A Blueprint for the Synthesis and Characterization of Thiolated Graphene

Graphene derivatization to either engineer its physical and chemical properties or overcome the problem of the facile synthesis of nanographenes is a subject of significant attention in the nanomaterials research community. In this paper, we propose a facile and scalable method for the synthesis of...

Full description

Saved in:
Bibliographic Details
Published inNanomaterials (Basel, Switzerland) Vol. 12; no. 1; p. 45
Main Authors Rabchinskii, Maxim K., Sysoev, Victor V., Ryzhkov, Sergei A., Eliseyev, Ilya A., Stolyarova, Dina Yu, Antonov, Grigorii A., Struchkov, Nikolai S., Brzhezinskaya, Maria, Kirilenko, Demid A., Pavlov, Sergei I., Palenov, Mihail E., Mishin, Maxim V., Kvashenkina, Olga E., Gabdullin, Pavel G., Varezhnikov, Alexey S., Solomatin, Maksim A., Brunkov, Pavel N.
Format Journal Article
LanguageEnglish
Published Switzerland MDPI AG 24.12.2021
MDPI
Subjects
2D materials
Carbon
Caustic soda
Chemical properties
Chemistry
Energy storage
Ethanol
functionalization
Graphene
graphene derivatives
Liquid phases
Nanomaterials
Nanotechnology
Sensors
Smart materials
Sodium
Thiols
Valence band
Vapors
Work functions
Russia
functionalization
graphene derivatives
valence band
Mott conductivity
2D materials
gas sensor
thiols
graphene
Online AccessGet full text

Cover

Abstract Graphene derivatization to either engineer its physical and chemical properties or overcome the problem of the facile synthesis of nanographenes is a subject of significant attention in the nanomaterials research community. In this paper, we propose a facile and scalable method for the synthesis of thiolated graphene via a two-step liquid-phase treatment of graphene oxide (GO). Employing the core-level methods, the introduction of up to 5.1 at.% of thiols is indicated with the simultaneous rise of the C/O ratio to 16.8. The crumpling of the graphene layer upon thiolation without its perforation is pointed out by microscopic and Raman studies. The conductance of thiolated graphene is revealed to be driven by the Mott hopping mechanism with the sheet resistance values of 2.15 kΩ/sq and dependable on the environment. The preliminary results on the chemiresistive effect of these films upon exposure to ethanol vapors in the mix with dry and humid air are shown. Finally, the work function value and valence band structure of thiolated graphene are analyzed. Taken together, the developed method and findings of the morphology and physics of the thiolated graphene guide the further application of this derivative in energy storage, sensing devices, and smart materials.
AbstractList Graphene derivatization to either engineer its physical and chemical properties or overcome the problem of the facile synthesis of nanographenes is a subject of significant attention in the nanomaterials research community. In this paper, we propose a facile and scalable method for the synthesis of thiolated graphene via a two-step liquid-phase treatment of graphene oxide (GO). Employing the core-level methods, the introduction of up to 5.1 at.% of thiols is indicated with the simultaneous rise of the C/O ratio to 16.8. The crumpling of the graphene layer upon thiolation without its perforation is pointed out by microscopic and Raman studies. The conductance of thiolated graphene is revealed to be driven by the Mott hopping mechanism with the sheet resistance values of 2.15 kΩ/sq and dependable on the environment. The preliminary results on the chemiresistive effect of these films upon exposure to ethanol vapors in the mix with dry and humid air are shown. Finally, the work function value and valence band structure of thiolated graphene are analyzed. Taken together, the developed method and findings of the morphology and physics of the thiolated graphene guide the further application of this derivative in energy storage, sensing devices, and smart materials.
Graphene derivatization to either engineer its physical and chemical properties or overcome the problem of the facile synthesis of nanographenes is a subject of significant attention in the nanomaterials research community. In this paper, we propose a facile and scalable method for the synthesis of thiolated graphene via a two-step liquid-phase treatment of graphene oxide (GO). Employing the core-level methods, the introduction of up to 5.1 at.% of thiols is indicated with the simultaneous rise of the C/O ratio to 16.8. The crumpling of the graphene layer upon thiolation without its perforation is pointed out by microscopic and Raman studies. The conductance of thiolated graphene is revealed to be driven by the Mott hopping mechanism with the sheet resistance values of 2.15 kΩ/sq and dependable on the environment. The preliminary results on the chemiresistive effect of these films upon exposure to ethanol vapors in the mix with dry and humid air are shown. Finally, the work function value and valence band structure of thiolated graphene are analyzed. Taken together, the developed method and findings of the morphology and physics of the thiolated graphene guide the further application of this derivative in energy storage, sensing devices, and smart materials.Graphene derivatization to either engineer its physical and chemical properties or overcome the problem of the facile synthesis of nanographenes is a subject of significant attention in the nanomaterials research community. In this paper, we propose a facile and scalable method for the synthesis of thiolated graphene via a two-step liquid-phase treatment of graphene oxide (GO). Employing the core-level methods, the introduction of up to 5.1 at.% of thiols is indicated with the simultaneous rise of the C/O ratio to 16.8. The crumpling of the graphene layer upon thiolation without its perforation is pointed out by microscopic and Raman studies. The conductance of thiolated graphene is revealed to be driven by the Mott hopping mechanism with the sheet resistance values of 2.15 kΩ/sq and dependable on the environment. The preliminary results on the chemiresistive effect of these films upon exposure to ethanol vapors in the mix with dry and humid air are shown. Finally, the work function value and valence band structure of thiolated graphene are analyzed. Taken together, the developed method and findings of the morphology and physics of the thiolated graphene guide the further application of this derivative in energy storage, sensing devices, and smart materials.
Author Kvashenkina, Olga E.
Rabchinskii, Maxim K.
Solomatin, Maksim A.
Gabdullin, Pavel G.
Mishin, Maxim V.
Struchkov, Nikolai S.
Varezhnikov, Alexey S.
Ryzhkov, Sergei A.
Palenov, Mihail E.
Antonov, Grigorii A.
Brzhezinskaya, Maria
Pavlov, Sergei I.
Kirilenko, Demid A.
Eliseyev, Ilya A.
Brunkov, Pavel N.
Sysoev, Victor V.
Stolyarova, Dina Yu
AuthorAffiliation 1 Ioffe Institute, Politekhnicheskaya St. 26, 194021 Saint Petersburg, Russia; ryzhkov@mail.ioffe.ru (S.A.R.); Ilya.Eliseyev@mail.ioffe.ru (I.A.E.); antonov@mail.ioffe.ru (G.A.A.); Demid.Kirilenko@mail.ioffe.ru (D.A.K.); Pavlov_sergey@mail.ioffe.ru (S.I.P.); Brunkov@mail.ioffe.ru (P.N.B.)
5 Helmholtz-Zentrum Berlin für Materialien und Energie, Hahn-Meitner-Platz 1, 14109 Berlin, Germany; maria.brzhezinskaya@helmholtz-berlin.de
6 Institute of Electronics and Telecommunications, Peter the Great St. Petersburg Polytechnic University (SPbPU), Polytechnicheskaya 29, 195251 Saint Petersburg, Russia; m.e.palenov@gmail.com (M.E.P.); max@mail.spbstu.ru (M.V.M.); kvol.spbspu@gmail.com (O.E.K.); gabdullin_pg@spbstu.ru (P.G.G.)
