Hydrotreatment of pyrolysis bio-oil: A review

Fast pyrolysis converts >60 wt% of lignocellulosic materials into bio-oil. The two-step bio-oil hydrotreatment concept has had a major impact in the development of bio-oil hydro-treatment. In the first step, known as stabilization, the carbonyl and carboxyl functional groups are transformed into...

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Published inFuel processing technology Vol. 195; no. C; p. 106140
Main Authors Han, Yinglei, Gholizadeh, Mortaza, Tran, Chi-Cong, Kaliaguine, Serge, Li, Chun-Zhu, Olarte, Mariefel, Garcia-Perez, Manuel
Format Journal Article
LanguageEnglish
Published Amsterdam Elsevier B.V 01.12.2019
Elsevier Science Ltd
Elsevier
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Abstract Fast pyrolysis converts >60 wt% of lignocellulosic materials into bio-oil. The two-step bio-oil hydrotreatment concept has had a major impact in the development of bio-oil hydro-treatment. In the first step, known as stabilization, the carbonyl and carboxyl functional groups are transformed into alcohols between 373 and 573 K, in the presence of noble metals (Pt, Ru and Pd) supported on carbon and metal oxides. In the second step, between 623 and 673 K, cracking and hydro-deoxygenation occur using Ru, Ni or sulfided CoMo catalysts. Transition metal phosphides and carbides are also active. The first section is devoted to summarizing the current understanding of bio-oil composition. The second section is an overview of bio-oil hydrotreatment processing parameters. Many of the bio-oil hydrotreatment studies in the literature are based on model compound results, which are reviewed in the third section. Section four is devoted to review studies with bio-oil fractions and the nature of polymerization and cross linked reactions responsible for catalyst deactivation. The progress in the development of new catalysts is discussed in section five. The review ends with a discussion on future prospects and challenges to hydrotreat pyrolysis bio-oils. •The two steps hydrotreatment concept had a major impact in the development of the field•Most common catalysts used in stabilization step: Pt, Ru and Pd•Most common catalysts for de-oxygenation: Ru, Ni and sulfided CoMo•Separation of bio-oil into fractions and separate processing is necessary•HDO of oligomeric fractions is challenging
AbstractList Fast pyrolysis converts >60 wt% of lignocellulosic materials into bio-oil. The two-step bio-oil hydrotreatment concept has had a major impact in the development of bio-oil hydro-treatment. In the first step, known as stabilization, the carbonyl and carboxyl functional groups are transformed into alcohols between 373 and 573 K, in the presence of noble metals (Pt, Ru and Pd) supported on carbon and metal oxides. In the second step, between 623 and 673 K, cracking and hydro-deoxygenation occur using Ru, Ni or sulfided CoMo catalysts. Transition metal phosphides and carbides are also active. The first section is devoted to summarizing the current understanding of bio-oil composition. The second section is an overview of bio-oil hydrotreatment processing parameters. Many of the bio-oil hydrotreatment studies in the literature are based on model compound results, which are reviewed in the third section. Section four is devoted to review studies with bio-oil fractions and the nature of polymerization and cross linked reactions responsible for catalyst deactivation. The progress in the development of new catalysts is discussed in section five. The review ends with a discussion on future prospects and challenges to hydrotreat pyrolysis bio-oils.
Fast pyrolysis converts >60 wt% of lignocellulosic materials into bio-oil. The two-step bio-oil hydrotreatment concept has had a major impact in the development of bio-oil hydro-treatment. In the first step, known as stabilization, the carbonyl and carboxyl functional groups are transformed into alcohols between 373 and 573 K, in the presence of noble metals (Pt, Ru and Pd) supported on carbon and metal oxides. In the second step, between 623 and 673 K, cracking and hydro-deoxygenation occur using Ru, Ni or sulfided CoMo catalysts. Transition metal phosphides and carbides are also active. The first section is devoted to summarizing the current understanding of bio-oil composition. The second section is an overview of bio-oil hydrotreatment processing parameters. Many of the bio-oil hydrotreatment studies in the literature are based on model compound results, which are reviewed in the third section. Section four is devoted to review studies with bio-oil fractions and the nature of polymerization and cross linked reactions responsible for catalyst deactivation. The progress in the development of new catalysts is discussed in section five. The review ends with a discussion on future prospects and challenges to hydrotreat pyrolysis bio-oils. •The two steps hydrotreatment concept had a major impact in the development of the field•Most common catalysts used in stabilization step: Pt, Ru and Pd•Most common catalysts for de-oxygenation: Ru, Ni and sulfided CoMo•Separation of bio-oil into fractions and separate processing is necessary•HDO of oligomeric fractions is challenging
ArticleNumber 106140
Author Li, Chun-Zhu
Garcia-Perez, Manuel
Tran, Chi-Cong
Kaliaguine, Serge
Han, Yinglei
Olarte, Mariefel
Gholizadeh, Mortaza
Author_xml – sequence: 1
  givenname: Yinglei
  surname: Han
  fullname: Han, Yinglei
  organization: Biological Systems Engineering Department, Washington State University, 99163, United States of America
– sequence: 2
  givenname: Mortaza
  surname: Gholizadeh
  fullname: Gholizadeh, Mortaza
  organization: Faculty of Chemical and Petroleum Engineering, University of Tabriz, Tabriz, Iran
– sequence: 3
  givenname: Chi-Cong
  surname: Tran
  fullname: Tran, Chi-Cong
  organization: Chemical Engineering Department, Laval University, Quebec, Canada
– sequence: 4
  givenname: Serge
  surname: Kaliaguine
  fullname: Kaliaguine, Serge
  organization: Chemical Engineering Department, Laval University, Quebec, Canada
– sequence: 5
  givenname: Chun-Zhu
  surname: Li
  fullname: Li, Chun-Zhu
  organization: Fuels and Energy Technology Institute, Curtin University, GPO Box U1987, Perth, WA 6845, Australia
– sequence: 6
  givenname: Mariefel
  surname: Olarte
  fullname: Olarte, Mariefel
  organization: Chemical and Biological Process Development Group, Pacific Northwest National Laboratory, Richland, WA 99352, United States of America
– sequence: 7
  givenname: Manuel
  surname: Garcia-Perez
  fullname: Garcia-Perez, Manuel
  email: mgarcia-perez@wsu.edu
  organization: Biological Systems Engineering Department, Washington State University, 99163, United States of America
BackLink https://www.osti.gov/biblio/1544915$$D View this record in Osti.gov
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Snippet Fast pyrolysis converts >60 wt% of lignocellulosic materials into bio-oil. The two-step bio-oil hydrotreatment concept has had a major impact in the...
Fast pyrolysis converts >60 wt% of lignocellulosic materials into bio-oil. The two-step bio-oil hydrotreatment concept has had a major impact in the...
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StartPage 106140
SubjectTerms Alcohols
Bio-oil hydrotreatment
carbides
carbon
Carbonyls
Catalysis
Catalysts
cracking
crosslinking
Deactivation
Deoxygenation
Functional groups
Hydro-deoxygenation
Hydrocracking
Hydrotreatment mechanism
Lignocellulose
moieties
Nickel
Noble metals
oxides
Palladium
Phosphides
Platinum
polymerization
Process parameters
Pyrolysis
pyrolysis oils
Ruthenium
Transition metals
Title Hydrotreatment of pyrolysis bio-oil: A review
URI https://dx.doi.org/10.1016/j.fuproc.2019.106140
https://www.proquest.com/docview/2283204285
https://www.proquest.com/docview/2286856431
https://www.osti.gov/biblio/1544915
Volume 195
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