies
  publication-title: J. Non‐Cryst. Solids
– volume: 18
  start-page: 307
  issue: 3
  year: 1975
  end-page: 31
  article-title: The Structure of Borate Glasses Studied by Raman Scattering
  publication-title: J. Non‐Cryst. Solids
– volume: 40
  start-page: 6239
  year: 2001
  end-page: 46
  article-title: Three‐Coordinated Boron‐11 Chemical Shifts in Borates
  publication-title: Inorg. Chem.
– volume: 374
  start-page: 185
  year: 2008
  end-page: 91
  article-title: Corrosion of Alloy 690 Process Pot by Sulfate Containing High Level Radioactive Waste at Feed Stage
  publication-title: J. Nucl. Mater.
– volume: 352
  start-page: 2834
  year: 2006
  end-page: 40
  article-title: Solid State Multinuclear Magnetic Resonance Investigation of Pyrex
  publication-title: J. Non‐Cryst. Solids
– volume: 31
  start-page: 30
  issue: 1
  year: 1990
  end-page: 41
  article-title: Multinuclear Nuclear Magnetic Resonance and Raman Investigation of Sodium Borosilicate Glass Structures
  publication-title: Phys. Chem. Glasses
– volume: 253
  start-page: 178
  year: 1999
  end-page: 91
  article-title: Thermodynamic Modelling of Glass Forming Melts
  publication-title: J. Non‐Cryst. Solids
– volume: 54
  start-page: 621
  issue: 5
  year: 1993
  end-page: 8
  article-title: Raman Scattering Study of Lithium Borate Glasses
  publication-title: J. Phys. Chem. Solids
– volume: 107
  start-page: 6769
  year: 1985
  end-page: 75
  article-title: Prediction of Silicon‐29 Nuclear Magnetic Resonance Chemical Shifts Using a Group Electronegativity Approach: Applications to Silicate and Aluminosilicate Structures
  publication-title: J. Am. Chem. Soc.
– volume: 43
  start-page: 189
  issue: 4
  year: 2002
  end-page: 98
  article-title: Chemistry of Sulphur in Soda–Lime–Silica Glass Melts
  publication-title: Phys. Chem. Glasses
– volume: 104
  start-page: 2109
  issue: 9
  year: 2000
  end-page: 16
  article-title: Clarification of Phase Separation Mechanism of Sodium Borosilicate Glasses in Early Stage by Nuclear Magnetic Resonance
  publication-title: J. Phys. Chem. B
– volume: 107
  start-page: 10063
  issue: 37
  year: 2003
  end-page: 76
  article-title: Nature of Silicon−Boron Mixing in Sodium Borosilicate Glasses:  A High‐Resolution B and O NMR Study
  publication-title: J. Phys. Chem. B
– volume: 126
  start-page: 224
  issue: 3
  year: 1990
  end-page: 30
  article-title: Raman Study of Lead Borate Glasses
  publication-title: J. Non‐Cryst. Solids
– volume: 13
  start-page: 1071
  year: 1978
  end-page: 5
  article-title: X‐Ray Diffraction Studies of Glasses in the TeO ‐V O System
  publication-title: Mater. Res. Bull.
– volume: 210
  start-page: 163
  issue: 2–3
  year: 1997
  end-page: 70
  article-title: Structure of Borovandate Glasses Studied by Raman Spectroscopy
  publication-title: J. Non‐Cryst. Solids
– volume: 294
  start-page: 201
  year: 1992
  end-page: 3
  article-title: Raman Spectroscopy of Oxide Glass System 1−x [YB O .ZLi O].XGd O
  publication-title: J. Mol. Struct.
– volume: 298
  start-page: 160
  year: 2002
  end-page: 75
  article-title: X‐Ray Absorption Studies of Vanadium Valence and Local Environment in Borosilicate Waste Glasses Using Vanadium Sulfide, Silicate, and Oxide Standards
  publication-title: J. Non‐Cryst. Solids
– volume: 2
  start-page: 1
  year: 2009
  end-page: 6
  article-title: Glass Matrices for Vitrification of Radioactive Waste‐ An Update on R&D Efforts
  publication-title: ISSTGM‐2009. IOP Conf Series: Mater. Sci. Engg.