3 National Research Centre “Kurchatov Institute”, Akademika Kurchatova pl. 1, 123182 Moscow, Russia; stolyarova.d@gmail.com
4 Center for Probe Microscopy and Nanotechnology, National Research University of Electronic Technology, Bld. 1, Shokin Square, 124498 Moscow, Russia; str
AuthorAffiliation_xml – name: 3 National Research Centre “Kurchatov Institute”, Akademika Kurchatova pl. 1, 123182 Moscow, Russia; stolyarova.d@gmail.com
– name: 6 Institute of Electronics and Telecommunications, Peter the Great St. Petersburg Polytechnic University (SPbPU), Polytechnicheskaya 29, 195251 Saint Petersburg, Russia; m.e.palenov@gmail.com (M.E.P.); max@mail.spbstu.ru (M.V.M.); kvol.spbspu@gmail.com (O.E.K.); gabdullin_pg@spbstu.ru (P.G.G.)
– name: 5 Helmholtz-Zentrum Berlin für Materialien und Energie, Hahn-Meitner-Platz 1, 14109 Berlin, Germany; maria.brzhezinskaya@helmholtz-berlin.de
– name: 1 Ioffe Institute, Politekhnicheskaya St. 26, 194021 Saint Petersburg, Russia; ryzhkov@mail.ioffe.ru (S.A.R.); Ilya.Eliseyev@mail.ioffe.ru (I.A.E.); antonov@mail.ioffe.ru (G.A.A.); Demid.Kirilenko@mail.ioffe.ru (D.A.K.); Pavlov_sergey@mail.ioffe.ru (S.I.P.); Brunkov@mail.ioffe.ru (P.N.B.)
– name: 2 Department of Physics, Yuri Gagarin State Technical University of Saratov, 77 Polytechnicheskaya St., 410054 Saratov, Russia; vsysoev@sstu.ru (V.V.S.); alexspb88@mail.ru (A.S.V.); solomatin1994@gmail.com (M.A.S.)
– name: 4 Center for Probe Microscopy and Nanotechnology, National Research University of Electronic Technology, Bld. 1, Shokin Square, 124498 Moscow, Russia; struchkov.nikolaj@gmail.com
Author_xml – sequence: 1
  givenname: Maxim K.
  orcidid: 0000-0003-4264-7147
  surname: Rabchinskii
  fullname: Rabchinskii, Maxim K.
– sequence: 2
  givenname: Victor V.
  orcidid: 0000-0002-0372-1802
  surname: Sysoev
  fullname: Sysoev, Victor V.
– sequence: 3
  givenname: Sergei A.
  surname: Ryzhkov
  fullname: Ryzhkov, Sergei A.
– sequence: 4
  givenname: Ilya A.
  orcidid: 0000-0001-9980-6191
  surname: Eliseyev
  fullname: Eliseyev, Ilya A.
– sequence: 5
  givenname: Dina Yu
  surname: Stolyarova
  fullname: Stolyarova, Dina Yu
– sequence: 6
  givenname: Grigorii A.
  surname: Antonov
  fullname: Antonov, Grigorii A.
– sequence: 7
  givenname: Nikolai S.
  orcidid: 0000-0002-7382-8058
  surname: Struchkov
  fullname: Struchkov, Nikolai S.
– sequence: 8
  givenname: Maria
  surname: Brzhezinskaya
  fullname: Brzhezinskaya, Maria
– sequence: 9
  givenname: Demid A.
  orcidid: 0000-0002-1571-209X
  surname: Kirilenko
  fullname: Kirilenko, Demid A.
– sequence: 10
  givenname: Sergei I.
  orcidid: 0000-0001-9589-8017
  surname: Pavlov
  fullname: Pavlov, Sergei I.
– sequence: 11
  givenname: Mihail E.
  surname: Palenov
  fullname: Palenov, Mihail E.
– sequence: 12
  givenname: Maxim V.
  surname: Mishin
  fullname: Mishin, Maxim V.
– sequence: 13
  givenname: Olga E.
  surname: Kvashenkina
  fullname: Kvashenkina, Olga E.
– sequence: 14
  givenname: Pavel G.
  orcidid: 0000-0002-2519-2577
  surname: Gabdullin
  fullname: Gabdullin, Pavel G.
– sequence: 15
  givenname: Alexey S.
  orcidid: 0000-0002-0896-9102
  surname: Varezhnikov
  fullname: Varezhnikov, Alexey S.
– sequence: 16
  givenname: Maksim A.
  surname: Solomatin
  fullname: Solomatin, Maksim A.
– sequence: 17
  givenname: Pavel N.
  orcidid: 0000-0002-3400-4654
  surname: Brunkov
  fullname: Brunkov, Pavel N.
BackLink https://www.ncbi.nlm.nih.gov/pubmed/35009995$$D View this record in MEDLINE/PubMed
BookMark eNptkk1vEzEQhleoiJbSG2e0EhcOBPy5Xl-QSgRtpUocKGdr1h9dRxs72N5K5dfjJC1KK3wZj_3Mq1cz87o5CjHYpnmL0SdKJfocIERMEEaI8RfNCUFCLpiU-Ojgftyc5bxC9UhMe05fNceU10RKftJcnrdfp9lukg-ldTG1ZbTtz_tQQ_a5hWDa5QgJdLHJ_4HiY2ija29GHyco1rQXCTajDfZN89LBlO3ZQzxtfn3_drO8XFz_uLhanl8vNBN9WTjdSU0laARUODcYPgysp9wJKwzusTED42BkJwx1HLNBOGkYIYYJR2otPW2u9romwkpV32tI9yqCV7uHmG4VpOL1ZFXtAO5ADBY0YxqzHjTBDDNksTbcbbW-7LU287C2RttQEkxPRJ_-BD-q23inesE6RnAV-PAgkOLv2eai1j5rO00QbJyzIh3uJUai26Lvn6GrOKdQW7WjCEeM0Eq9O3T0z8rjwCpA9oBOMedkndK-7MZSDfpJYaS2i6EOF6MWfXxW9Kj7X_wv6ji5bA
CitedBy_id crossref_primary_10_3390_nano13010023
crossref_primary_10_1016_j_jallcom_2025_179386
crossref_primary_10_3390_encyclopedia4040120
crossref_primary_10_1063_5_0159624
crossref_primary_10_1021_acsami_4c21591
crossref_primary_10_3390_s23135780
crossref_primary_10_1016_j_nxmate_2024_100205
Cites_doi 10.1088/2053-1583/ab9695
10.1016/0016-2361(90)90306-B
10.1209/0295-5075/97/38001
10.1088/1742-6596/1695/1/012070
10.1038/srep00662
10.1021/ja504054s
10.1021/acs.jpcc.6b08758
10.1016/j.electacta.2019.03.070
10.1016/j.carbon.2020.09.087
10.1039/C4NR01154F
10.1016/j.ssc.2012.04.064
10.1038/nchem.1820
10.1021/cr3000412
10.1016/j.synthmet.2014.06.008
10.1088/2053-1591/aae6be
10.1039/C7CS00215G
10.1002/pssa.201532855
10.1002/chem.201502127
10.1002/adom.201800441
10.1186/1556-276X-6-526
10.1016/j.msea.2005.01.007
10.1103/PhysRevB.67.155306
10.1016/j.carbon.2013.09.002
10.1016/j.carbon.2018.02.036
10.1002/chem.201702031
10.1103/PhysRevB.84.235417
10.3390/nano11040915
10.1002/smll.202104316
10.1098/rsta.2004.1452
10.1103/PhysRevB.86.235423
10.3390/s18093147
10.1021/ie404139z
10.1002/chem.201704192
10.1080/1536383X.2019.1686625
10.1016/j.jallcom.2020.156699
10.1016/j.carbon.2021.06.057
10.1021/nn302784m
10.1016/j.apsusc.2017.05.028
10.1103/PhysRevB.88.035426
10.1021/nl8034256
10.1039/C3CS60303B
10.1088/0957-4484/27/12/125704
10.1002/adma.201302358
10.1016/j.apsusc.2009.11.002
10.1007/BF03174800
10.1016/j.cplett.2012.12.053
10.1098/rspa.1975.0131
10.1021/jp203741y
10.1021/acs.jpcc.5b01590
10.1021/jp306497f
10.1039/c2jm31218b
10.1016/S0008-6223(03)00325-7
10.1103/PhysRevB.9.5268
10.1039/D0RA01068E
10.1016/j.talanta.2014.09.010
10.1016/j.cej.2017.02.030
10.1039/c3cs60132c
10.1007/s00339-008-4916-1
10.1016/j.molstruc.2020.128835
10.1088/0957-4484/18/39/395702
10.1021/nn900694t
10.1016/j.ssc.2012.02.002
10.1039/c2cp42866k
10.1016/0008-6223(94)90148-1
10.1021/acsnano.6b07746
10.1007/978-3-662-02853-7
10.1007/BF00203219
10.1038/nnano.2013.46
10.1016/j.carbon.2017.10.100
10.1088/2053-1583/ab1e0a
10.1021/acsami.8b16027
10.1039/C8TA04255A
10.3390/nano10040674
10.1039/b926109e
10.1039/c2jm34358d
10.1016/j.carbon.2005.02.018
10.1038/s41598-020-63935-3
10.1021/acsnano.5b00438
10.1016/j.jcat.2005.12.020
10.1039/C5NR06295K
10.1021/ja807934n
10.1021/acs.joc.8b02462
10.1016/j.joca.2012.01.010
10.1016/j.microc.2017.02.011
10.1039/C3RA45591B
10.1021/nl803698b
10.1002/(SICI)1096-9918(200004)29:4<265::AID-SIA739>3.0.CO;2-3
10.1039/C3TA13647G
ContentType Journal Article
Copyright 2021 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.
