Electrochemical determination of inorganic mercury and arsenic--A review

Inorganic mercury and arsenic encompasses a term which includes As(III), As(V) and Hg(II) species. These metal ions have been extensively studied due to their toxicity related issues. Different analytical methods are used to monitor inorganic mercury and arsenic in a variety of samples at trace leve...

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Published inBiosensors & bioelectronics Vol. 74; pp. 895 - 908
Main Authors Zaib, Maria, Athar, Muhammad Makshoof, Saeed, Asma, Farooq, Umar
Format Journal Article
LanguageEnglish
Published England 01.12.2015
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Abstract Inorganic mercury and arsenic encompasses a term which includes As(III), As(V) and Hg(II) species. These metal ions have been extensively studied due to their toxicity related issues. Different analytical methods are used to monitor inorganic mercury and arsenic in a variety of samples at trace level. The present study reviews various analytical techniques available for detection of inorganic mercury and arsenic with particular emphasis on electrochemical methods especially stripping voltammetry. A detailed critical evaluation of methods, advantages of electrochemical methods over other analytical methods, and various electrode materials available for mercury and arsenic analysis is presented in this review study. Modified carbon paste electrode provides better determination due to better deposition with linear and improved response under studied set of conditions. Biological materials may be the potent and economical alternative as compared to macro-electrodes and chemically modified carbon paste electrodes in stripping analysis of inorganic mercury and arsenic.
AbstractList Inorganic mercury and arsenic encompasses a term which includes As(III), As(V) and Hg(II) species. These metal ions have been extensively studied due to their toxicity related issues. Different analytical methods are used to monitor inorganic mercury and arsenic in a variety of samples at trace level. The present study reviews various analytical techniques available for detection of inorganic mercury and arsenic with particular emphasis on electrochemical methods especially stripping voltammetry. A detailed critical evaluation of methods, advantages of electrochemical methods over other analytical methods, and various electrode materials available for mercury and arsenic analysis is presented in this review study. Modified carbon paste electrode provides better determination due to better deposition with linear and improved response under studied set of conditions. Biological materials may be the potent and economical alternative as compared to macro-electrodes and chemically modified carbon paste electrodes in stripping analysis of inorganic mercury and arsenic.
Author Farooq, Umar
Zaib, Maria
Saeed, Asma
Athar, Muhammad Makshoof
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BackLink https://www.ncbi.nlm.nih.gov/pubmed/26253796$$D View this record in MEDLINE/PubMed
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Keywords Macro-electrodes
Microbially modified carbon paste electrode
Voltammetry
Electrochemical methods
Hg(II)
As(III)
Language English
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Snippet Inorganic mercury and arsenic encompasses a term which includes As(III), As(V) and Hg(II) species. These metal ions have been extensively studied due to their...
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StartPage 895
SubjectTerms Arsenic
Arsenic - analysis
Biological materials
Carbon
Conductometry - instrumentation
Conductometry - methods
Electrodes
Environmental Monitoring - instrumentation
Environmental Monitoring - methods
Equipment Design
Equipment Failure Analysis
Inorganic Chemicals - analysis
Mathematical analysis
Mercury (metal)
Mercury - analysis
Pastes
Stripping
Water Pollutants, Chemical - analysis
Title Electrochemical determination of inorganic mercury and arsenic--A review
URI https://www.ncbi.nlm.nih.gov/pubmed/26253796
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