X-ray Structure Elucidation of a Pt-Metalloporphyrin and Its Application for Obtaining Sensitive AuNPs-Plasmonic Hybrids Capable of Detecting Triiodide Anions
The development of UV⁻vis spectrophotometric methods based on metalloporphyrins for fast, highly sensitive and selective anion detection, which avoids several of the practical challenges associated with other detection methods, is of tremendous importance in analytical chemistry. In this study, we f...
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| Published in | International journal of molecular sciences Vol. 20; no. 3; p. 710 |
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| Main Authors | , , , , , , , , |
| Format | Journal Article |
| Language | English |
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MDPI AG
07.02.2019
MDPI |
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| Abstract | The development of UV⁻vis spectrophotometric methods based on metalloporphyrins for fast, highly sensitive and selective anion detection, which avoids several of the practical challenges associated with other detection methods, is of tremendous importance in analytical chemistry. In this study, we focused on achieving a selective optical sensor for triiodide ion detection in traces based on a novel hybrid material comprised of Pt(II) 5,10,15,20-tetra(4-methoxy-phenyl)-porphyrin (PtTMeOPP) and gold nanoparticles (AuNPs). This sensor has high relevance in medical physiological tests. The structure of PtTMeOPP was investigated by single crystal X-ray diffraction in order to understand the metal surroundings and the molecule conformation and to assess if it qualifies as a potential sensitive material. It was proven that the Pt-porphyrin generated 1D H-bond supramolecular chains due to the weak C-H···O intermolecular hydrogen bonding. The presence of ordered voids in the crystal encouraged us to use PtTMeOPP as the sensing material for triiodide ion and to enhance its potential in a novel AuNPs/PtTMeOPP hybrid by the synergistic effects provided by the plasmonic gold nanoparticles. The spectrophotometric sensor is characterized by a detection limit of 1.5 × 10
M triiodide ion concentration and a remarkable confidence coefficient of 99.98%. |
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| AbstractList | The development of UV⁻vis spectrophotometric methods based on metalloporphyrins for fast, highly sensitive and selective anion detection, which avoids several of the practical challenges associated with other detection methods, is of tremendous importance in analytical chemistry. In this study, we focused on achieving a selective optical sensor for triiodide ion detection in traces based on a novel hybrid material comprised of Pt(II) 5,10,15,20-tetra(4-methoxy-phenyl)-porphyrin (PtTMeOPP) and gold nanoparticles (AuNPs). This sensor has high relevance in medical physiological tests. The structure of PtTMeOPP was investigated by single crystal X-ray diffraction in order to understand the metal surroundings and the molecule conformation and to assess if it qualifies as a potential sensitive material. It was proven that the Pt-porphyrin generated 1D H-bond supramolecular chains due to the weak C-H···O intermolecular hydrogen bonding. The presence of ordered voids in the crystal encouraged us to use PtTMeOPP as the sensing material for triiodide ion and to enhance its potential in a novel AuNPs/PtTMeOPP hybrid by the synergistic effects provided by the plasmonic gold nanoparticles. The spectrophotometric sensor is characterized by a detection limit of 1.5 × 10