2021 by the authors. 2021
Copyright_xml – notice: 2021 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.
– notice: 2021 by the authors. 2021
DBID AAYXX
CITATION
NPM
7QF
7QO
7QQ
7SC
7SE
7SP
7SR
7TA
7TB
7U5
8BQ
8FD
8FE
8FG
8FH
ABJCF
ABUWG
AFKRA
AZQEC
BBNVY
BENPR
BGLVJ
BHPHI
CCPQU
D1I
DWQXO
F28
FR3
GNUQQ
H8D
H8G
HCIFZ
JG9
JQ2
KB.
KR7
L7M
LK8
L~C
L~D
M7P
P64
PDBOC
PHGZM
PHGZT
PIMPY
PKEHL
PQEST
PQGLB
PQQKQ
PQUKI
PRINS
7X8
5PM
DOA
DOI 10.3390/nano12010045
DatabaseName CrossRef
PubMed
Aluminium Industry Abstracts
Biotechnology Research Abstracts
Ceramic Abstracts
Computer and Information Systems Abstracts
Corrosion Abstracts
Electronics & Communications Abstracts
Engineered Materials Abstracts
Materials Business File
Mechanical & Transportation Engineering Abstracts
Solid State and Superconductivity Abstracts
METADEX
Technology Research Database
ProQuest SciTech Collection
ProQuest Technology Collection
ProQuest Natural Science Journals
Materials Science & Engineering Collection
ProQuest Central (Alumni)
ProQuest Central UK/Ireland
ProQuest Central Essentials
Biological Science Collection
ProQuest Central
Technology Collection
Natural Science Collection
ProQuest One
ProQuest Materials Science Collection
ProQuest Central
ANTE: Abstracts in New Technology & Engineering
Engineering Research Database
ProQuest Central Student
Aerospace Database
Copper Technical Reference Library
SciTech Premium Collection
Materials Research Database
ProQuest Computer Science Collection
Materials Science Database
Civil Engineering Abstracts
Advanced Technologies Database with Aerospace
Biological Sciences
Computer and Information Systems Abstracts – Academic
Computer and Information Systems Abstracts Professional
Biological Science Database
Biotechnology and BioEngineering Abstracts
Materials Science Collection
ProQuest Central Premium
ProQuest One Academic (New)
Publicly Available Content Database
ProQuest One Academic Middle East (New)
ProQuest One Academic Eastern Edition (DO NOT USE)
ProQuest One Applied & Life Sciences
ProQuest One Academic
ProQuest One Academic UKI Edition
ProQuest Central China
MEDLINE - Academic
PubMed Central (Full Participant titles)
DOAJ Directory of Open Access Journals
DatabaseTitle CrossRef
PubMed
Publicly Available Content Database
Materials Research Database
ProQuest Central Student
ProQuest Central Essentials
ProQuest Computer Science Collection
Computer and Information Systems Abstracts
SciTech Premium Collection
ProQuest Central China
Materials Business File
ProQuest One Applied & Life Sciences
Engineered Materials Abstracts
Natural Science Collection
Biological Science Collection
ProQuest Central (New)
ANTE: Abstracts in New Technology & Engineering
Aluminium Industry Abstracts
ProQuest Biological Science Collection
ProQuest One Academic Eastern Edition
Electronics & Communications Abstracts
ProQuest Technology Collection
Ceramic Abstracts
Biological Science Database
Biotechnology and BioEngineering Abstracts
ProQuest One Academic UKI Edition
Solid State and Superconductivity Abstracts
Engineering Research Database
ProQuest One Academic
ProQuest One Academic (New)
Technology Collection
Technology Research Database
Computer and Information Systems Abstracts – Academic
ProQuest One Academic Middle East (New)
Mechanical & Transportation Engineering Abstracts
Materials Science Collection
ProQuest Central (Alumni Edition)
ProQuest One Community College
ProQuest Natural Science Collection
ProQuest Central
Aerospace Database
Copper Technical Reference Library
Biotechnology Research Abstracts
ProQuest Central Korea
Materials Science Database
Advanced Technologies Database with Aerospace
ProQuest Materials Science Collection
Civil Engineering Abstracts
ProQuest SciTech Collection
METADEX
Computer and Information Systems Abstracts Professional
Materials Science & Engineering Collection
Corrosion Abstracts
MEDLINE - Academic
DatabaseTitleList Publicly Available Content Database
PubMed
CrossRef


MEDLINE - Academic
Database_xml – sequence: 1
  dbid: DOA
  name: DOAJ Directory of Open Access Journals
  url: https://www.doaj.org/
  sourceTypes: Open Website
– sequence: 2
  dbid: NPM
  name: PubMed
  url: https://proxy.k.utb.cz/login?url=http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?db=PubMed
  sourceTypes: Index Database
– sequence: 3
  dbid: 8FG
  name: ProQuest Technology Collection
  url: https://search.proquest.com/technologycollection1
  sourceTypes: Aggregation Database
DeliveryMethod fulltext_linktorsrc
Discipline Engineering
Chemistry
EISSN 2079-4991
ExternalDocumentID oai_doaj_org_article_20716a7beac44c148ac214140e1cd5f9
PMC8746421
35009995
10_3390_nano12010045
Genre Journal Article
GeographicLocations Russia
GeographicLocations_xml – name: Russia
GrantInformation_xml – fundername: Ministry of Science and Higher Education of the Russian Federation
  grantid: contract No. 075-15-2020-934 dated 17.11.2020
GroupedDBID 53G
5VS
8FE
8FG
8FH
AADQD
AAFWJ
AAHBH
AAYXX
ABJCF
ADBBV
ADMLS
AENEX
AFKRA
AFPKN
AFZYC
ALMA_UNASSIGNED_HOLDINGS
AOIJS
BBNVY
BCNDV
BENPR
BGLVJ
BHPHI
CCPQU
CITATION
D1I
GROUPED_DOAJ
HCIFZ
HYE
I-F
IAO
ITC
KB.
