Zeolite‐Encaged Single‐Atom Rhodium Catalysts: Highly‐Efficient Hydrogen Generation and Shape‐Selective Tandem Hydrogenation of Nitroarenes

• Published in: Angewandte Chemie International Edition Vol. 58; no. 51; pp. 18570 - 18576
• Main Authors: Sun, Qiming, Wang, Ning, Zhang, Tianjun, Bai, Risheng, Mayoral, Alvaro, Zhang, Peng, Zhang, Qinghong, Terasaki, Osamu, Yu, Jihong
• Format: Journal Article
• Language: English
• Published: WEINHEIM Wiley 16.12.2019; Wiley Subscription Services, Inc
• Edition: International ed. in English
• Subjects: Ammonia; Catalysis; Catalysts; Chemical synthesis; Chemistry; Chemistry, Multidisciplinary; hydrogen generation; Hydrogen production; Hydrogen storage; Hydrogenation; Hydrolysis; Oxygen atoms; Physical Sciences; Rhodium; Scanning transmission electron microscopy; Science & Technology; Single atom catalysts; tandem reactions; Transmission electron microscopy; Zeolites; single-atom catalysts; OXIDATION; TRANSFORMATION; STORAGE; HYDROLYTIC DEHYDROGENATION; PLATINUM; AMMONIA-BORANE; CO; NANOPARTICLES; zeolites; CLUSTERS; hydrogen generation; SITES; tandem reactions; rhodium

Single‐atom catalysts are emerging as a new frontier in heterogeneous catalysis because of their maximum atom utilization efficiency, but they usually suffer from inferior stability. Herein, we synthesized single‐atom Rh catalysts embedded in MFI‐type zeolites under hydrothermal conditions and subse...