M triiodide ion concentration and a remarkable confidence coefficient of 99.98%. The development of UV⁻vis spectrophotometric methods based on metalloporphyrins for fast, highly sensitive and selective anion detection, which avoids several of the practical challenges associated with other detection methods, is of tremendous importance in analytical chemistry. In this study, we focused on achieving a selective optical sensor for triiodide ion detection in traces based on a novel hybrid material comprised of Pt(II) 5,10,15,20-tetra(4-methoxy-phenyl)-porphyrin (PtTMeOPP) and gold nanoparticles (AuNPs). This sensor has high relevance in medical physiological tests. The structure of PtTMeOPP was investigated by single crystal X-ray diffraction in order to understand the metal surroundings and the molecule conformation and to assess if it qualifies as a potential sensitive material. It was proven that the Pt-porphyrin generated 1D H-bond supramolecular chains due to the weak C-H···O intermolecular hydrogen bonding. The presence of ordered voids in the crystal encouraged us to use PtTMeOPP as the sensing material for triiodide ion and to enhance its potential in a novel AuNPs/PtTMeOPP hybrid by the synergistic effects provided by the plasmonic gold nanoparticles. The spectrophotometric sensor is characterized by a detection limit of 1.5 × 10−9 M triiodide ion concentration and a remarkable confidence coefficient of 99.98%. The development of UV–vis spectrophotometric methods based on metalloporphyrins for fast, highly sensitive and selective anion detection, which avoids several of the practical challenges associated with other detection methods, is of tremendous importance in analytical chemistry. In this study, we focused on achieving a selective optical sensor for triiodide ion detection in traces based on a novel hybrid material comprised of Pt(II) 5,10,15,20-tetra(4-methoxy-phenyl)-porphyrin (PtTMeOPP) and gold nanoparticles (AuNPs). This sensor has high relevance in medical physiological tests. The structure of PtTMeOPP was investigated by single crystal X-ray diffraction in order to understand the metal surroundings and the molecule conformation and to assess if it qualifies as a potential sensitive material. It was proven that the Pt-porphyrin generated 1D H-bond supramolecular chains due to the weak C-H···O intermolecular hydrogen bonding. The presence of ordered voids in the crystal encouraged us to use PtTMeOPP as the sensing material for triiodide ion and to enhance its potential in a novel AuNPs/PtTMeOPP hybrid by the synergistic effects provided by the plasmonic gold nanoparticles. The spectrophotometric sensor is characterized by a detection limit of 1.5 × 10 −9 M triiodide ion concentration and a remarkable confidence coefficient of 99.98%. The development of UV⁻vis spectrophotometric methods based on metalloporphyrins for fast, highly sensitive and selective anion detection, which avoids several of the practical challenges associated with other detection methods, is of tremendous importance in analytical chemistry. In this study, we focused on achieving a selective optical sensor for triiodide ion detection in traces based on a novel hybrid material comprised of Pt(II) 5,10,15,20-tetra(4-methoxy-phenyl)-porphyrin (PtTMeOPP) and gold nanoparticles (AuNPs). This sensor has high relevance in medical physiological tests. The structure of PtTMeOPP was investigated by single crystal X-ray diffraction in order to understand the metal surroundings and the molecule conformation and to assess if it qualifies as a potential sensitive material. It was proven that the Pt-porphyrin generated 1D H-bond supramolecular chains due to the weak C-H···O intermolecular hydrogen bonding. The presence of ordered voids in the crystal encouraged us to use PtTMeOPP as the sensing material for triiodide ion and to enhance its potential in a novel AuNPs/PtTMeOPP hybrid by the synergistic effects provided by the plasmonic gold nanoparticles. The spectrophotometric sensor is characterized by a detection limit of 1.5 × 10-9 M triiodide ion concentration and a remarkable confidence coefficient of 99.98%. Iodine is concentrated by the human body predominantly in the thyroid gland [4] and in other important storage tissues (especially for individuals who had their thyroid glands removed), such as the salivary glands, gastric mucosa, breast tissues, choroid plexus, ovaries and sweat glands. Based on this property, triiodide ions are used in pharmacology