KQ8
LK8
M7P
MODMG
M~E
OK1
PDBOC
PGMZT
PHGZM
PHGZT
PIMPY
PROAC
RPM
NPM
PQGLB
7QF
7QO
7QQ
7SC
7SE
7SP
7SR
7TA
7TB
7U5
8BQ
8FD
ABUWG
AZQEC
DWQXO
F28
FR3
GNUQQ
H8D
H8G
JG9
JQ2
KR7
L7M
L~C
L~D
P64
PKEHL
PQEST
PQQKQ
PQUKI
PRINS
7X8
5PM
PUEGO
ID FETCH-LOGICAL-c478t-fc69c39ac0a37ffbd5bb4835f7e7d181ddb45ad967d3f514b7f9d422d47f2c693
IEDL.DBID DOA
ISSN 2079-4991
IngestDate Wed Aug 27 01:20:02 EDT 2025
Thu Aug 21 18:31:10 EDT 2025
Fri Jul 11 15:51:47 EDT 2025
Fri Jul 25 11:56:07 EDT 2025
Mon Jul 21 06:06:05 EDT 2025
Thu Apr 24 23:05:21 EDT 2025
Tue Jul 01 01:17:25 EDT 2025
IsDoiOpenAccess true
IsOpenAccess true
IsPeerReviewed true
IsScholarly true
Issue 1
Keywords functionalization
graphene derivatives
valence band
Mott conductivity
2D materials
gas sensor
thiols
graphene
Language English
License https://creativecommons.org/licenses/by/4.0
Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
LinkModel DirectLink
MergedId FETCHMERGED-LOGICAL-c478t-fc69c39ac0a37ffbd5bb4835f7e7d181ddb45ad967d3f514b7f9d422d47f2c693
Notes ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 14
content type line 23
ORCID 0000-0002-1571-209X
0000-0002-2519-2577
0000-0001-9980-6191
0000-0003-4264-7147
0000-0002-0372-1802
0000-0002-7382-8058
0000-0001-9589-8017
0000-0002-3400-4654
0000-0002-0896-9102
OpenAccessLink https://doaj.org/article/20716a7beac44c148ac214140e1cd5f9
PMID 35009995
PQID 2618250423
PQPubID 2032354
ParticipantIDs doaj_primary_oai_doaj_org_article_20716a7beac44c148ac214140e1cd5f9
pubmedcentral_primary_oai_pubmedcentral_nih_gov_8746421
proquest_miscellaneous_2618910761
proquest_journals_2618250423
pubmed_primary_35009995
crossref_citationtrail_10_3390_nano12010045
crossref_primary_10_3390_nano12010045
ProviderPackageCode CITATION
AAYXX
PublicationCentury 2000
PublicationDate 20211224
PublicationDateYYYYMMDD 2021-12-24
PublicationDate_xml – month: 12
  year: 2021
  text: 20211224
  day: 24
PublicationDecade 2020
PublicationPlace Switzerland
PublicationPlace_xml – name: Switzerland
– name: Basel
PublicationTitle Nanomaterials (Basel, Switzerland)
PublicationTitleAlternate Nanomaterials (Basel)
PublicationYear 2021
Publisher MDPI AG
MDPI
Publisher_xml – name: MDPI AG
– name: MDPI
References Eckmann (ref_62) 2013; 88
Luxa (ref_16) 2015; 21
Parviz (ref_14) 2012; 6
Cheng (ref_18) 2019; 7
Jiac (ref_83) 2017; 419
Rabchinskii (ref_9) 2020; 10
Ganguly (ref_43) 2011; 115
Rieppo (ref_85) 2012; 20
Rabchinskii (ref_76) 2020; 7
Liu (ref_17) 2012; 22
Sturala (ref_4) 2018; 24
Rabchinskii (ref_10) 2020; 28
Lee (ref_50) 2012; 116
Cuesta (ref_57) 1994; 32
Audi (ref_41) 2000; 29
Chua (ref_46) 2014; 43
Rabchinskii (ref_47) 2016; 120
Zhang (ref_55) 2012; 14
Wilson (ref_70) 2009; 3
Schultz (ref_49) 2014; 4
McFeely (ref_86) 1974; 9
Li (ref_42) 2017; 132
Kasrai (ref_53) 1990; 69
Joung (ref_79) 2012; 86
Yu (ref_5) 2020; 10
Rabchinskii (ref_12) 2021; 172
Rabchinskii (ref_48) 2021; 182
Ferrari (ref_56) 2013; 8
Kim (ref_21) 2006; 238
Ferrari (ref_61) 2004; 362
Ferrari (ref_60) 2003; 67
Zhang (ref_27) 2017; 316
Eng (ref_11) 2017; 11
Backes (ref_1) 2020; 7
Pumera (ref_7) 2017; 46
Rabchinskii (ref_36) 2020; 1695
Pumera (ref_8) 2013; 42
Wu (ref_25) 2019; 84
Yamaguchi (ref_88) 2016; 213
Kaiser (ref_75) 2009; 9
McIntosh (ref_78) 2012; 97
Yu (ref_19) 2017; 2
Kumar (ref_68) 2014; 6
Wrobel (ref_31) 2019; 6
Mkhoyan (ref_69) 2009; 9
Kirilenko (ref_71) 2011; 84
Mak (ref_73) 2012; 152
Chuang (ref_80) 2012; 152
Kang (ref_81) 2013; 25
Nipane (ref_45) 2014; 53
Helander (ref_35) 2010; 256
Sadezky (ref_63) 2005; 43
Liu (ref_67) 2018; 127
Chua (ref_22) 2015; 9
Pumera (ref_15) 2016; 8
Naito (ref_82) 2014; 195
Pivac (ref_58) 2005; 396
ref_34
ref_74
Gao (ref_13) 2015; 132
Wang (ref_65) 2020; 1221
Li (ref_54) 1994; 20
Darmstadt (ref_33) 2003; 41
Zheng (ref_39) 2012; 2
Jankovsky (ref_40) 2017; 23
Withers (ref_6) 2011; 6
Brzhezinskaya (ref_51) 2020; 849
Mott (ref_77) 1975; 345
Jankovsky (ref_37) 2014; 6
Seshadri (ref_59) 1942; 16
Villaume (ref_52) 2010; 12
Claramunt (ref_64) 2015; 119
Chuang (ref_24) 2007; 18
Marquardt (ref_20) 2014; 66
Kairi (ref_2) 2018; 6
Chua (ref_38) 2012; 22
Yang (ref_87) 2013; 559
ref_89
ref_44
Georgakilas (ref_3) 2012; 112
Shearer (ref_66) 2016; 27
ref_84
Kannappan (ref_23) 2018; 134
Yeo (ref_29) 2014; 2
Luo (ref_72) 2009; 131
Molodtsov (ref_32) 2009; 94
Malinowska (ref_30) 2019; 305
Zhang (ref_26) 2014; 136
Zhang (ref_28) 2018; 10
References_xml – volume: 7
  start-page: 045001
  year: 2020
  ident: ref_76
  article-title: Unveiling a facile approach for large-scale synthesis of N-doped graphene with tuned electrical properties
  publication-title: 2D Mater.
  doi: 10.1088/2053-1583/ab9695
– volume: 2
  start-page: 17046
  year: 2017
  ident: ref_19
  article-title: Graphene-based smart materials
  publication-title: Nat. Rev.
