A Highly Red‐Emissive Lead‐Free Indium‐Based Perovskite Single Crystal for Sensitive Water Detection
Low‐dimensional luminescent lead halide perovskites have attracted tremendous attention for their fascinating optoelectronic properties, while the toxicity of lead is still considered a drawback. Herein, we report a novel lead‐free zero‐dimensional (0D) indium‐based perovskite (Cs2InBr5⋅H2O) single...
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Published in | Angewandte Chemie International Edition Vol. 58; no. 16; pp. 5277 - 5281 |
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Main Authors | , , , , , , , , |
Format | Journal Article |
Language | English |
Published |
Germany
Wiley Subscription Services, Inc
08.04.2019
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Edition | International ed. in English |
Subjects | |
Online Access | Get full text |
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Abstract | Low‐dimensional luminescent lead halide perovskites have attracted tremendous attention for their fascinating optoelectronic properties, while the toxicity of lead is still considered a drawback. Herein, we report a novel lead‐free zero‐dimensional (0D) indium‐based perovskite (Cs2InBr5⋅H2O) single crystal that is red‐luminescent with a high photoluminescence quantum yield (PLQY) of 33 %. Experimental and computational studies reveal that the strong PL emission might originate from self‐trapping excitons (STEs) that result from an excited‐state structural deformation. More importantly, the in situ transformation between hydrated Cs2InBr5⋅H2O and the dehydrated form is accompanied with a switchable dual emission, which enables it to act as a PL water‐sensor in humidity detection or the detection of traces of water in organic solvents.
Unleaded and unleashed: A highly emissive lead‐free indium‐based perovskite single crystal, Cs2InBr5⋅H2O, was successfully prepared. The versatile material is the first reversible metal halide perovskite photoluminescence water sensor and paves the way for the application of metal halide perovskites in water detection. |
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AbstractList | Low‐dimensional luminescent lead halide perovskites have attracted tremendous attention for their fascinating optoelectronic properties, while the toxicity of lead is still considered a drawback. Herein, we report a novel lead‐free zero‐dimensional (0D) indium‐based perovskite (Cs2InBr5⋅H2O) single crystal that is red‐luminescent with a high photoluminescence quantum yield (PLQY) of 33 %. Experimental and computational studies reveal that the strong PL emission might originate from self‐trapping excitons (STEs) that result from an excited‐state structural deformation. More importantly, the in situ transformation between hydrated Cs2InBr5⋅H2O and the dehydrated form is accompanied with a switchable dual emission, which enables it to act as a PL water‐sensor in humidity detection or the detection of traces of water in organic solvents.
Unleaded and unleashed: A highly emissive lead‐free indium‐based perovskite single crystal, Cs2InBr5⋅H2O, was successfully prepared. The versatile material is the first reversible metal halide perovskite photoluminescence water sensor and paves the way for the application of metal halide perovskites in water detection. Low‐dimensional luminescent lead halide perovskites have attracted tremendous attention for their fascinating optoelectronic properties, while the toxicity of lead is still considered a drawback. Herein, we report a novel lead‐free zero‐dimensional (0D) indium‐based perovskite (Cs2InBr5⋅H2O) single crystal that is red‐luminescent with a high photoluminescence quantum yield (PLQY) of 33 %. Experimental and computational studies reveal that the strong PL emission might originate from self‐trapping excitons (STEs) that result from an excited‐state structural deformation. More importantly, the in situ transformation between hydrated Cs2InBr5⋅H2O and the dehydrated form is accompanied with a switchable dual emission, which enables it to act as a PL water‐sensor in humidity detection or the detection of traces of water in organic solvents. Low-dimensional luminescent lead halide perovskites have attracted tremendous attention for their fascinating optoelectronic properties, while the toxicity of lead is still considered a drawback. Herein, we report a novel lead-free zero-dimensional (0D) indium-based perovskite (Cs2 InBr5 ⋅H2 O) single crystal that is red-luminescent with a high