Assembly‐Induced Strong Circularly Polarized Luminescence of Spirocyclic Chiral Silver(I) Clusters
Spirocyclic Ag9 clusters, as a new form of intrinsically chiral metal clusters, were constructed through vertex‐sharing of two in‐situ‐generated heteroaryl diide‐centered metal rings. Such core‐peripheral type clusters exhibit versatile photoluminescent and chiroptical behavior under different aggre...
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| Published in | Angewandte Chemie International Edition Vol. 60; no. 3; pp. 1535 - 1539 |
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| Main Authors | , , , , |
| Format | Journal Article |
| Language | English |
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18.01.2021
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| Edition | International ed. in English |
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| Abstract | Spirocyclic Ag9 clusters, as a new form of intrinsically chiral metal clusters, were constructed through vertex‐sharing of two in‐situ‐generated heteroaryl diide‐centered metal rings. Such core‐peripheral type clusters exhibit versatile photoluminescent and chiroptical behavior under different aggregation conditions. In contrast to a ligand‐based fluorescence emission in a diluted solution of the clusters, a solvent polarity‐caused assembly gives rise to new cluster‐based phosphorous luminescence owing to radiative mode switching and aggregation‐induced emission. Assembly of cluster enantiomers leads to micrometer‐long helical nanofibers, whose handedness is determined by absolute configuration of individual spirocyclic clusters. Benefiting from exciton couplings of helical arrangements of chelating ligands at molecular and microscopic levels, the assembled film of cluster enantiomers exhibits circularly polarized luminescence with a high anisotropy factor (0.16).
Two spirocyclic Ag9 chiral clusters, as a new form of intrinsic chiral metal clusters, have been constructed. They show unique fluorescence‐to‐phosphorescence switching and aggregation‐induced emission under different aggregation conditions. The assembly of cluster enantiomers leads to micrometer‐long helical nanofibers and superior circularly polarized luminescence performance with a remarkably high anisotropy factor of 0.16. |
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| AbstractList | Spirocyclic Ag
clusters, as a new form of intrinsically chiral metal clusters, were constructed through vertex-sharing of two in-situ-generated heteroaryl diide-centered metal rings. Such core-peripheral type clusters exhibit versatile photoluminescent and chiroptical behavior under different aggregation conditions. In contrast to a ligand-based fluorescence emission in a diluted solution of the clusters, a solvent polarity-caused assembly gives rise to new cluster-based phosphorous luminescence owing to radiative mode switching and aggregation-induced emission. Assembly of cluster enantiomers leads to micrometer-long helical nanofibers, whose handedness is determined by absolute configuration of individual spirocyclic clusters. Benefiting from exciton couplings of helical arrangements of chelating ligands at molecular and microscopic levels, the assembled film of cluster enantiomers exhibits circularly polarized luminescence with a high anisotropy factor (0.16). Spirocyclic Ag 9 clusters, as a new form of intrinsically chiral metal clusters, were constructed through vertex‐sharing of two in‐situ‐generated heteroaryl diide‐centered metal rings. Such core‐peripheral type clusters exhibit versatile photoluminescent and chiroptical behavior under different aggregation conditions. In contrast to a ligand‐based fluorescence emission in a diluted solution of the clusters, a solvent polarity‐caused assembly gives rise to new cluster‐based phosphorous luminescence owing to radiative mode switching and aggregation‐induced emission. Assembly of cluster enantiomers leads to micrometer‐long helical nanofibers, whose handedness is determined by absolute configuration of individual spirocyclic clusters. Benefiting from exciton couplings of helical arrangements of chelating ligands at molecular and microscopic levels, the assembled film of cluster enantiomers exhibits circularly polarized luminescence with a high anisotropy factor (0.16). Spirocyclic Ag9 clusters, as a new form of intrinsically chiral metal clusters, were constructed through vertex‐sharing of two in‐situ‐generated heteroaryl diide‐centered metal rings. Such core‐peripheral type clusters exhibit versatile photoluminescent and chiroptical behavior under different aggregation conditions. In contrast to a ligand‐based fluorescence emission in a diluted solution of the clusters, a solvent polarity‐caused assembly gives rise to new cluster‐based phosphorous luminescence owing to radiative mode switching and aggregation‐induced emission. Assembly of cluster enantiomers leads to micrometer‐long helical nanofibers, whose handedness is determined by absolute configuration of individual spirocyclic clusters. Benefiting from exciton couplings of helical arrangements of chelating ligands at molecular and microscopic levels, the assembled film of cluster enantiomers exhibits circularly polarized luminescence with a high anisotropy factor (0.16). Spirocyclic Ag9 clusters, as a new form of intrinsically chiral metal clusters, were constructed through vertex‐sharing of two in‐situ‐generated heteroaryl diide‐centered metal rings. Such core‐peripheral type clusters exhibit versatile photoluminescent