– volume: 69
  start-page: 411
  year: 1990
  ident: ref_53
  article-title: Characterization of sulphur in coal from sulphur L-edge XANES spectra
  publication-title: Fuel
  doi: 10.1016/0016-2361(90)90306-B
– volume: 97
  start-page: 38001
  year: 2012
  ident: ref_78
  article-title: Improved electronic and magnetic properties of reduced graphene oxide films
  publication-title: EPL
  doi: 10.1209/0295-5075/97/38001
– volume: 1695
  start-page: 012070
  year: 2020
  ident: ref_36
  article-title: Establishing the applicability of the laser diffraction technique for the graphene oxide platelets lateral size measurements
  publication-title: J. Phys. Conf. Ser.
  doi: 10.1088/1742-6596/1695/1/012070
– volume: 2
  start-page: 662
  year: 2012
  ident: ref_39
  article-title: Production of Graphite Chloride and Bromide Using Microwave Sparks
  publication-title: Sci. Rep.
  doi: 10.1038/srep00662
– volume: 136
  start-page: 8193
  year: 2014
  ident: ref_26
  article-title: Synthesis and Structure of an Open-Cage Thiafullerene C69S: Reactivity Differences of an Open-Cage C70 Tetraketone Relative to Its C60 Analogue
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/ja504054s
– volume: 120
  start-page: 28261
  year: 2016
  ident: ref_47
  article-title: Nanoscale perforation of graphene oxide during photoreduction process in the argon atmosphere
  publication-title: J. Phys. Chem. C
  doi: 10.1021/acs.jpcc.6b08758
– volume: 305
  start-page: 329
  year: 2019
  ident: ref_30
  article-title: Directly-thiolated graphene based electrochemical sensor for Hg(II) ion
  publication-title: Electrochim. Acta
  doi: 10.1016/j.electacta.2019.03.070
– volume: 172
  start-page: 236
  year: 2021
  ident: ref_12
  article-title: Hole-matrixed carbonylated graphene: Synthesis, properties, and highly-selective ammonia gas sensing
  publication-title: Carbon
  doi: 10.1016/j.carbon.2020.09.087
– volume: 6
  start-page: 6065
  year: 2014
  ident: ref_37
  article-title: Towards graphene bromide: Bromination of graphite oxide
  publication-title: Nanoscale
  doi: 10.1039/C4NR01154F
– volume: 152
  start-page: 1341
  year: 2012
  ident: ref_73
  article-title: Optical spectroscopy of graphene: From the far infrared to the ultraviolet
  publication-title: Solid State Commun.
  doi: 10.1016/j.ssc.2012.04.064
– volume: 6
  start-page: 151
  year: 2014
  ident: ref_68
  article-title: Scalable enhancement of graphene oxide properties by thermally driven phase transformation
  publication-title: Nat. Chem.
  doi: 10.1038/nchem.1820
– volume: 112
  start-page: 6156
  year: 2012
  ident: ref_3
  article-title: Functionalization of Graphene: Covalent and Non-Covalent Approaches, Derivatives and Applications
  publication-title: Chem. Rev.
  doi: 10.1021/cr3000412
– volume: 195
  start-page: 260
  year: 2014
  ident: ref_82
  article-title: Work-function decrease of transparent conducting films composed of hydrazine-reduced graphene oxide and silver nanowire stacked layers by electrochemical treatment
  publication-title: Synth. Met.
  doi: 10.1016/j.synthmet.2014.06.008
– volume: 6
  start-page: 015607
  year: 2019
  ident: ref_31
  article-title: A comparative study on simple and practical chemical gas sensors from chemically modified graphene films
  publication-title: Mater. Res. Express
  doi: 10.1088/2053-1591/aae6be
– volume: 46
  start-page: 4450
  year: 2017
  ident: ref_7
  article-title: Towards stoichiometric analogues of graphene: Graphane, fluorographene, graphol, graphene acid and others
  publication-title: Chem. Soc. Rev.
  doi: 10.1039/C7CS00215G
– volume: 213
  start-page: 2380
  year: 2016
  ident: ref_88
  article-title: Valence-band electronic structure evolution of graphene oxide upon thermal annealing for optoelectronics
  publication-title: Phys. Status Solidi A
  doi: 10.1002/pssa.201532855
– volume: 21
  start-page: 17728
  year: 2015
  ident: ref_16
  article-title: Mesomeric Effects of Graphene Modified with Diazonium Salts: Substituent Type and Position Influence its Properties
  publication-title: Chem. Eur. J.
  doi: 10.1002/chem.201502127
– volume: 7
  start-page: 1800441
  year: 2019
  ident: ref_18
  article-title: Recent Advances in Optoelectronic Devices Based on 2D Materials and Their Heterostructures
  publication-title: Adv. Opt. Mater.
  doi: 10.1002/adom.201800441
– volume: 6
  start-page: 526
  year: 2011
  ident: ref_6
  article-title: Tuning the Electronic Transport Properties of Graphene through Functionalisation with Fluorine
  publication-title: Nanoscale Res. Lett.
  doi: 10.1186/1556-276X-6-526
– volume: 396
  start-page: 290
  year: 2005
  ident: ref_58
  article-title: Raman study of carbon clusters in W–C thin films
  publication-title: Mater. Sci. Eng. A
  doi: 10.1016/j.msea.2005.01.007
– volume: 67
  start-page: 1
  year: 2003
  ident: ref_60
  article-title: Interpretation of infrared and Raman spectra of amorphous carbon nitrides
  publication-title: Phys. Rev. B
  doi: 10.1103/PhysRevB.67.155306
– volume: 66
  start-page: 285
  year: 2014
  ident: ref_20
  article-title: Hybrid materials of platinum nanoparticles and thiol-functionalized graphene derivatives
  publication-title: Carbon
  doi: 10.1016/j.carbon.2013.09.002
– volume: 134
  start-page: 326
  year: 2018
  ident: ref_23
  article-title: Thiolated-graphene-based supercapacitors with high energy density and stable cycling performance
  publication-title: Carbon
  doi: 10.1016/j.carbon.2018.02.036
– volume: 23
  start-page: 10473
  year: 2017
  ident: ref_40
  article-title: Selective Bromination of Graphene Oxide by the Hunsdiecker Reaction
  publication-title: Chem. Eur. J.
  doi: 10.1002/chem.201702031
– volume: 84
  start-page: 235417
  year: 2011
  ident: ref_71
  article-title: Measuring the corrugation amplitude of suspended and supported graphene
  publication-title: Phys. Rev. B
  doi: 10.1103/PhysRevB.84.235417
– ident: ref_74
  doi: 10.3390/nano11040915
– ident: ref_84
  doi: 10.1002/smll.202104316
– volume: 362
  start-page: 2477
  year: 2004
  ident: ref_61
  article-title: Raman spectroscopy of amorphous, nanostructured, diamond–like carbon, and nanodiamond
  publication-title: Philos. Trans. R. Soc. London. Ser. A
  doi: 10.1098/rsta.2004.1452
– volume: 86
  start-page: 235423
  year: 2012
  ident: ref_79
  article-title: Efros-Shklovskii variable-range hopping in reduced graphene oxide sheets of varying carbon sp2 fraction
  publication-title: Phys. Rev. B
  doi: 10.1103/PhysRevB.86.235423
– ident: ref_89
  doi: 10.3390/s18093147
– volume: 53
  start-page: 3924
  year: 2014
  ident: ref_45
  article-title: Reduced Graphene Oxide Supported Silicotungstic Acid for Efficient Conversion of Thiols to Disulfides by Hydrogen Peroxide
  publication-title: Ind. Eng. Chem. Res.
  doi: 10.1021/ie404139z
– volume: 24
  start-page: 5992
  year: 2018
  ident: ref_4
  article-title: Chemistry of Graphene Derivatives: Synthesis, Applications, and Perspectives
  publication-title: Chem. Eur. J.
  doi: 10.1002/chem.201704192
– volume: 28
  start-page: 221
  year: 2020
  ident: ref_10
  article-title: Graphene oxide conversion into controllably carboxylated graphene layers via photoreduction process in the inert atmosphere
  publication-title: Fuller. Nanotub. Carbon Nanostruct.
