Hydrotreatment of pyrolysis bio-oil: A review
Fast pyrolysis converts >60 wt% of lignocellulosic materials into bio-oil. The two-step bio-oil hydrotreatment concept has had a major impact in the development of bio-oil hydro-treatment. In the first step, known as stabilization, the carbonyl and carboxyl functional groups are transformed into...
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Published in | Fuel processing technology Vol. 195; no. C; p. 106140 |
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Main Authors | , , , , , , |
Format | Journal Article |
Language | English |
Published |
Amsterdam
Elsevier B.V
01.12.2019
Elsevier Science Ltd Elsevier |
Subjects | |
Online Access | Get full text |
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Abstract | Fast pyrolysis converts >60 wt% of lignocellulosic materials into bio-oil. The two-step bio-oil hydrotreatment concept has had a major impact in the development of bio-oil hydro-treatment. In the first step, known as stabilization, the carbonyl and carboxyl functional groups are transformed into alcohols between 373 and 573 K, in the presence of noble metals (Pt, Ru and Pd) supported on carbon and metal oxides. In the second step, between 623 and 673 K, cracking and hydro-deoxygenation occur using Ru, Ni or sulfided CoMo catalysts. Transition metal phosphides and carbides are also active. The first section is devoted to summarizing the current understanding of bio-oil composition. The second section is an overview of bio-oil hydrotreatment processing parameters. Many of the bio-oil hydrotreatment studies in the literature are based on model compound results, which are reviewed in the third section. Section four is devoted to review studies with bio-oil fractions and the nature of polymerization and cross linked reactions responsible for catalyst deactivation. The progress in the development of new catalysts is discussed in section five. The review ends with a discussion on future prospects and challenges to hydrotreat pyrolysis bio-oils.
•The two steps hydrotreatment concept had a major impact in the development of the field•Most common catalysts used in stabilization step: Pt, Ru and Pd•Most common catalysts for de-oxygenation: Ru, Ni and sulfided CoMo•Separation of bio-oil into fractions and separate processing is necessary•HDO of oligomeric fractions is challenging |
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AbstractList | Fast pyrolysis converts >60 wt% of lignocellulosic materials into bio-oil. The two-step bio-oil hydrotreatment concept has had a major impact in the development of bio-oil hydro-treatment. In the first step, known as stabilization, the carbonyl and carboxyl functional groups are transformed into alcohols between 373 and 573 K, in the presence of noble metals (Pt, Ru and Pd) supported on carbon and metal oxides. In the second step, between 623 and 673 K, cracking and hydro-deoxygenation occur using Ru, Ni or sulfided CoMo catalysts. Transition metal phosphides and carbides are also active. The first section is devoted to summarizing the current understanding of bio-oil composition. The second section is an overview of bio-oil hydrotreatment processing parameters. Many of the bio-oil hydrotreatment studies in the literature are based on model compound results, which are reviewed in the third section. Section four is devoted to review studies with bio-oil fractions and the nature of polymerization and cross linked reactions responsible for catalyst deactivation. The progress in the development of new catalysts is discussed in section five. The review ends with a discussion on future prospects and challenges to hydrotreat pyrolysis bio-oils. Fast pyrolysis converts >60 wt% of lignocellulosic materials into bio-oil. The two-step bio-oil hydrotreatment concept has had a major impact in the development of bio-oil hydro-treatment. In the first step, known as stabilization, the carbonyl and carboxyl functional groups are transformed into alcohols between 373 and 573 K, in the presence of noble metals (Pt, Ru and Pd) supported on carbon and metal oxides. In the second step, between 623 and 673 K, cracking and hydro-deoxygenation occur using Ru, Ni or sulfided CoMo catalysts. Transition metal phosphides and carbides are also active. The first section is devoted to summarizing the current understanding of bio-oil composition. The second section is an overview of bio-oil hydrotreatment processing parameters. Many of the bio-oil hydrotreatment studies in the literature are based on model compound results, which are reviewed in the third section. Section four is devoted to review studies with bio-oil fractions and the nature of polymerization and cross linked reactions responsible for catalyst deactivation. The progress in the development of new catalysts is discussed in section five. The review ends with a discussion on future prospects and challenges to hydrotreat pyrolysis bio-oils. •The two steps hydrotreatment concept had a major impact in the development of the field•Most common catalysts used in stabilization step: Pt, Ru and Pd•Most common catalysts for de-oxygenation: Ru, Ni and sulfided CoMo•Separation of bio-oil into fractions and separate processing is necessary•HDO of oligomeric fractions is challenging |
ArticleNumber | 106140 |
Author | Li, Chun-Zhu Garcia-Perez, Manuel Tran, Chi-Cong Kaliaguine, Serge Han, Yinglei Olarte, Mariefel Gholizadeh, Mortaza |
Author_xml | – sequence: 1 givenname: Yinglei surname: Han fullname: Han, Yinglei organization: Biological Systems Engineering Department, Washington State University, 99163, United States of America – sequence: 2 givenname: Mortaza surname: Gholizadeh fullname: Gholizadeh, Mortaza organization: Faculty of Chemical and Petroleum Engineering, University of Tabriz, Tabriz, Iran – sequence: 3 givenname: Chi-Cong surname: Tran fullname: Tran, Chi-Cong organization: Chemical Engineering Department, Laval University, Quebec, Canada – sequence: 4 givenname: Serge surname: Kaliaguine fullname: Kaliaguine, Serge organization: Chemical Engineering Department, Laval University, Quebec, Canada – sequence: 5 givenname: Chun-Zhu surname: Li fullname: Li, Chun-Zhu organization: Fuels and Energy Technology Institute, Curtin University, GPO Box U1987, Perth, WA 6845, Australia – sequence: 6 givenname: Mariefel surname: Olarte fullname: Olarte, Mariefel organization: Chemical and Biological Process Development Group, Pacific Northwest National Laboratory, Richland, WA 99352, United States of America – sequence: 7 givenname: Manuel surname: Garcia-Perez fullname: Garcia-Perez, Manuel email: mgarcia-perez@wsu.edu organization: Biological Systems Engineering Department, Washington State University, 99163, United States of America |
BackLink | https://www.osti.gov/biblio/1544915$$D View this record in Osti.gov |
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Snippet | Fast pyrolysis converts >60 wt% of lignocellulosic materials into bio-oil. The two-step bio-oil hydrotreatment concept has had a major impact in the... Fast pyrolysis converts >60 wt% of lignocellulosic materials into bio-oil. The two-step bio-oil hydrotreatment concept has had a major impact in the... |
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SubjectTerms | Alcohols Bio-oil hydrotreatment carbides carbon Carbonyls Catalysis Catalysts cracking crosslinking Deactivation Deoxygenation Functional groups Hydro-deoxygenation Hydrocracking Hydrotreatment mechanism Lignocellulose moieties Nickel Noble metals oxides Palladium Phosphides Platinum polymerization Process parameters Pyrolysis pyrolysis oils Ruthenium Transition metals |
Title | Hydrotreatment of pyrolysis bio-oil: A review |
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