– volume: 350
  start-page: 66
  year: 2006
  end-page: 73
  article-title: Interaction Between Borosilicate Melt and Inconel
  publication-title: J. Nucl. Mater.
– start-page: 101
  year: 1995
  end-page: 6
– volume: 411
  start-page: 181
  year: 2011
  end-page: 4
  article-title: Interaction Study Between Nuclear Waste Glass Melt and Ceramic Melter Bellow Liner Materials
  publication-title: J. Nucl. Mater.
– volume: 31
  start-page: 129
  year: 1989
  end-page: 34
  article-title: Glasses for Immobilization of Sulfate Containing Radioactive Wastes
  publication-title: Radiokhimiya
– volume: 64
  start-page: 1059
  year: 1991
  end-page: 72
  article-title: A Structural Basis for Ionic Diffusion in Oxide Glasses
  publication-title: Philos. Mag. A
– volume: 190
  start-page: 229
  year: 2011
  end-page: 39
  article-title: Preliminary Study on Calcium Aluminosilicate Glass as a Potential Host Matrix for Radioactive Sr – An Approach Based on Natural Analogue Study
  publication-title: J. Hazar. Mater.
– volume: 68
  start-page: 5081
  issue: 24
  year: 2004
  end-page: 101
  article-title: Sulfur Speciation and Network Structural Changes in Sodium Silicate Glasses: Constraints from NMR and Raman Spectroscopy
  publication-title: Geochim. Cosmochim. Acta
– volume: 2
  start-page: 117
  year: 1976
  end-page: 23
  article-title: Raman Spectroscopy of Crystalline and Vitreous Borates
  publication-title: Philips Res. Rept. Suppl
– volume: 14
  start-page: 6553
  year: 2002
  end-page: 65
  article-title: Structural Aspects of B O ‐Substituted (PbO) (SiO ) Glasses
  publication-title: J. Phys.: Condens. Matter
– volume: 298
  start-page: 47
  year: 2001
  end-page: 54
  article-title: Overview of Actinides Np, Pu, Am and Tc Release from Waste Glasses: Influence of Solution Composition
  publication-title: J. Nucl. Mater.
– volume: 44
  start-page: 1037
  issue: 7
  year: 1982
  end-page: 40
  article-title: Planar Rings in Glasses
  publication-title: Solid State Commun.
– ident: e_1_2_5_55_1
  doi: 10.1016/S0016-7037(01)00775-X
– ident: e_1_2_5_12_1
– start-page: 157
  volume-title: Nuclear Waste Management
  year: 1986
  ident: e_1_2_5_38_1
– ident: e_1_2_5_23_1
  doi: 10.1016/j.jnucmat.2005.11.012
– ident: e_1_2_5_44_1
  doi: 10.1021/ja00310a004
– ident: e_1_2_5_50_1
  doi: 10.1515/9781501509384-008
– volume: 43
  start-page: 189
  issue: 4
  year: 2002
  ident: e_1_2_5_41_1
  article-title: Chemistry of Sulphur in Soda–Lime–Silica Glass Melts
  publication-title: Phys. Chem. Glasses
– ident: e_1_2_5_69_1
  doi: 10.1016/S0022-3093(96)00596-0
– ident: e_1_2_5_53_1
  doi: 10.1016/S0926-2040(00)00050-3
– volume: 67
  start-page: 544
  issue: 3
  year: 1986
  ident: e_1_2_5_63_1
  article-title: Boron‐11 Nuclear Magnetic Resonance Spectroscopic Study of Borate and Borosilicate Minerals and a Borosilicate Glass
  publication-title: J. Magn. Reson.
