Single‐Step Synthesis of Organometallic Molecular Squares from NR,NR′,NR′′,NR′′′‐Substituted Benzobiscarbenes
The single‐step multicomponent self‐assembly of molecular squares featuring four bridging benzobiscarbenes and four PdII(allyl) or IrI(COD) vertices is presented. Four equivalents of the linear benzobisimidazolium salt [1](PF6)2 react with two equivalents of [Pd(allyl)Cl]2 or [IrCl(COD)]2 in the pre...
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| Published in | Chemistry : a European journal Vol. 23; no. 25; pp. 5939 - 5942 |
|---|---|
| Main Authors | , , , |
| Format | Journal Article |
| Language | English |
| Published |
Germany
Wiley Subscription Services, Inc
02.05.2017
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| Subjects | |
| Online Access | Get full text |
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| Abstract | The single‐step multicomponent self‐assembly of molecular squares featuring four bridging benzobiscarbenes and four PdII(allyl) or IrI(COD) vertices is presented. Four equivalents of the linear benzobisimidazolium salt [1](PF6)2 react with two equivalents of [Pd(allyl)Cl]2 or [IrCl(COD)]2 in the presence of Cs2CO3 to yield the tetranuclear octacarbene molecular squares [2](PF6)4 (M=Pd) and [3](PF6)4 (M=Ir), respectively. Compounds [2](PF6)4 and [3](PF6)4 feature exclusively M–carbon bonds making them the first purely organometallic molecular squares.
First time! Organometallic molecular squares featuring four NR,NR‐substituted dicarbene ligands and four PdII or IrI vertices have been synthesized by a single‐step multicomponent procedure. Uniquely, the metal centers in the molecular squares feature only M−C bonds. |
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| AbstractList | The single-step multicomponent self-assembly of molecular squares featuring four bridging benzobiscarbenes and four Pd
(allyl) or Ir
(COD) vertices is presented. Four equivalents of the linear benzobisimidazolium salt [1](PF
)
react with two equivalents of [Pd(allyl)Cl]
or [IrCl(COD)]
in the presence of Cs
CO
to yield the tetranuclear octacarbene molecular squares [2](PF
)
(M=Pd) and [3](PF
)
(M=Ir), respectively. Compounds [2](PF
)
and [3](PF
)
feature exclusively M-carbon bonds making them the first purely organometallic molecular squares. The single-step multicomponent self-assembly of molecular squares featuring four bridging benzobiscarbenes and four PdII(allyl) or IrI(COD) vertices is presented. Four equivalents of the linear benzobisimidazolium salt [1](PF6)2 react with two equivalents of [Pd(allyl)Cl]2 or [IrCl(COD)]2 in the presence of Cs2CO3 to yield the tetranuclear octacarbene molecular squares [2](PF6)4 (M=Pd) and [3](PF6)4 (M=Ir), respectively. Compounds [2](PF6)4 and [3](PF6)4 feature exclusively M-carbon bonds making them the first purely organometallic molecular squares. The single‐step multicomponent self‐assembly of molecular squares featuring four bridging benzobiscarbenes and four PdII(allyl) or IrI(COD) vertices is presented. Four equivalents of the linear benzobisimidazolium salt [1](PF6)2 react with two equivalents of [Pd(allyl)Cl]2 or [IrCl(COD)]2 in the presence of Cs2CO3 to yield the tetranuclear octacarbene molecular squares [2](PF6)4 (M=Pd) and [3](PF6)4 (M=Ir), respectively. Compounds [2](PF6)4 and [3](PF6)4 feature exclusively M–carbon bonds making them the first purely organometallic molecular squares. First time! Organometallic molecular squares featuring four NR,NR‐substituted dicarbene ligands and four PdII or IrI vertices have been synthesized by a single‐step multicomponent procedure. Uniquely, the metal centers in the molecular squares feature only M−C bonds. The single‐step multicomponent self‐assembly of molecular squares featuring four bridging benzobiscarbenes and four Pd II (allyl) or Ir I (COD) vertices is presented. Four equivalents of the linear benzobisimidazolium salt [ 1 ](PF 6 ) 2 react with two