Large‐Amplitude Thermal Vibration‐Coupled Valence Tautomeric Transition Observed in a Conductive One‐Dimensional Rhodium–Dioxolene Complex

• Published in: Chemistry : a European journal Vol. 27; no. 9; pp. 3074 - 3084
• Main Authors: Mitsumi, Minoru, Komatsu, Yuuki, Hashimoto, Masahiro, Toriumi, Koshiro, Kitagawa, Yasutaka, Miyazaki, Yuji, Akutsu, Hiroki, Akashi, Haruo
• Format: Journal Article
• Language: English
• Published: Germany Wiley Subscription Services, Inc 10.02.2021
• Subjects: Amplitudes; Chemistry; conducting materials; Coupling (molecular); Crystals; Electron transfer; large-amplitude vibration; mixed-valent compounds; Phase transitions; Photoelectron spectroscopy; Photoelectrons; Rhodium; Valence; valence tautomerism; Vibration; vibronic interactions; conducting materials; large-amplitude vibration; valence tautomerism; mixed-valent compounds; vibronic interactions

The exploration of dynamic molecular crystals is a fascinating theme for materials scientists owing to their fundamental science and potential application to molecular devices. Herein, a one‐dimensional (1D) rhodium‐dioxolene complex is reported that exhibits drastic changes in properties with the p...