– ident: e_1_2_5_25_1
  doi: 10.1021/ic3016832
– ident: e_1_2_5_39_1
  doi: 10.1016/S0022-3093(02)00945-6
– ident: e_1_2_5_60_1
  doi: 10.1016/j.jnoncrysol.2007.02.013
– ident: e_1_2_5_66_1
  doi: 10.1016/0022-3093(83)90032-7
– ident: e_1_2_5_74_1
  doi: 10.1016/0022-3697(93)90242-J
– ident: e_1_2_5_3_1
  doi: 10.1016/0191-815X(84)90045-7
– ident: e_1_2_5_54_1
  doi: 10.1021/ic010305u
– ident: e_1_2_5_31_1
  doi: 10.1111/j.1551-2916.2008.02773.x
– ident: e_1_2_5_46_1
  doi: 10.1080/01418619108204878
– ident: e_1_2_5_80_1
  doi: 10.1007/BF02402831
– ident: e_1_2_5_29_1
  doi: 10.1016/j.jhazmat.2011.03.031
– ident: e_1_2_5_56_1
  doi: 10.1016/S0022-3093(99)00693-6
– ident: e_1_2_5_30_1
  doi: 10.1016/j.jnucmat.2006.07.004
– ident: e_1_2_5_70_1
  doi: 10.1016/j.jnoncrysol.2009.05.015
– ident: e_1_2_5_73_1
  doi: 10.1016/0038-1098(82)90329-5
– ident: e_1_2_5_13_1
  doi: 10.1016/j.jnoncrysol.2006.09.041
– volume: 2
  start-page: 117
  year: 1976
  ident: e_1_2_5_75_1
  article-title: Raman Spectroscopy of Crystalline and Vitreous Borates
  publication-title: Philips Res. Rept. Suppl
– ident: e_1_2_5_67_1
  doi: 10.1016/0022-3093(75)90137-4
– ident: e_1_2_5_14_1
  doi: 10.2138/rmg.2011.73.6
– ident: e_1_2_5_58_1
  doi: 10.1021/jp961439
– ident: e_1_2_5_33_1
  doi: 10.2172/890179
– ident: e_1_2_5_4_1
  doi: 10.1179/174367606X81669
– ident: e_1_2_5_61_1
  doi: 10.1016/j.jnoncrysol.2007.04.029
– ident: e_1_2_5_83_1
  doi: 10.1016/0025-5408(94)90004-3
– ident: e_1_2_5_48_1
  doi: 10.1021/jp100530m
– ident: e_1_2_5_78_1
  doi: 10.1016/0022-2860(93)80349-Z
– start-page: 121
  volume-title: Structure, Dynamics and Properties of Silicate Melts
  year: 1995
  ident: e_1_2_5_49_1
  doi: 10.1515/9781501509384-007
– ident: e_1_2_5_68_1
  doi: 10.1016/0022-3093(76)90132-0
– ident: e_1_2_5_71_1
  doi: 10.1002/jrs.2763
– ident: e_1_2_5_57_1
  doi: 10.1021/ja00109a026
– ident: e_1_2_5_15_1
  doi: 10.1016/S0022-3115(01)00591-8
– ident: e_1_2_5_76_1
  doi: 10.1016/0167-577X(95)00148-4
– ident: e_1_2_5_35_1
  doi: 10.1016/S0022-3093(99)00352-X
– ident: e_1_2_5_24_1
  doi: 10.1007/s11661-005-0201-5
– start-page: 1
  volume-title: Mineralogical Society of America, Reviews in Mineralogy
  year: 1999
  ident: e_1_2_5_10_1
– volume: 31
  start-page: 129
  year: 1989
  ident: e_1_2_5_36_1
  article-title: Glasses for Immobilization of Sulfate Containing Radioactive Wastes
  publication-title: Radiokhimiya
– ident: e_1_2_5_22_1
  doi: 10.1111/j.1551-2916.2007.01853.x
– ident: e_1_2_5_32_1
  doi: 10.1016/j.jnucmat.2006.09.012
– ident: e_1_2_5_42_1
  doi: 10.1088/0953-8984/14/25/322
– volume-title: New Developments in Glassy Nuclear Wasteforms
  year: 2007
  ident: e_1_2_5_6_1
– ident: e_1_2_5_65_1
  doi: 10.1016/j.gca.2004.08.029
– ident: e_1_2_5_8_1
  doi: 10.1007/978-3-642-32917-3_2
– ident: e_1_2_5_77_1
  doi: 10.1016/0022-3093(90)90823-5
– volume: 192
  start-page: 208
  year: 2011
  ident: e_1_2_5_18_1
  article-title: Development of Graded Ni‐YSZ Composite Coating on Alloy 690 by Pulsed Laser Deposition Technique to Reduce Hazardous Metallic Nuclear Waste Inventory
  publication-title: J. Hazar. Mater.