and chiroptical behavior under different aggregation conditions. In contrast to a ligand‐based fluorescence emission in a diluted solution of the clusters, a solvent polarity‐caused assembly gives rise to new cluster‐based phosphorous luminescence owing to radiative mode switching and aggregation‐induced emission. Assembly of cluster enantiomers leads to micrometer‐long helical nanofibers, whose handedness is determined by absolute configuration of individual spirocyclic clusters. Benefiting from exciton couplings of helical arrangements of chelating ligands at molecular and microscopic levels, the assembled film of cluster enantiomers exhibits circularly polarized luminescence with a high anisotropy factor (0.16). Two spirocyclic Ag9 chiral clusters, as a new form of intrinsic chiral metal clusters, have been constructed. They show unique fluorescence‐to‐phosphorescence switching and aggregation‐induced emission under different aggregation conditions. The assembly of cluster enantiomers leads to micrometer‐long helical nanofibers and superior circularly polarized luminescence performance with a remarkably high anisotropy factor of 0.16. Spirocyclic Ag9 clusters, as a new form of intrinsically chiral metal clusters, were constructed through vertex-sharing of two in-situ-generated heteroaryl diide-centered metal rings. Such core-peripheral type clusters exhibit versatile photoluminescent and chiroptical behavior under different aggregation conditions. In contrast to a ligand-based fluorescence emission in a diluted solution of the clusters, a solvent polarity-caused assembly gives rise to new cluster-based phosphorous luminescence owing to radiative mode switching and aggregation-induced emission. Assembly of cluster enantiomers leads to micrometer-long helical nanofibers, whose handedness is determined by absolute configuration of individual spirocyclic clusters. Benefiting from exciton couplings of helical arrangements of chelating ligands at molecular and microscopic levels, the assembled film of cluster enantiomers exhibits circularly polarized luminescence with a high anisotropy factor (0.16).Spirocyclic Ag9 clusters, as a new form of intrinsically chiral metal clusters, were constructed through vertex-sharing of two in-situ-generated heteroaryl diide-centered metal rings. Such core-peripheral type clusters exhibit versatile photoluminescent and chiroptical behavior under different aggregation conditions. In contrast to a ligand-based fluorescence emission in a diluted solution of the clusters, a solvent polarity-caused assembly gives rise to new cluster-based phosphorous luminescence owing to radiative mode switching and aggregation-induced emission. Assembly of cluster enantiomers leads to micrometer-long helical nanofibers, whose handedness is determined by absolute configuration of individual spirocyclic clusters. Benefiting from exciton couplings of helical arrangements of chelating ligands at molecular and microscopic levels, the assembled film of cluster enantiomers exhibits circularly polarized luminescence with a high anisotropy factor (0.16). |
| Author | He, Xin Wu, Han Yang, Biao Li, Cui‐Cui Zhao, Liang |
| Author_xml | – sequence: 1 givenname: Han surname: Wu fullname: Wu, Han organization: Tsinghua University – sequence: 2 givenname: Xin surname: He fullname: He, Xin organization: Tsinghua University – sequence: 3 givenname: Biao surname: Yang fullname: Yang, Biao organization: Tsinghua University – sequence: 4 givenname: Cui‐Cui surname: Li fullname: Li, Cui‐Cui organization: Tsinghua University – sequence: 5 givenname: Liang orcidid: 0000-0003-4646-2887 surname: Zhao fullname: Zhao, Liang email: zhaolchem@mail.tsinghua.edu.cn organization: Tsinghua University |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/32959488$$D View this record in MEDLINE/PubMed |
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| Keywords | aggregation-induced emission supramolecular assembly cluster compounds circularly polarized luminescence (CPL) chirality |
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| Snippet | Spirocyclic Ag9 clusters, as a new form of intrinsically chiral metal clusters, were constructed through vertex‐sharing of two in‐situ‐generated heteroaryl... Spirocyclic Ag 9 clusters, as a new form of intrinsically chiral metal clusters, were constructed through vertex‐sharing of two in‐situ‐generated heteroaryl... Spirocyclic Ag clusters, as a new form of intrinsically chiral metal clusters, were constructed through vertex-sharing of two in-situ-generated heteroaryl... Spirocyclic Ag9 clusters, as a new form of intrinsically chiral metal clusters, were constructed through vertex-sharing of two in-situ-generated heteroaryl... |
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| SubjectTerms | Absolute configuration Agglomeration Aggregation behavior aggregation-induced emission Anisotropy Assembly Chelation chirality Circular polarization circularly polarized luminescence (CPL) cluster compounds Couplings Emission Emissions Enantiomers Excitons Fluorescence Handedness Ligands Luminescence Metal clusters Nanofibers Photoluminescence Polarity Silver supramolecular assembly |
| Title | Assembly‐Induced Strong Circularly Polarized Luminescence of Spirocyclic Chiral Silver(I) Clusters |
| URI | https://onlinelibrary.wiley.com/doi/abs/10.1002%2Fanie.202008765 https://www.ncbi.nlm.nih.gov/pubmed/32959488 https://www.proquest.com/docview/2476860331 https://www.proquest.com/docview/2444881332 |
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