equivalents of [Pd(allyl)Cl] 2 or [IrCl(COD)] 2 in the presence of Cs 2 CO 3 to yield the tetranuclear octacarbene molecular squares [ 2 ](PF 6 ) 4 (M=Pd) and [ 3 ](PF 6 ) 4 (M=Ir), respectively. Compounds [ 2 ](PF 6 ) 4 and [ 3 ](PF 6 ) 4 feature exclusively M–carbon bonds making them the first purely organometallic molecular squares. The single-step multicomponent self-assembly of molecular squares featuring four bridging benzobiscarbenes and four PdII (allyl) or IrI (COD) vertices is presented. Four equivalents of the linear benzobisimidazolium salt [1](PF6 )2 react with two equivalents of [Pd(allyl)Cl]2 or [IrCl(COD)]2 in the presence of Cs2 CO3 to yield the tetranuclear octacarbene molecular squares [2](PF6 )4 (M=Pd) and [3](PF6 )4 (M=Ir), respectively. Compounds [2](PF6 )4 and [3](PF6 )4 feature exclusively M-carbon bonds making them the first purely organometallic molecular squares.The single-step multicomponent self-assembly of molecular squares featuring four bridging benzobiscarbenes and four PdII (allyl) or IrI (COD) vertices is presented. Four equivalents of the linear benzobisimidazolium salt [1](PF6 )2 react with two equivalents of [Pd(allyl)Cl]2 or [IrCl(COD)]2 in the presence of Cs2 CO3 to yield the tetranuclear octacarbene molecular squares [2](PF6 )4 (M=Pd) and [3](PF6 )4 (M=Ir), respectively. Compounds [2](PF6 )4 and [3](PF6 )4 feature exclusively M-carbon bonds making them the first purely organometallic molecular squares. |
| Author | Roelfes, Florian Hahn, F. Ekkehardt Hepp, Alexander Sinha, Narayan |
| Author_xml | – sequence: 1 givenname: Narayan surname: Sinha fullname: Sinha, Narayan organization: Westfälische Wilhelms-Universität Münster – sequence: 2 givenname: Florian surname: Roelfes fullname: Roelfes, Florian organization: Westfälische Wilhelms-Universität Münster – sequence: 3 givenname: Alexander surname: Hepp fullname: Hepp, Alexander organization: Westfälische Wilhelms-Universität Münster – sequence: 4 givenname: F. Ekkehardt surname: Hahn fullname: Hahn, F. Ekkehardt email: fehahn@uni-muenster.de organization: Westfälische Wilhelms-Universität Münster |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/27786392$$D View this record in MEDLINE/PubMed |
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| Copyright | 2017 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim |
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| Keywords | self-assembly molecular squares supramolecular chemistry carbene ligands transition metals |
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| Snippet | The single‐step multicomponent self‐assembly of molecular squares featuring four bridging benzobiscarbenes and four PdII(allyl) or IrI(COD) vertices is... The single‐step multicomponent self‐assembly of molecular squares featuring four bridging benzobiscarbenes and four Pd II (allyl) or Ir I (COD) vertices is... The single-step multicomponent self-assembly of molecular squares featuring four bridging benzobiscarbenes and four Pd (allyl) or Ir (COD) vertices is... The single-step multicomponent self-assembly of molecular squares featuring four bridging benzobiscarbenes and four PdII(allyl) or IrI(COD) vertices is... The single-step multicomponent self-assembly of molecular squares featuring four bridging benzobiscarbenes and four PdII (allyl) or IrI (COD) vertices is... |
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| SubjectTerms | Apexes carbene ligands Chemical synthesis Chemistry Equivalence molecular squares Self-assembly supramolecular chemistry transition metals |
| Title | Single‐Step Synthesis of Organometallic Molecular Squares from NR,NR′,NR′′,NR′′′‐Substituted Benzobiscarbenes |
| URI | https://onlinelibrary.wiley.com/doi/abs/10.1002%2Fchem.201604996 https://www.ncbi.nlm.nih.gov/pubmed/27786392 https://www.proquest.com/docview/1895084805 https://www.proquest.com/docview/1835687284 |
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