– ident: e_1_2_5_45_1
  doi: 10.1021/cm1006058
– ident: e_1_2_5_28_1
  doi: 10.1016/j.jhazmat.2012.07.039
– ident: e_1_2_5_81_1
  doi: 10.1016/j.chemgeo.2008.07.002
– ident: e_1_2_5_62_1
  doi: 10.1016/j.jnoncrysol.2006.02.085
– ident: e_1_2_5_47_1
  doi: 10.1080/13642818908209739
– ident: e_1_2_5_17_1
  doi: 10.1016/j.jnucmat.2012.08.012
– ident: e_1_2_5_82_1
  doi: 10.1002/jrs.1250120110
– ident: e_1_2_5_19_1
  doi: 10.1016/j.jnucmat.2011.01.122
– volume: 2
  start-page: 1
  year: 2009
  ident: e_1_2_5_34_1
  article-title: Glass Matrices for Vitrification of Radioactive Waste‐ An Update on R&D Efforts
  publication-title: ISSTGM‐2009. IOP Conf Series: Mater. Sci. Engg.
– start-page: 157
  volume-title: Nuclear Waste Management
  year: 1986
  ident: e_1_2_5_7_1
– volume-title: An Introduction to Nuclear Waste Immobilization
  year: 2005
  ident: e_1_2_5_5_1
– ident: e_1_2_5_26_1
  doi: 10.2172/219300
– ident: e_1_2_5_27_1
  doi: 10.1016/j.jnoncrysol.2003.08.070
– start-page: 101
  volume-title: Scientific Basis for Nuclear Waste Management
  year: 1995
  ident: e_1_2_5_37_1
– volume: 31
  start-page: 30
  issue: 1
  year: 1990
  ident: e_1_2_5_72_1
  article-title: Multinuclear Nuclear Magnetic Resonance and Raman Investigation of Sodium Borosilicate Glass Structures
  publication-title: Phys. Chem. Glasses
– ident: e_1_2_5_2_1
  doi: 10.1023/A:1018646507438
– ident: e_1_2_5_51_1
  doi: 10.1021/jp034048l
– ident: e_1_2_5_59_1
  doi: 10.1016/S0022-3093(97)00491-2
– ident: e_1_2_5_52_1
  doi: 10.1021/jp993416b
– volume: 68
  start-page: 1206
  year: 1983
  ident: e_1_2_5_43_1
  article-title: High Resolution Si NMR Spectroscopic Study of Rock Forming Silicates
  publication-title: Am. Miner.
– ident: e_1_2_5_9_1
  doi: 10.1016/B978-0-08-056033-5.00107-5
– ident: e_1_2_5_16_1
  doi: 10.2172/145022
– ident: e_1_2_5_11_1
  doi: 10.1007/978-1-4615-9107-8_7
– ident: e_1_2_5_64_1
  doi: 10.1016/S0022-3093(01)00624-X
– ident: e_1_2_5_20_1
  doi: 10.1016/j.jnucmat.2008.07.046
– ident: e_1_2_5_79_1
  doi: 10.1016/S0022-2860(96)09674-3
– ident: e_1_2_5_21_1
  doi: 10.1016/j.jnucmat.2007.08.005
– ident: e_1_2_5_40_1
  doi: 10.1016/0025-5408(78)90173-3
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Snippet Understanding the role of V2O5 within borosilicate glass matrices is important for the development of novel matrices toward immobilization of sulfate...
Understanding the role of V 2 O 5 within borosilicate glass matrices is important for the development of novel matrices toward immobilization of sulfate...
Understanding the role of ... within borosilicate glass matrices is important for the development of novel matrices toward immobilization of sulfate containing...
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StartPage 88
SubjectTerms Addition polymerization
Borates
Borosilicate glasses
Ceramics
Glass
Networks
NMR
Nuclear magnetic resonance
Polymers
Silica
Silicates
Vanadium
Vanadium pentoxide
Title Vanadium in Borosilicate Glass
URI https://api.istex.fr/ark:/67375/WNG-Q74VH7F6-S/fulltext.pdf
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Volume 98
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