  doi: 10.1080/1536383X.2019.1686625
– volume: 849
  start-page: 156699
  year: 2020
  ident: ref_51
  article-title: Large-scalable graphene oxide films with resistive switching for non-volatile memory applications
  publication-title: J. Alloys Compd.
  doi: 10.1016/j.jallcom.2020.156699
– volume: 182
  start-page: 593
  year: 2021
  ident: ref_48
  article-title: Modulating nitrogen species via N-doping and post annealing of graphene derivatives: XPS and XAS examination
  publication-title: Carbon
  doi: 10.1016/j.carbon.2021.06.057
– volume: 6
  start-page: 8857
  year: 2012
  ident: ref_14
  article-title: Dispersions of non-covalently functionalized graphene with minimal stabilizer
  publication-title: ACS Nano
  doi: 10.1021/nn302784m
– volume: 419
  start-page: 252
  year: 2017
  ident: ref_83
  article-title: Work function engineering of graphene oxide via covalent functionalization for organic field-effect transistors
  publication-title: Appl. Surf. Sci.
  doi: 10.1016/j.apsusc.2017.05.028
– volume: 88
  start-page: 35426
  year: 2013
  ident: ref_62
  article-title: Raman study on defective graphene: Effect of the excitation energy, type, and amount of defects
  publication-title: Phys. Rev. B
  doi: 10.1103/PhysRevB.88.035426
– volume: 9
  start-page: 1058
  year: 2009
  ident: ref_69
  article-title: Atomic and Electronic Structure of Graphene-Oxide
  publication-title: Nano Lett.
  doi: 10.1021/nl8034256
– volume: 43
  start-page: 291
  year: 2014
  ident: ref_46
  article-title: Chem. Chemical reduction of graphene oxide: A synthetic chemistry viewpoint
  publication-title: Soc. Rev.
  doi: 10.1039/C3CS60303B
– volume: 27
  start-page: 125704
  year: 2016
  ident: ref_66
  article-title: Accurate thickness measurement of graphene
  publication-title: Nanotechnology
  doi: 10.1088/0957-4484/27/12/125704
– volume: 25
  start-page: 5856
  year: 2013
  ident: ref_81
  article-title: Work-Function-Tuned Reduced Graphene Oxide via Direct Surface Functionalization as Source/Drain Electrodes in Bottom-Contact Organic Transistors
  publication-title: Adv. Mat.
  doi: 10.1002/adma.201302358
– volume: 256
  start-page: 2602
  year: 2010
  ident: ref_35
  article-title: Pitfalls in measuring work function using photoelectron spectroscopy
  publication-title: Appl. Surf. Sci.
  doi: 10.1016/j.apsusc.2009.11.002
– volume: 16
  start-page: 264
  year: 1942
  ident: ref_59
  article-title: Raman effect and hydrogen bonds Part VII. Study of a Few Typical Carboxylic Acids
  publication-title: Proc. Indian Acad. Sci.
  doi: 10.1007/BF03174800
– volume: 559
  start-page: 67
  year: 2013
  ident: ref_87
  article-title: Valence band of poly(sodium 4-styrenesulfonate) intercalated graphite oxide composites
  publication-title: Chem. Phys. Lett.
  doi: 10.1016/j.cplett.2012.12.053
– volume: 345
  start-page: 169
  year: 1975
  ident: ref_77
  article-title: The Anderson transition
  publication-title: Proc. R. Soc. Lond. A
  doi: 10.1098/rspa.1975.0131
– volume: 115
  start-page: 17009
  year: 2011
  ident: ref_43
  article-title: Probing the Thermal Deoxygenation of Graphene Oxide Using High-Resolution in situ X-Ray-Based Spectroscopies
  publication-title: J. Phys. Chem. C
  doi: 10.1021/jp203741y
– volume: 119
  start-page: 10123
  year: 2015
  ident: ref_64
  article-title: The importance of interbands on the interpretation of the raman spectrum of graphene oxide
  publication-title: J. Phys. Chem. C
  doi: 10.1021/acs.jpcc.5b01590
– volume: 116
  start-page: 20591
  year: 2012
  ident: ref_50
  article-title: Soft X-ray Absorption Spectroscopy Studies of the Electronic Structure Recovery of Graphene Oxide upon Chemical Defunctionalization
  publication-title: Phys. Chem. C
  doi: 10.1021/jp306497f
– volume: 22
  start-page: 12435
  year: 2012
  ident: ref_17
  article-title: Strategies for Chemical Modification of Graphene and Applications of Chemically Modified Graphene
  publication-title: J. Mater. Chem.
  doi: 10.1039/c2jm31218b
– volume: 41
  start-page: 2662
  year: 2003
  ident: ref_33
  article-title: Surface spectroscopic study of basic sites on carbon blacks
  publication-title: Carbon
  doi: 10.1016/S0008-6223(03)00325-7
– volume: 9
  start-page: 5268
  year: 1974
  ident: ref_86
  article-title: X-ray photoemission studies of diamond, graphite, and glassy carbon valence bands
  publication-title: Phys. Rev. B
  doi: 10.1103/PhysRevB.9.5268
– volume: 10
  start-page: 15328
  year: 2020
  ident: ref_5
  article-title: Progress in the functional modification of graphene/graphene oxide: A review
  publication-title: RSC Adv.
  doi: 10.1039/D0RA01068E
– volume: 132
  start-page: 215
  year: 2015
  ident: ref_13
  article-title: A carboxylated graphene and aptamer nanocomposite-based aptasensor for sensitive and specific detection of hemin
  publication-title: Talanta
  doi: 10.1016/j.talanta.2014.09.010
– volume: 316
  start-page: 736
  year: 2017
  ident: ref_27
  article-title: Thiolated graphene-based superhydrophobic sponges for oil-water separation
  publication-title: Chem. Eng. Sci.
  doi: 10.1016/j.cej.2017.02.030
– volume: 42
  start-page: 5987
  year: 2013
  ident: ref_8
  article-title: Graphane and hydrogenated graphene
  publication-title: Chem. Soc. Rev.
  doi: 10.1039/c3cs60132c
– volume: 94
  start-page: 501
  year: 2009
  ident: ref_32
  article-title: High-resolution Russian–German beamline at BESSY
  publication-title: Appl. Phys. A
  doi: 10.1007/s00339-008-4916-1
– volume: 1221
  start-page: 128835
  year: 2020
  ident: ref_65
  article-title: Preparation and characterization of polyaniline/p-phenylenediamine grafted graphene oxide composites for supercapacitors
  publication-title: J. Mol. Struct.
  doi: 10.1016/j.molstruc.2020.128835
– volume: 18
  start-page: 395702
  year: 2007
  ident: ref_24
  article-title: Improved field emission properties of thiolated multi-wall carbon nanotubes on a flexible carbon cloth substrate
  publication-title: Nanotechnology
  doi: 10.1088/0957-4484/18/39/395702
– volume: 3
  start-page: 2547
  year: 2009
  ident: ref_70
  article-title: Graphene Oxide: Structural Analysis and Application as a Highly Transparent Support for Electron Microscopy
  publication-title: ACS Nano
  doi: 10.1021/nn900694t
– volume: 152
  start-page: 905
  year: 2012
  ident: ref_80
  article-title: Experimental evidence for Efros–Shklovskii variable range hopping in hydrogenated graphene
  publication-title: Solid State Commun.
  doi: 10.1016/j.ssc.2012.02.002
– volume: 14
  start-page: 13670
  year: 2012
  ident: ref_55
  article-title: Electronic structure and chemical bonding of a graphene oxide–sulfur nanocomposite for use in superior performance lithium–sulfur cells
  publication-title: Phys. Chem. Chem. Phys.
