Magnetite nanorod thermotropic liquid crystal colloids: Synthesis, optics and theory

• Published in: Journal of colloid and interface science Vol. 386; no. 1; pp. 158 - 166
• Main Authors: Podoliak, Nina, Buchnev, Oleksandr, Bavykin, Dmitry V., Kulak, Alexander N., Kaczmarek, Malgosia, Sluckin, Timothy J.
• Format: Journal Article
• Language: English
• Published: Amsterdam Elsevier Inc 15.11.2012; Elsevier
• Subjects: air; Chemistry; Coating; coatings; Colloidal state and disperse state; Colloids; Devices; Exact sciences and technology; Fe3O4; Ferronematics; General and physical chemistry; hot water treatment; Liquid crystals; Magnetite; Nanocomposites; Nanomaterials; nanoparticles; Nanorods; Nanostructure; Nanostructures; oleic acid; optics; Physical and chemical studies. Granulometry. Electrokinetic phenomena; sodium hydroxide; Fe3O4; Nanostructures; Liquid crystals; Ferronematics; Nanorods; Binary compound; Iron oxide; Nanoparticle; Theory; Composite material; O; Magnetite; Synthesis; Hydrothermal treatment; Carboxylic acid; Oleic acid; Polydispersed particle; Magnetic field; Nanorod; Diameter; Fe; Device; Transition element compounds; Nanostructure; Air; Colloid; Colloid particle; Magnetic suspension
• ISSN: 0021-9797; 1095-7103; 1095-7103
• DOI: 10.1016/j.jcis.2012.07.082

[Display omitted] ► Templateless preparation of magnetite nanorods by alkaline hydrothermal treatment. ► New surfactant improves magnetite nanorod–LC suspension stability. ► Strong nanorod–LC coupling leads to 20% reduction in LC Frederiks threshold. ► Theoretical model highlights routes to enhanced magneto-optical properties. ► Improved performance requires control of magnetic domains in magnetite nanorods. We have developed a facile method for preparing magnetic nanoparticles which couple strongly with a liquid crystal (LC) matrix, with the aim of preparing ferronematic liquid crystal colloids for use in magneto-optical devices. Magnetite nanoparticles were prepared by oxidising colloidal Fe(OH)2 with air in aqueous media, and were then subject to alkaline hydrothermal treatment with 10moldm−3 NaOH at 100°C, transforming them into a polydisperse set of domain magnetite nanorods with maximal length ∼500nm and typical diameter ∼20nm. The nanorods were coated with 4-n-octyloxybiphenyl-4-carboxylic acid (OBPh) and suspended in nematic liquid crystal E7. As compared to the conventional oleic acid coating, this coating stabilizes LC-magnetic nanorod suspensions. The suspension acts as a ferronematic system, using the colloidal particles as intermediaries to amplify magnetic field–LC director interactions. The effective Frederiks magnetic threshold field of the magnetite nanorod–liquid crystal composite is reduced by 20% as compared to the undoped liquid crystal. In contrast with some previous work in this field, the magneto-optical effects are reproducible on time scales of months. Prospects for magnetically switched liquid crystal devices using these materials are good, but a method is required to synthesize single magnetic domain nanorods.