Stimuli‐Responsive Purely Organic Room‐Temperature Phosphorescence Materials
This Minireview summarizes the recent progress of stimuli‐responsive purely organic phosphorescence materials. Organic phosphorescence is closely related to the intermolecular interactions, because such interactions are beneficial to promote spin orbital coupling (SOC) and boost intersystem cross (I...
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| Published in | Chemistry : a European journal Vol. 26; no. 52; pp. 11914 - 11930 |
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| Main Authors | , , |
| Format | Journal Article |
| Language | English |
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16.09.2020
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| Abstract | This Minireview summarizes the recent progress of stimuli‐responsive purely organic phosphorescence materials. Organic phosphorescence is closely related to the intermolecular interactions, because such interactions are beneficial to promote spin orbital coupling (SOC) and boost intersystem cross (ISC) efficiency and finally are conducive to satisfactory phosphorescence. It is found that the intermolecular interactions, which are essential for organic phosphorescence, are easily disturbed by external stimuli such as mechanical force, photon, acid, chemical vapor, leading to the luminescence change. According to this principle, various purely organic phosphorescence materials sensitive to external stimuli have been developed. This Minireview categorizes reported stimuli‐responsive purely organic phosphorescence materials on the basis of different stimuli, including mechanochromism, mechanoluminescence, photoactivity, acid‐responsiveness and other stimuli. Some prospective strategies for constructing stimuli‐responsive purely organic phosphorescence molecules are provided.
Stimulus check: The minireview categorizes reported stimuli‐responsive purely organic phosphorescence materials on the basis of different stimuli, including mechanochromism, mechanoluminescence, photoactivity, acid‐responsiveness and other stimuli. Some prospective strategies for constructing stimuli‐responsive purely organic phosphorescence molecules are provided. |
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| AbstractList | This Minireview summarizes the recent progress of stimuli-responsive purely organic phosphorescence materials. Organic phosphorescence is closely related to the intermolecular interactions, because such interactions are beneficial to promote spin orbital coupling (SOC) and boost intersystem cross (ISC) efficiency and finally are conducive to satisfactory phosphorescence. It is found that the intermolecular interactions, which are essential for organic phosphorescence, are easily disturbed by external stimuli such as mechanical force, photon, acid, chemical vapor, leading to the luminescence change. According to this principle, various purely organic phosphorescence materials sensitive to external stimuli have been developed. This Minireview categorizes reported stimuli-responsive purely organic phosphorescence materials on the basis of different stimuli, including mechanochromism, mechanoluminescence, photoactivity, acid-responsiveness and other stimuli. Some prospective strategies for constructing stimuli-responsive purely organic phosphorescence molecules are provided. This Minireview summarizes the recent progress of stimuli-responsive purely organic phosphorescence materials. Organic phosphorescence is closely related to the intermolecular interactions, because such interactions are beneficial to promote spin orbital coupling (SOC) and boost intersystem cross (ISC) efficiency and finally are conducive to satisfactory phosphorescence. It is found that the intermolecular interactions, which are essential for organic phosphorescence, are easily disturbed by external stimuli such as mechanical force, photon, acid, chemical vapor, leading to the luminescence change. According to this principle, various purely organic phosphorescence materials sensitive to external stimuli have been developed. This Minireview categorizes reported stimuli-responsive purely organic phosphorescence materials on the basis of different stimuli, including mechanochromism, mechanoluminescence, photoactivity, acid-responsiveness and other stimuli. Some prospective strategies for constructing stimuli-responsive purely organic phosphorescence molecules are provided.This Minireview summarizes the recent progress of stimuli-responsive purely organic phosphorescence materials. Organic phosphorescence is closely related to the intermolecular interactions, because such interactions are beneficial to promote spin orbital coupling (SOC) and boost intersystem cross (ISC) efficiency and finally are conducive to satisfactory phosphorescence. It is found that the intermolecular interactions, which are essential for organic phosphorescence, are easily disturbed by external stimuli such as mechanical force, photon, acid, chemical vapor, leading to the luminescence change. According to this principle, various purely organic phosphorescence materials sensitive to external stimuli have been developed. This Minireview categorizes reported stimuli-responsive purely organic phosphorescence materials on the basis of different stimuli, including mechanochromism, mechanoluminescence, photoactivity, acid-responsiveness and other stimuli. Some prospective strategies for constructing stimuli-responsive purely organic phosphorescence molecules are provided. This Minireview summarizes the recent progress of stimuli‐responsive purely organic phosphorescence materials. Organic phosphorescence is closely related to the intermolecular interactions, because such interactions are beneficial to promote spin orbital coupling (SOC) and boost intersystem cross (ISC) efficiency and finally are conducive to satisfactory phosphorescence. It is found that the intermolecular interactions, which are essential for organic phosphorescence, are easily disturbed by external stimuli such as mechanical force, photon, acid, chemical vapor, leading to the luminescence change. According to this principle, various purely organic phosphorescence materials sensitive to external stimuli have been developed. This Minireview categorizes reported stimuli‐responsive purely organic phosphorescence materials on the basis of different stimuli, including mechanochromism, mechanoluminescence, photoactivity, acid‐responsiveness and other stimuli. Some prospective strategies for constructing stimuli‐responsive purely organic phosphorescence molecules are provided. Stimulus check: The minireview categorizes reported stimuli‐responsive purely organic phosphorescence materials on the basis of different stimuli, including mechanochromism, mechanoluminescence, photoactivity, acid‐responsiveness and other stimuli. Some prospective strategies for constructing stimuli‐responsive purely organic phosphorescence molecules are provided. |
| Author | Ma, Zhiyong Qian, Chen Huang, Lili |
| Author_xml | – sequence: 1 givenname: Lili surname: Huang fullname: Huang, Lili organization: Beijing University of, Chemical Technology – sequence: 2 givenname: Chen surname: Qian fullname: Qian, Chen organization: Beijing University of, Chemical Technology – sequence: 3 givenname: Zhiyong orcidid: 0000-0002-2942-6545 surname: Ma fullname: Ma, Zhiyong email: mazhy@mail.buct.edu.cn organization: Beijing University of, Chemical Technology |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/32159896$$D View this record in MEDLINE/PubMed |
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| Copyright | 2020 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim 2020 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. 2020 Wiley‐VCH GmbH |
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| Keywords | organic phosphorescence intermolecular interactions stimuli-responsive photoactivity mechanical forces |
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| Snippet | This Minireview summarizes the recent progress of stimuli‐responsive purely organic phosphorescence materials. Organic phosphorescence is closely related to... This Minireview summarizes the recent progress of stimuli-responsive purely organic phosphorescence materials. Organic phosphorescence is closely related to... |
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| SubjectTerms | Chemistry Coupling (molecular) External stimuli intermolecular interactions mechanical forces Mechanoluminescence organic phosphorescence Phosphorescence photoactivity Stimuli stimuli-responsive |
| Title | Stimuli‐Responsive Purely Organic Room‐Temperature Phosphorescence Materials |
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