  doi: 10.1039/c2cp42866k
– volume: 32
  start-page: 1523
  year: 1994
  ident: ref_57
  article-title: Raman microprobe studies on carbon materials
  publication-title: Carbon
  doi: 10.1016/0008-6223(94)90148-1
– volume: 11
  start-page: 1789
  year: 2017
  ident: ref_11
  article-title: Synthesis of Carboxylated-Graphenes by the Kolbe–Schmitt Process
  publication-title: ACS Nano
  doi: 10.1021/acsnano.6b07746
– ident: ref_34
  doi: 10.1007/978-3-662-02853-7
– volume: 20
  start-page: 489
  year: 1994
  ident: ref_54
  article-title: Sulfur K- and L-edge X-ray Absorption Spectroscopy of Sphalerite, Chalcopyrite and Stannite
  publication-title: Phys. Chem. Miner.
  doi: 10.1007/BF00203219
– volume: 8
  start-page: 235
  year: 2013
  ident: ref_56
  article-title: Raman spectroscopy as a versatile tool for studying the properties of graphene
  publication-title: Nat. Nanotechnol.
  doi: 10.1038/nnano.2013.46
– volume: 127
  start-page: 141
  year: 2018
  ident: ref_67
  article-title: Direct observation of oxygen configuration on individual graphene oxide sheets
  publication-title: Carbon
  doi: 10.1016/j.carbon.2017.10.100
– volume: 7
  start-page: 022001
  year: 2020
  ident: ref_1
  article-title: Production and processing of graphene and related materials
  publication-title: 2D Mater.
  doi: 10.1088/2053-1583/ab1e0a
– volume: 10
  start-page: 41784
  year: 2018
  ident: ref_28
  article-title: Thiolated Graphene@Polyester Fabric-Based Multilayer Piezoresistive Pressure Sensors for Detecting Human Motion
  publication-title: ACS Appl. Mater. Interfaces
  doi: 10.1021/acsami.8b16027
– volume: 6
  start-page: 15010
  year: 2018
  ident: ref_2
  article-title: Toward high production of graphene flakes—A review on recent developments in their synthesis methods and scalability
  publication-title: J. Mater. Chem. A
  doi: 10.1039/C8TA04255A
– ident: ref_44
  doi: 10.3390/nano10040674
– volume: 12
  start-page: 5596
  year: 2010
  ident: ref_52
  article-title: Near sulfur L-edge X-ray absorption spectra of methanethiol in isolation and adsorbed on a Au(111) surface: A theoretical study using the four-component static exchange approximation
  publication-title: Phys. Chem. Chem. Phys.
  doi: 10.1039/b926109e
– volume: 22
  start-page: 23227
  year: 2012
  ident: ref_38
  article-title: Renewal of sp2 bonds in graphene oxides via dehydrobromination
  publication-title: J. Mater. Chem.
  doi: 10.1039/c2jm34358d
– volume: 43
  start-page: 1731
  year: 2005
  ident: ref_63
  article-title: Raman microspectroscopy of soot and related carbonaceous materials: Spectral analysis and structural information
  publication-title: Carbon
  doi: 10.1016/j.carbon.2005.02.018
– volume: 10
  start-page: 6902
  year: 2020
  ident: ref_9
  article-title: From Graphene Oxide towards Aminated Graphene: Facile Synthesis, Its Structure and Electronic Properties
  publication-title: Sci. Rep.
  doi: 10.1038/s41598-020-63935-3
– volume: 9
  start-page: 4193
  year: 2015
  ident: ref_22
  article-title: Monothiolation and Reduction of Graphene Oxide via One-Pot Synthesis: Hybrid Catalyst for Oxygen Reduction
  publication-title: ACS Nano
  doi: 10.1021/acsnano.5b00438
– volume: 238
  start-page: 394
  year: 2006
  ident: ref_21
  article-title: Surface thiolation of carbon nanotubes as supports: A promising route for the high dispersion of Pt nanoparticles for electrocatalysts
  publication-title: J. Catal.
  doi: 10.1016/j.jcat.2005.12.020
– volume: 8
  start-page: 1493
  year: 2016
  ident: ref_15
  article-title: Fine tuning of graphene properties by modification with aryl halogens
  publication-title: Nanoscale
  doi: 10.1039/C5NR06295K
– volume: 131
  start-page: 898
  year: 2009
  ident: ref_72
  article-title: High Yield Preparation of Macroscopic Graphene Oxide Membranes
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/ja807934n
– volume: 84
  start-page: 3045
  year: 2019
  ident: ref_25
  article-title: Dithiolation of [70] Fullerene with Aliphatic Primary Thiols in the Presence of n-Butylamine via Aerobic Oxidation Reaction
  publication-title: J. Org. Chem.
  doi: 10.1021/acs.joc.8b02462
– volume: 20
  start-page: 451
  year: 2012
  ident: ref_85
  article-title: Application of second derivative spectroscopy for increasing molecular specificity of fourier transform infrared spectroscopic imaging of articular cartilage
  publication-title: Osteoarthr. Cartil.
  doi: 10.1016/j.joca.2012.01.010
– volume: 132
  start-page: 299
  year: 2017
  ident: ref_42
  article-title: Directly-thiolated graphene based organic solvent-free cloud point extraction-like method for enrichment and speciation of mercury by HPLC-ICP-MS
  publication-title: Microchem. J.
  doi: 10.1016/j.microc.2017.02.011
– volume: 4
  start-page: 634
  year: 2014
  ident: ref_49
  article-title: X-ray absorption spectroscopy studies of electronic structure recovery and nitrogen local structure upon thermal reduction of graphene oxide in an ammonia environment
  publication-title: RSC Adv.
  doi: 10.1039/C3RA45591B
– volume: 9
  start-page: 1787
  year: 2009
  ident: ref_75
  article-title: Electrical Conduction Mechanism in Chemically Derived Graphene Monolayers
  publication-title: Nano Lett.
  doi: 10.1021/nl803698b
– volume: 29
  start-page: 265
  year: 2000
  ident: ref_41
  article-title: X-ray photoelectron spectroscopic studies of sulfates and bisulfates interpreted by Xa and band structure calculations
  publication-title: Surf. Interface Anal.
  doi: 10.1002/(SICI)1096-9918(200004)29:4<265::AID-SIA739>3.0.CO;2-3
– volume: 2
  start-page: 292
  year: 2014
  ident: ref_29
  article-title: Sulfonic acid-functionalized, reduced graphene oxide as an advanced interfacial material leading to donor polymer-independent high-performance polymer solar cells
  publication-title: J. Mater. Chem. A
  doi: 10.1039/C3TA13647G
SSID ssj0000913853
Score 2.2360065
Snippet Graphene derivatization to either engineer its physical and chemical properties or overcome the problem of the facile synthesis of nanographenes is a subject...
