A Metal Chelating Porous Polymeric Support: The Missing Link for a Defect‐Free Metal–Organic Framework Composite Membrane
Since the discovery of size‐selective metal–organic frameworks (MOFs), researchers have tried to incorporate these materials into gas separation membranes. Impressive gas selectivities were found, but these MOF membranes were mostly made on inorganic supports, which are generally too bulky and expen...
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| Published in | Angewandte Chemie International Edition Vol. 56; no. 11; pp. 2965 - 2968 |
|---|---|
| Main Authors | , , , , |
| Format | Journal Article |
| Language | English |
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Germany
Wiley Subscription Services, Inc
06.03.2017
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| Edition | International ed. in English |
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| Abstract | Since the discovery of size‐selective metal–organic frameworks (MOFs), researchers have tried to incorporate these materials into gas separation membranes. Impressive gas selectivities were found, but these MOF membranes were mostly made on inorganic supports, which are generally too bulky and expensive for industrial gas separation. Forming MOF layers on porous polymer supports is industrially attractive but technically challenging. Two features to overcome these problems are described: 1) a metal chelating support polymer to bind the MOF layer, and 2) control of MOF crystal growth by contra‐diffusion, aiming at a very thin nanocrystalline MOF layer. Using a metal chelating poly‐thiosemicarbazide (PTSC) support and adjusting the metal and organic ligand concentrations carefully, a very compact ZIF‐8 (ZIF=zeolitic imidazolate framework) layer was produced that displayed interference colors because of its smooth surface and extreme thinness—within the range of visible light. High performances were measured in terms of hydrogen/propane (8350) and propylene/propane (150) selectivity.
Thin‐film interference: An extremely thin, smooth, and defect‐free zeolitic imidazolate framework (ZIF‐8) layer displays interference colors similar to an oily film on water. The film was grown on top of a metal‐chelating polymer; the thickness was controlled by a contra‐diffusion preparative method. |
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| AbstractList | Since the discovery of size-selective metal-organic frameworks (MOFs), researchers have tried to incorporate these materials into gas separation membranes. Impressive gas selectivities were found, but these MOF membranes were mostly made on inorganic supports, which are generally too bulky and expensive for industrial gas separation. Forming MOF layers on porous polymer supports is industrially attractive but technically challenging. Two features to overcome these problems are described: 1) a metal chelating support polymer to bind the MOF layer, and 2) control of MOF crystal growth by contra-diffusion, aiming at a very thin nanocrystalline MOF layer. Using a metal chelating poly-thiosemicarbazide (PTSC) support and adjusting the metal and organic ligand concentrations carefully, a very compact ZIF-8 (ZIF=zeolitic imidazolate framework) layer was produced that displayed interference colors because of its smooth surface and extreme thinness-within the range of visible light. High performances were measured in terms of hydrogen/propane (8350) and propylene/propane (150) selectivity.Since the discovery of size-selective metal-organic frameworks (MOFs), researchers have tried to incorporate these materials into gas separation membranes. Impressive gas selectivities were found, but these MOF membranes were mostly made on inorganic supports, which are generally too bulky and expensive for industrial gas separation. Forming MOF layers on porous polymer supports is industrially attractive but technically challenging. Two features to overcome these problems are described: 1) a metal chelating support polymer to bind the MOF layer, and 2) control of MOF crystal growth by contra-diffusion, aiming at a very thin nanocrystalline MOF layer. Using a metal chelating poly-thiosemicarbazide (PTSC) support and adjusting the metal and organic ligand concentrations carefully, a very compact ZIF-8 (ZIF=zeolitic imidazolate framework) layer was produced that displayed interference colors because of its smooth surface and extreme thinness-within the range of visible light. High performances were measured in terms of hydrogen/propane (8350) and propylene/propane (150) selectivity. Since the discovery of size-selective metal-organic frameworks (MOFs), researchers have tried to incorporate these materials into gas separation