Mechanisms of Electron Transport and Recombination in ZnO Nanostructures for Dye-Sensitized Solar Cells
ZnO is an attractive material for applications in dye‐sensitized solar cells and related devices. This material has excellent electron‐transport properties in the bulk but its electron diffusion coefficient is much smaller in mesoporous films. In this work the electron‐transport properties of two di...
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Published in | Chemphyschem Vol. 15; no. 6; pp. 1088 - 1097 |
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Main Authors | , , , , , , , , |
Format | Journal Article |
Language | English |
Published |
Weinheim
WILEY-VCH Verlag
14.04.2014
WILEY‐VCH Verlag Wiley Wiley Subscription Services, Inc |
Subjects | |
Online Access | Get full text |
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Summary: | ZnO is an attractive material for applications in dye‐sensitized solar cells and related devices. This material has excellent electron‐transport properties in the bulk but its electron diffusion coefficient is much smaller in mesoporous films. In this work the electron‐transport properties of two different kinds of dye‐sensitized ZnO nanostructures are investigated by small‐perturbation electrochemical techniques. For nanoparticulate ZnO photoanodes prepared via a wet‐chemistry technique, the diffusion coefficient is found to reproduce the typical behavior predicted by the multiple‐trapping and the hopping models, with an exponential increase with respect to the applied bias. In contrast, in ZnO nanostructured thin films of controlled texture and crystallinity prepared via a plasma chemical vapor deposition method, the diffusion coefficient is found to be independent of the electrochemical bias. This observation suggests a different transport mechanism not controlled by trapping and electron accumulation. In spite of the quite different transport features, the recombination kinetics, the electron‐collection efficiency and the photoconversion efficiency are very similar for both kinds of photoanodes, an observation that indicates that surface properties rather than electron transport is the main efficiency‐determining factor in solar cells based on ZnO nanostructured photoanodes.
Two very different behaviors of the electron‐transport properties are found in nanostructured ZnO‐based photoanodes. Texturized samples show a voltage‐independent transport time, whereas films produced from nanocrystalline powders exhibit a voltage‐dependent signal, consistent with trap‐limited electron diffusion. |
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Bibliography: | ark:/67375/WNG-4N0HGDFS-C CONACYT Ministerio de Economía y Competitividad of Spain - No. CSD2007-00007; No. CSD2008-0002; No. CTQ2009-10477; No. MAT2010-21228; No. MAT2010-18447 Abengoa Research S.L. Junta de Andalucía CONACYT of Mexico ArticleID:CPHC201301068 istex:B27E1E4BBF75DA7FF619E8F95D4366C8DCD634D6 These two authors contributed equally to this work. |
ISSN: | 1439-4235 1439-7641 |
DOI: | 10.1002/cphc.201301068 |