SourceID doaj
pubmedcentral
proquest
pubmed
crossref
SourceType Open Website
Open Access Repository
Aggregation Database
Index Database
Enrichment Source
StartPage 45
SubjectTerms 2D materials
Carbon
Caustic soda
Chemical properties
Chemistry
Energy storage
Ethanol
functionalization
Graphene
graphene derivatives
Liquid phases
Nanomaterials
Nanotechnology
Sensors
Smart materials
Sodium
Thiols
Valence band
Vapors
Work functions
SummonAdditionalLinks – databaseName: ProQuest Central
  dbid: BENPR
  link: http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwfV1Lb9QwEB5BewAOCMorUJCR4ISiJrYTJyfUXbWskKgQtFJvkeNHu1LllO7uof--M4k37CLgFClxpJHH9nwznvkG4INDO1rZzKbUkSaVVKOLbjNPnSPjppTPCqpG_nZSzs7k1_PiPAbcFjGtcn0m9ge17QzFyA8Q6VdEt8XF5-tfKXWNotvV2ELjPuziEVyh87U7OTr5_mOMshDrJRqkIeNdoH9_EHTocroCzqiCacMW9ZT9f8OZf6ZLbtif4yfwOAJHdjho-incc2EPHkzX_dr24NEGteAzmB2yydXKUdhuyRCYMgR67OdtwMdivmA6WDYduZqHUkzWeXZ6OUdfF1Eo-0JM1ngQPoez46PT6SyNXRNSI1W1TL0payNqbTItlPetLdpWIs7yyimL9tzaVhba1qWywiNcapWvreTcSuU5_itewE7ognsFzJmyLTJthBQINIRrK8OtE1ltTKnKTCTwaT1_jYmU4tTZ4qpB14Jmu9mc7QQ-jqOvByqNf4ybkCrGMUSA3b_obi6auJ8ajtCo1KpFuyGlQZ9OG55L9BZdbmzh6wT214ps4q5cNL_XUALvx8-oJrok0cF1q2EMQihV5gm8HPQ-SiKKHlCjhGprRWyJuv0lzC97zu5KSSopfv1_sd7AQ045MzlPudyHneXNyr1F0LNs38WVfQdrnwKT
  priority: 102
  providerName: ProQuest
Title A Blueprint for the Synthesis and Characterization of Thiolated Graphene
URI https://www.ncbi.nlm.nih.gov/pubmed/35009995
https://www.proquest.com/docview/2618250423
https://www.proquest.com/docview/2618910761
https://pubmed.ncbi.nlm.nih.gov/PMC8746421
https://doaj.org/article/20716a7beac44c148ac214140e1cd5f9
Volume 12
hasFullText 1
inHoldings 1
isFullTextHit
isPrint
link http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwrV1La9wwEB7yuDSHkL63TRcF2lMxtSXZso_ZkM1SSAhpArkZPclC0Jbs7iH_PjO2Y7wlpZeeDNYYxqOR5htJ8wngq8c4WrrUJXQjTSKpRhfTZp54T8FNqZDmVI18flHMbuTP2_x2cNUXnQlr6YFbw9EKSFZoZXCCkNIieNeWZxLTAp9Zl4emdA9j3iCZaubgKhMYiNqT7gLz-h9Rx0VGW78pVS4NYlBD1f8SvvzzmOQg7kwPYL8DjOy4VfQ1bPn4BvYGNIJvYXbMJvdrT0t0K4YglCGoY78eIz6W8yXT0bGTnpe5Lbtki8Cu7-aY1yLiZGfEWo2T3ju4mZ5en8yS7oaExEpVrpJgi8qKSttUCxWCcbkxEjFVUF45jN3OGZlrVxXKiYDQyKhQOcm5kypw_Fa8h524iP4jMG8Lk6faCikQVAhvSsudF2llbaGKVIzg-7PNatvRh9MtFvc1phFk4Xpo4RF866V_t7QZf5GbkPl7GSK7bl6gC9SdC9T_coERHD53Xt2NwGWNmWFJ9GwcNT_qm3Hs0IaIjn6xbmUQLqkiG8GHtq97TUTegGfUUG14wYaqmy1xftfwc5dKUvnwp__xb5_hFadTNBlPuDyEndXD2n9BGLQyY9gup2dj2J2cXlxejRv_fwJRLwhY
linkProvider Directory of Open Access Journals
linkToHtml http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwtV1Lb9QwEB6VcigcUClQAi0YiZ5Q1MR24uSAULtlu6WPC1upt5D4QVeqktLdFeqf4jcyk1d3EXDrKVI8iSzP2PON7fkG4L1FP5qYwPhUkcaXlKOLYTP3rSXnppQLIspGPj2LR-fyy0V0sQK_ulwYulbZrYn1Qm0qTXvku4j0E6Lb4uLT9Q-fqkbR6WpXQqMxi2N7-xNDtunHowPU7w7nw8_jwchvqwr4Wqpk5jsdp1qkuQ5yoZwrTFQUEnGIU1YZ9HfGFDLKTRorIxzCiUK51EjOjVSO47cC__sAHkohUppRyfCw39Mhjk10f839emwPdsu8rEI6cA4oX2rB89UFAv6Gav-8nLng7Ybr8KSFqWyvsaunsGLLDVgbdNXhNuDxApHhMxjtsf2ruaVNwhlDGMwQVrKvtyU-ppMpy0vDBj0zdJP4ySrHxpcTjKwR87JD4s3GZfc5nN_LaL6A1bIq7UtgVsdFFORaSIGwRtgi0dxYEaRaxyoOhAcfuvHLdEtgTnU0rjIMZGi0s8XR9mCnl75uiDv-IbdPquhliG67flHdfM_a2ZtxBGJxrgr0UlJqjCBzzUOJsakNtYlc6sFWp8isXQOm2Z3FevCub0Y10ZFMXtpq3sggYFNx6MFmo_e-JyKq4Tv2UC1ZxFJXl1vKyWXNEJ4oSQnMr_7frbewNhqfnmQnR2fHr-ERp9s6Ife53ILV2c3cbiPcmhVvahtn8O2-J9VvExM_mQ
linkToPdf http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwtV1Lb9QwEB6VrcTjgKC8AgWMRE8o2sR24s0Boe62y5bCqoJW6i0kftCVqqR0d4X61_h1zOTFLgJuPUWKncjyjD3f2DPfALy2aEcHJjA-VaTxJeXootvMfWvJuCnlgoiykT9N48mJ_HAanW7AzzYXhsIq2z2x2qhNqemMvI9If0B0W1z0XRMWcbQ3fnfx3acKUnTT2pbTqFXk0F79QPdt_vZgD2W9w_l4_3g08ZsKA76WarDwnY4TLZJMB5lQzuUmynOJmMQpqwzaPmNyGWUmiZURDqFFrlxiJOdGKsfxW4H_vQGbCr2ioAebw_3p0efuhIcYN9EY1tH2QiRBv8iKMqTr54Cyp1bsYFUu4G8Y989QzRXbN74HdxvQynZrLbsPG7bYglujtlbcFtxZoTV8AJNdNjxfWjoyXDAExQxBJvtyVeBjPpuzrDBs1PFE12mgrHTs-GyGfjYiYPaeWLRxE34IJ9cyn4-gV5SFfQLM6jiPgkwLKRDkCJsPNDdWBInWsYoD4cGbdv5S3dCZU1WN8xTdGprtdHW2Pdjpel_UNB7_6DckUXR9iHy7elFefkubtZxyhGVxpnK0WVJq9CczzUOJnqoNtYlc4sF2K8i02RHm6W_99eBV14xioguarLDlsu6D8E3FoQePa7l3IxFRBeZxhGpNI9aGut5SzM4qvvCBkpTO_PT_w3oJN3FBpR8PpofP4Dan0J2Q-1xuQ29xubTPEXst8heNkjP4et3r6hcFjkUr
openUrl ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=A+Blueprint+for+the+Synthesis+and+Characterization+of+Thiolated+Graphene&rft.jtitle=Nanomaterials+%28Basel%2C+Switzerland%29&rft.au=Maxim+K.+Rabchinskii&rft.au=Victor+V.+Sysoev&rft.au=Sergei+A.+Ryzhkov&rft.au=Ilya+A.+Eliseyev&rft.date=2021-12-24&rft.pub=MDPI+AG&rft.eissn=2079-4991&rft.volume=12&rft.issue=1&rft.spage=45&rft_id=info:doi/10.3390%2Fnano12010045&rft.externalDBID=DOA&rft.externalDocID=oai_doaj_org_article_20716a7beac44c148ac214140e1cd5f9
thumbnail_l http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=2079-4991&client=summon
thumbnail_m http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=2079-4991&client=summon
thumbnail_s http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=2079-4991&client=summon