for the quantitative determination of ascorbic acid and hydroquinone in drugs [5]; in controlling the environment or human health by monitoring chlorine and dissolved O2 in water [6]; in control of industrial processes by detection of copper and iron in ores [7]; and even as a temperature radiation detector [8,9]. Based on the already proven synergistic effects of gold nanoparticles on electro-optical properties of metalloporphyrins and with the purpose to develop a better sensor with high relevance in medical physiological tests, a hybrid of PtTMeOPP with AuNPs [30] was obtained and tested as a sensitive material in the optical detection of triiodide ions. According to X-ray crystallography, the crystal has a molecular structure that is comprised of PtTMeOPP complex units and DMF as solvate molecules in a ratio of 2:1. The development of UV–vis spectrophotometric methods based on metalloporphyrins for fast, highly sensitive and selective anion detection, which avoids several of the practical challenges associated with other detection methods, is of tremendous importance in analytical chemistry. In this study, we focused on achieving a selective optical sensor for triiodide ion detection in traces based on a novel hybrid material comprised of Pt(II) 5,10,15,20-tetra(4-methoxy-phenyl)-porphyrin (PtTMeOPP) and gold nanoparticles (AuNPs). This sensor has high relevance in medical physiological tests. The structure of PtTMeOPP was investigated by single crystal X-ray diffraction in order to understand the metal surroundings and the molecule conformation and to assess if it qualifies as a potential sensitive material. It was proven that the Pt-porphyrin generated 1D H-bond supramolecular chains due to the weak C-H···O intermolecular hydrogen bonding. The presence of ordered voids in the crystal encouraged us to use PtTMeOPP as the sensing material for triiodide ion and to enhance its potential in a novel AuNPs/PtTMeOPP hybrid by the synergistic effects provided by the plasmonic gold nanoparticles. The spectrophotometric sensor is characterized by a detection limit of 1.5 × 10−9 M triiodide ion concentration and a remarkable confidence coefficient of 99.98%. |
| Author | Fagadar-Cosma, Eugenia Lascu, Anca Shova, Sergiu Balan, Adriana Anghel, Diana Croitor, Lilia Stamatin, Serban Zaltariov, Mirela-Fernanda Birdeanu, Mihaela |
| AuthorAffiliation | 4 3Nano-SAE Research Center, Faculty of Physics, University of Bucharest, Atomistilor Street, No 405, 077125 Măgurele, Romania; andronie@3nanosae.org (A.B.); serban@3nanosae.org (S.S.) 3 National Institute for Research and Development in Electrochemistry and Condensed Matter, P. Andronescu Street, No. 1, 300224 Timisoara, Romania; mihaione2002@yahoo.com 1 Institute of Chemistry Timisoara of Romanian Academy, Mihai Viteazu Ave. No. 24, 300223 Timisoara, Romania; croitor.lilia@gmail.com (L.C.); dianaracanel@yahoo.com (D.A.) 2 Laboratory of Inorganic Polymers, “Petru Poni” Institute of Macromolecular Chemistry, Aleea Grigore Ghica Voda No. 41A, RO-700487 Iasi, Romania; shova@icmpp.ro (S.S.); zaltariov.mirela@icmpp.ro (M.-F.Z.) |
| AuthorAffiliation_xml | – name: 1 Institute of Chemistry Timisoara of Romanian Academy, Mihai Viteazu Ave. No. 24, 300223 Timisoara, Romania; croitor.lilia@gmail.com (L.C.); dianaracanel@yahoo.com (D.A.) – name: 3 National Institute for Research and Development in Electrochemistry and Condensed Matter, P. Andronescu Street, No. 1, 300224 Timisoara, Romania; mihaione2002@yahoo.com – name: 4 3Nano-SAE Research Center, Faculty of Physics, University of Bucharest, Atomistilor Street, No 405, 077125 Măgurele, Romania; andronie@3nanosae.org (A.B.); serban@3nanosae.org (S.S.) – name: 2 Laboratory of Inorganic Polymers, “Petru Poni” Institute of Macromolecular Chemistry, Aleea Grigore Ghica Voda No. 41A, RO-700487 Iasi, Romania; shova@icmpp.ro (S.S.); zaltariov.mirela@icmpp.ro (M.-F.Z.) |
