Electrochemical determination of inorganic mercury and arsenic--A review
Inorganic mercury and arsenic encompasses a term which includes As(III), As(V) and Hg(II) species. These metal ions have been extensively studied due to their toxicity related issues. Different analytical methods are used to monitor inorganic mercury and arsenic in a variety of samples at trace leve...
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Published in | Biosensors & bioelectronics Vol. 74; pp. 895 - 908 |
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Main Authors | , , , |
Format | Journal Article |
Language | English |
Published |
England
01.12.2015
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Abstract | Inorganic mercury and arsenic encompasses a term which includes As(III), As(V) and Hg(II) species. These metal ions have been extensively studied due to their toxicity related issues. Different analytical methods are used to monitor inorganic mercury and arsenic in a variety of samples at trace level. The present study reviews various analytical techniques available for detection of inorganic mercury and arsenic with particular emphasis on electrochemical methods especially stripping voltammetry. A detailed critical evaluation of methods, advantages of electrochemical methods over other analytical methods, and various electrode materials available for mercury and arsenic analysis is presented in this review study. Modified carbon paste electrode provides better determination due to better deposition with linear and improved response under studied set of conditions. Biological materials may be the potent and economical alternative as compared to macro-electrodes and chemically modified carbon paste electrodes in stripping analysis of inorganic mercury and arsenic. |
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AbstractList | Inorganic mercury and arsenic encompasses a term which includes As(III), As(V) and Hg(II) species. These metal ions have been extensively studied due to their toxicity related issues. Different analytical methods are used to monitor inorganic mercury and arsenic in a variety of samples at trace level. The present study reviews various analytical techniques available for detection of inorganic mercury and arsenic with particular emphasis on electrochemical methods especially stripping voltammetry. A detailed critical evaluation of methods, advantages of electrochemical methods over other analytical methods, and various electrode materials available for mercury and arsenic analysis is presented in this review study. Modified carbon paste electrode provides better determination due to better deposition with linear and improved response under studied set of conditions. Biological materials may be the potent and economical alternative as compared to macro-electrodes and chemically modified carbon paste electrodes in stripping analysis of inorganic mercury and arsenic. |
Author | Farooq, Umar Zaib, Maria Saeed, Asma Athar, Muhammad Makshoof |
Author_xml | – sequence: 1 givenname: Maria surname: Zaib fullname: Zaib, Maria organization: Institute of Chemistry, University of the Punjab, Lahore 54590, Pakistan – sequence: 2 givenname: Muhammad Makshoof surname: Athar fullname: Athar, Muhammad Makshoof email: atharmakshoof@gmail.com organization: Institute of Chemistry, University of the Punjab, Lahore 54590, Pakistan. Electronic address: atharmakshoof@gmail.com – sequence: 3 givenname: Asma surname: Saeed fullname: Saeed, Asma organization: Food and Biotechnology Research Centre, PCSIR Laboratories Complex, Ferozepur Road, Lahore 54600, Pakistan – sequence: 4 givenname: Umar surname: Farooq fullname: Farooq, Umar organization: Institute of Chemistry, University of the Punjab, Lahore 54590, Pakistan |
BackLink | https://www.ncbi.nlm.nih.gov/pubmed/26253796$$D View this record in MEDLINE/PubMed |
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Keywords | Macro-electrodes Microbially modified carbon paste electrode Voltammetry Electrochemical methods Hg(II) As(III) |
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Snippet | Inorganic mercury and arsenic encompasses a term which includes As(III), As(V) and Hg(II) species. These metal ions have been extensively studied due to their... |
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SubjectTerms | Arsenic Arsenic - analysis Biological materials Carbon Conductometry - instrumentation Conductometry - methods Electrodes Environmental Monitoring - instrumentation Environmental Monitoring - methods Equipment Design Equipment Failure Analysis Inorganic Chemicals - analysis Mathematical analysis Mercury (metal) Mercury - analysis Pastes Stripping Water Pollutants, Chemical - analysis |
Title | Electrochemical determination of inorganic mercury and arsenic--A review |
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