membranes. Impressive gas selectivities were found, but these MOF membranes were mostly made on inorganic supports, which are generally too bulky and expensive for industrial gas separation. Forming MOF layers on porous polymer supports is industrially attractive but technically challenging. Two features to overcome these problems are described: 1) a metal chelating support polymer to bind the MOF layer, and 2) control of MOF crystal growth by contra-diffusion, aiming at a very thin nanocrystalline MOF layer. Using a metal chelating poly-thiosemicarbazide (PTSC) support and adjusting the metal and organic ligand concentrations carefully, a very compact ZIF-8 (ZIF=zeolitic imidazolate framework) layer was produced that displayed interference colors because of its smooth surface and extreme thinness-within the range of visible light. High performances were measured in terms of hydrogen/propane (8350) and propylene/propane (150) selectivity. Since the discovery of size‐selective metal–organic frameworks (MOFs), researchers have tried to incorporate these materials into gas separation membranes. Impressive gas selectivities were found, but these MOF membranes were mostly made on inorganic supports, which are generally too bulky and expensive for industrial gas separation. Forming MOF layers on porous polymer supports is industrially attractive but technically challenging. Two features to overcome these problems are described: 1) a metal chelating support polymer to bind the MOF layer, and 2) control of MOF crystal growth by contra‐diffusion, aiming at a very thin nanocrystalline MOF layer. Using a metal chelating poly‐thiosemicarbazide (PTSC) support and adjusting the metal and organic ligand concentrations carefully, a very compact ZIF‐8 (ZIF=zeolitic imidazolate framework) layer was produced that displayed interference colors because of its smooth surface and extreme thinness—within the range of visible light. High performances were measured in terms of hydrogen/propane (8350) and propylene/propane (150) selectivity. Thin‐film interference: An extremely thin, smooth, and defect‐free zeolitic imidazolate framework (ZIF‐8) layer displays interference colors similar to an oily film on water. The film was grown on top of a metal‐chelating polymer; the thickness was controlled by a contra‐diffusion preparative method. |
| Author | Tan, Xiaoyu Peinemann, Klaus‐Viktor Villalobos, Luis Francisco Litwiller, Eric Barankova, Eva |
| Author_xml | – sequence: 1 givenname: Eva surname: Barankova fullname: Barankova, Eva organization: King Abdullah University of Science and Technology (KAUST) – sequence: 2 givenname: Xiaoyu surname: Tan fullname: Tan, Xiaoyu organization: King Abdullah University of Science and Technology (KAUST) – sequence: 3 givenname: Luis Francisco orcidid: 0000-0002-0745-4246 surname: Villalobos fullname: Villalobos, Luis Francisco organization: King Abdullah University of Science and Technology (KAUST) – sequence: 4 givenname: Eric orcidid: 0000-0001-5366-0967 surname: Litwiller fullname: Litwiller, Eric organization: King Abdullah University of Science and Technology (KAUST) – sequence: 5 givenname: Klaus‐Viktor orcidid: 0000-0003-0309-9598 surname: Peinemann fullname: Peinemann, Klaus‐Viktor email: klausviktor.peinemann@kaust.edu.sa organization: King Abdullah University of Science and Technology (KAUST) |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/28165189$$D View this record in MEDLINE/PubMed |
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| Cites_doi | 10.1039/c2cc36233c 10.1021/acs.jpclett.5b01602 10.1002/ange.201511340 10.1021/acs.nanolett.5b00275 10.1016/j.micromeso.2013.05.015 10.1016/j.reactfunctpolym.2014.09.011 10.1126/science.1251181 10.1021/ja907359t 10.1016/j.micromeso.2012.07.049 10.1002/pol.1962.1206217411 10.1021/acsami.5b12684 10.1016/j.micromeso.2015.08.038 10.1016/j.cattod.2013.10.067 10.1002/anie.201511340 10.1002/chem.201500007 10.1039/C4CC06699E 10.1002/(SICI)1099-0488(19960930)34:13<2209::AID-POLB10>3.0.CO;2-9 10.1016/S0376-7388(02)00430-1 10.1016/j.ces.2015.04.011 10.1002/pol.1962.1206217410 10.1002/marc.201500735 10.1016/j.memsci.2014.03.070 10.1039/c3cc45196h 10.1039/C3TA13781C 10.1016/j.seppur.2014.08.027 10.1039/c0cc04734a |
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| Copyright | 2017 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim |
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| Keywords | propylene/propane separation contra-diffusion composite membranes gas separation metal-organic frameworks |