| Author_xml | – sequence: 1 givenname: Eugenia orcidid: 0000-0001-5668-709X surname: Fagadar-Cosma fullname: Fagadar-Cosma, Eugenia email: efagadar@yahoo.com organization: Institute of Chemistry Timisoara of Romanian Academy, Mihai Viteazu Ave. No. 24, 300223 Timisoara, Romania. efagadar@yahoo.com – sequence: 2 givenname: Anca orcidid: 0000-0002-6081-3324 surname: Lascu fullname: Lascu, Anca email: ancalascu@yahoo.com organization: Institute of Chemistry Timisoara of Romanian Academy, Mihai Viteazu Ave. No. 24, 300223 Timisoara, Romania. ancalascu@yahoo.com – sequence: 3 givenname: Sergiu surname: Shova fullname: Shova, Sergiu email: shova@icmpp.ro organization: Laboratory of Inorganic Polymers, "Petru Poni" Institute of Macromolecular Chemistry, Aleea Grigore Ghica Voda No. 41A, RO-700487 Iasi, Romania. shova@icmpp.ro – sequence: 4 givenname: Mirela-Fernanda surname: Zaltariov fullname: Zaltariov, Mirela-Fernanda email: zaltariov.mirela@icmpp.ro organization: Laboratory of Inorganic Polymers, "Petru Poni" Institute of Macromolecular Chemistry, Aleea Grigore Ghica Voda No. 41A, RO-700487 Iasi, Romania. zaltariov.mirela@icmpp.ro – sequence: 5 givenname: Mihaela surname: Birdeanu fullname: Birdeanu, Mihaela email: mihaione2002@yahoo.com organization: National Institute for Research and Development in Electrochemistry and Condensed Matter, P. Andronescu Street, No. 1, 300224 Timisoara, Romania. mihaione2002@yahoo.com – sequence: 6 givenname: Lilia orcidid: 0000-0003-0757-7358 surname: Croitor fullname: Croitor, Lilia email: croitor.lilia@gmail.com organization: Institute of Chemistry Timisoara of Romanian Academy, Mihai Viteazu Ave. No. 24, 300223 Timisoara, Romania. croitor.lilia@gmail.com – sequence: 7 givenname: Adriana surname: Balan fullname: Balan, Adriana email: andronie@3nanosae.org organization: 3Nano-SAE Research Center, Faculty of Physics, University of Bucharest, Atomistilor Street, No 405, 077125 Măgurele, Romania. andronie@3nanosae.org – sequence: 8 givenname: Diana orcidid: 0000-0002-8728-2367 surname: Anghel fullname: Anghel, Diana email: dianaracanel@yahoo.com organization: Institute of Chemistry Timisoara of Romanian Academy, Mihai Viteazu Ave. No. 24, 300223 Timisoara, Romania. dianaracanel@yahoo.com – sequence: 9 givenname: Serban surname: Stamatin fullname: Stamatin, Serban email: serban@3nanosae.org organization: 3Nano-SAE Research Center, Faculty of Physics, University of Bucharest, Atomistilor Street, No 405, 077125 Măgurele, Romania. serban@3nanosae.org |
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| Keywords | single crystal X-ray diffraction UV–vis spectroscopy AFM microscopy Pt(II) metalloporphyrin triiodide detection |
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| Snippet | The development of UV⁻vis spectrophotometric methods based on metalloporphyrins for fast, highly sensitive and selective anion detection, which avoids several... The development of UV–vis spectrophotometric methods based on metalloporphyrins for fast, highly sensitive and selective anion detection, which avoids several... Iodine is concentrated by the human body predominantly in the thyroid gland [4] and in other important storage tissues (especially for individuals who had... |
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| SubjectTerms | AFM microscopy Anions Ascorbic acid Breast Chlorine Choroid plexus Concentrates (ores) Copper ores Crystal structure Crystallography Dietary supplements Electrodes Environmental monitoring Fetuses Gastric mucosa Gold Hybrids Hydroquinone Iodine Minerals Molecular structure Nanoparticles Optical properties Ores Ovaries Pharmacology Physiological tests Polymers Pt(II) metalloporphyrin Radiation detectors Salivary gland Salivary glands single crystal X-ray diffraction Single crystals Solvents Sweat gland Thyroid Thyroid gland triiodide detection UV–vis spectroscopy X-ray crystallography |
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| Title | X-ray Structure Elucidation of a Pt-Metalloporphyrin and Its Application for Obtaining Sensitive AuNPs-Plasmonic Hybrids Capable of Detecting Triiodide Anions |
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