Alkylating Reagents Employed in Catellani‐Type Reactions

• Published in: Chemistry : a European journal Vol. 24; no. 58; pp. 15461 - 15476
• Main Authors: Liu, Ze‐Shui, Gao, Qianwen, Cheng, Hong‐Gang, Zhou, Qianghui
• Format: Journal Article
• Language: English
• Published: Germany Wiley Subscription Services, Inc 17.10.2018
• Subjects: Alkylation; Aromatic compounds; Catalysis; Chemical reactions; Chemical synthesis; Chemistry; cooperative effects; homogeneous catalysis; Iodides; Organic chemistry; Palladium; Reagents; synthesis design; Catellani reaction palladium norbornene cooperative catalysis alkylating reagent

The Catellani reaction is a powerful strategy that allows the expeditious synthesis of highly substituted arenes, which are not easily accessible through traditional transition‐metal‐catalyzed cross‐coupling reactions. This reaction utilizes the synergistic interplay of palladium and norbornene cata...