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| References_xml | – volume: 136 start-page: 94 year: 2014 end-page: 104 publication-title: Sep. Purif. Technol. – volume: 34 start-page: 2209 year: 1996 end-page: 2222 publication-title: J. Polym. Sci. Part B – volume: 48 start-page: 11434 year: 2012 end-page: 11436 publication-title: Chem. Commun. – volume: 15 start-page: 3166 year: 2015 end-page: 3171 publication-title: Nano Lett. – volume: 62 start-page: 387 year: 1962 end-page: 399 publication-title: J. Polym. Sci. – volume: 86 start-page: 225 year: 2015 end-page: 232 publication-title: React. Funct. Polym. – volume: 21 start-page: 7224 year: 2015 end-page: 7230 publication-title: Chem. Eur. J. – volume: 165 start-page: 32 year: 2013 end-page: 39 publication-title: Microporous Mesoporous Mater. – volume: 464 start-page: 119 year: 2014 end-page: 126 publication-title: J. Membr. Sci. – volume: 51 start-page: 918 year: 2015 end-page: 920 publication-title: Chem. Commun. – volume: 47 start-page: 2559 year: 2011 end-page: 2561 publication-title: Chem. Commun. – volume: 2 start-page: 2110 year: 2014 end-page: 2118 publication-title: J. Mater. Chem. A – volume: 62 start-page: 379 year: 1962 end-page: 386 publication-title: J. Polym. Sci. – volume: 179 start-page: 10 year: 2013 end-page: 16 publication-title: Microporous Mesoporous Mater. – volume: 135 start-page: 232 year: 2015 end-page: 257 publication-title: Chem. Eng. Sci. – volume: 131 start-page: 16000 year: 2009 end-page: 16001 publication-title: J. Am. Chem. Soc. – volume: 6 start-page: 3841 year: 2015 end-page: 3849 publication-title: J. Phys. Chem. Lett. – volume: 236 start-page: 92 year: 2014 end-page: 97 publication-title: Catal. Today – volume: 37 start-page: 700 year: 2016 end-page: 704 publication-title: Macromol. Rapid Commun. – volume: 8 start-page: 6236 year: 2016 end-page: 6244 publication-title: ACS Appl. Mater. Interfaces – volume: 49 start-page: 9419 year: 2013 end-page: 9421 publication-title: Chem. Commun. – volume: 55 128 start-page: 3947 4015 year: 2016 2016 end-page: 3951 4019 publication-title: Angew. Chem. Int. Ed. Angew. Chem. – volume: 220 start-page: 215 year: 2016 end-page: 219 publication-title: Microporous Mesoporous Mater. – volume: 345 start-page: 72 year: 2014 end-page: 75 publication-title: Science – volume: 211 start-page: 299 year: 2003 end-page: 309 publication-title: J. Membr. Sci. – ident: e_1_2_2_14_1 doi: 10.1039/c2cc36233c – ident: e_1_2_2_2_1 doi: 10.1021/acs.jpclett.5b01602 – ident: e_1_2_2_15_2 doi: 10.1002/ange.201511340 – ident: e_1_2_2_20_1 doi: 10.1021/acs.nanolett.5b00275 – ident: e_1_2_2_23_1 doi: 10.1016/j.micromeso.2013.05.015 – ident: e_1_2_2_18_1 doi: 10.1016/j.reactfunctpolym.2014.09.011 – ident: e_1_2_2_12_1 doi: 10.1126/science.1251181 – ident: e_1_2_2_4_1 doi: 10.1021/ja907359t – ident: e_1_2_2_3_1 doi: 10.1016/j.micromeso.2012.07.049 – ident: e_1_2_2_17_1 doi: 10.1002/pol.1962.1206217411 – ident: e_1_2_2_11_1 doi: 10.1021/acsami.5b12684 – ident: e_1_2_2_6_1 doi: 10.1016/j.micromeso.2015.08.038 – ident: e_1_2_2_21_1 doi: 10.1016/j.cattod.2013.10.067 – ident: e_1_2_2_15_1 doi: 10.1002/anie.201511340 – ident: e_1_2_2_10_1 doi: 10.1002/chem.201500007 – ident: e_1_2_2_13_1 doi: 10.1039/C4CC06699E – ident: e_1_2_2_24_1 doi: 10.1002/(SICI)1099-0488(19960930)34:13<2209::AID-POLB10>3.0.CO;2-9 – ident: e_1_2_2_25_1 doi: 10.1016/S0376-7388(02)00430-1 – ident: e_1_2_2_1_1 doi: 10.1016/j.ces.2015.04.011 – ident: e_1_2_2_16_1 doi: 10.1002/pol.1962.1206217410 – ident: e_1_2_2_22_1 doi: 10.1002/marc.201500735 – ident: e_1_2_2_9_1 doi: 10.1016/j.memsci.2014.03.070 – ident: e_1_2_2_8_1 doi: 10.1039/c3cc45196h – ident: e_1_2_2_7_1 doi: 10.1039/C3TA13781C – ident: e_1_2_2_19_1 doi: 10.1016/j.seppur.2014.08.027 – ident: e_1_2_2_5_1 doi: 10.1039/c0cc04734a |
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| Snippet | Since the discovery of size‐selective metal–organic frameworks (MOFs), researchers have tried to incorporate these materials into gas separation membranes.... Since the discovery of size-selective metal-organic frameworks (MOFs), researchers have tried to incorporate these materials into gas separation membranes.... |
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| StartPage | 2965 |
| SubjectTerms | Chelation Composite materials composite membranes contra-diffusion Crystal growth Diffusion layers Gas separation Membranes Metal concentrations Metal-organic frameworks Polymers Propane Propylene propylene/propane separation Selectivity |
| Title | A Metal Chelating Porous Polymeric Support: The Missing Link for a Defect‐Free Metal–Organic Framework Composite Membrane |
| URI | https://onlinelibrary.wiley.com/doi/abs/10.1002%2Fanie.201611927 https://www.ncbi.nlm.nih.gov/pubmed/28165189 https://www.proquest.com/docview/1967854420 https://www.proquest.com/docview/1865544387 |
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