Coordination Tunes Selectivity: Two‐Electron Oxygen Reduction on High‐Loading Molybdenum Single‐Atom Catalysts

• Published in: Angewandte Chemie (International ed.) Vol. 59; no. 23; pp. 9171 - 9176
• Main Authors: Tang, Cheng, Jiao, Yan, Shi, Bingyang, Liu, Jia‐Ning, Xie, Zhenhua, Chen, Xiao, Zhang, Qiang, Qiao, Shi‐Zhang
• Format: Journal Article
• Language: English
• Published: Germany Wiley Subscription Services, Inc 02.06.2020; Wiley
• Edition: International ed. in English
• Subjects: Catalysts; Chemical reduction; Coordination; electrocatalysis; Electrochemistry; Fine structure; Hydrogen peroxide; INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; Molybdenum; Oxygen; oxygen reduction reaction (ORR); Oxygen reduction reactions; Scanning transmission electron microscopy; Selectivity; Single atom catalysts; single-atom catalyst; Transmission electron microscopy; Ultrastructure; selectivity; single-atom catalyst; electrocatalysis; oxygen reduction reaction (ORR); molybdenum

Single‐atom catalysts (SACs) have great potential in electrocatalysis. Their performance can be rationally optimized by tailoring the metal atoms, adjacent coordinative dopants, and metal loading. However, doing so is still a great challenge because of the limited synthesis approach and insufficient...