photoluminescence quantum yield (PLQY) of 33 %. Experimental and computational studies reveal that the strong PL emission might originate from self-trapping excitons (STEs) that result from an excited-state structural deformation. More importantly, the in situ transformation between hydrated Cs2 InBr5 ⋅H2 O and the dehydrated form is accompanied with a switchable dual emission, which enables it to act as a PL water-sensor in humidity detection or the detection of traces of water in organic solvents.Low-dimensional luminescent lead halide perovskites have attracted tremendous attention for their fascinating optoelectronic properties, while the toxicity of lead is still considered a drawback. Herein, we report a novel lead-free zero-dimensional (0D) indium-based perovskite (Cs2 InBr5 ⋅H2 O) single crystal that is red-luminescent with a high photoluminescence quantum yield (PLQY) of 33 %. Experimental and computational studies reveal that the strong PL emission might originate from self-trapping excitons (STEs) that result from an excited-state structural deformation. More importantly, the in situ transformation between hydrated Cs2 InBr5 ⋅H2 O and the dehydrated form is accompanied with a switchable dual emission, which enables it to act as a PL water-sensor in humidity detection or the detection of traces of water in organic solvents. Low-dimensional luminescent lead halide perovskites have attracted tremendous attention for their fascinating optoelectronic properties, while the toxicity of lead is still considered a drawback. Herein, we report a novel lead-free zero-dimensional (0D) indium-based perovskite (Cs InBr ⋅H O) single crystal that is red-luminescent with a high photoluminescence quantum yield (PLQY) of 33 %. Experimental and computational studies reveal that the strong PL emission might originate from self-trapping excitons (STEs) that result from an excited-state structural deformation. More importantly, the in situ transformation between hydrated Cs InBr ⋅H O and the dehydrated form is accompanied with a switchable dual emission, which enables it to act as a PL water-sensor in humidity detection or the detection of traces of water in organic solvents. Low‐dimensional luminescent lead halide perovskites have attracted tremendous attention for their fascinating optoelectronic properties, while the toxicity of lead is still considered a drawback. Herein, we report a novel lead‐free zero‐dimensional (0D) indium‐based perovskite (Cs 2 InBr 5 ⋅H 2 O) single crystal that is red‐luminescent with a high photoluminescence quantum yield (PLQY) of 33 %. Experimental and computational studies reveal that the strong PL emission might originate from self‐trapping excitons (STEs) that result from an excited‐state structural deformation. More importantly, the in situ transformation between hydrated Cs 2 InBr 5 ⋅H 2 O and the dehydrated form is accompanied with a switchable dual emission, which enables it to act as a PL water‐sensor in humidity detection or the detection of traces of water in organic solvents. |
Author | Wei, Jun‐Hua Kuang, Dai‐Bin Liao, Jin‐Feng Chen, Hong‐Yan Zhou, Lei Huang, Zeng‐Guang Li, Wen‐Guang Su, Cheng‐Yong Wang, Xu‐Dong |
Author_xml | – sequence: 1 givenname: Lei surname: Zhou fullname: Zhou, Lei organization: Sun Yat-sen University – sequence: 2 givenname: Jin‐Feng surname: Liao fullname: Liao, Jin‐Feng organization: Sun Yat-sen University – sequence: 3 givenname: Zeng‐Guang surname: Huang fullname: Huang, Zeng‐Guang organization: Sun Yat-sen University – sequence: 4 givenname: Jun‐Hua surname: Wei fullname: Wei, Jun‐Hua organization: Sun Yat-sen University – sequence: 5 givenname: Xu‐Dong surname: Wang fullname: Wang, Xu‐Dong organization: Sun Yat-sen University – sequence: 6 givenname: Wen‐Guang surname: Li fullname: Li, Wen‐Guang organization: Sun Yat-sen University – sequence: 7 givenname: Hong‐Yan surname: Chen fullname: Chen, Hong‐Yan organization: Sun Yat-sen University – sequence: 8 givenname: Dai‐Bin orcidid: 0000-0001-6773-2319 surname: Kuang fullname: Kuang, Dai‐Bin email: kuangdb@mail.sysu.edu.cn organization: Sun Yat-sen University – sequence: 9 givenname: Cheng‐Yong surname: Su fullname: Su, Cheng‐Yong email: cesscy@mail.sysu.edu.cn organization: Sun Yat-sen University |
BackLink | https://www.ncbi.nlm.nih.gov/pubmed/30788885$$D View this record in MEDLINE/PubMed |
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Snippet | Low‐dimensional luminescent lead halide perovskites have attracted tremendous attention for their fascinating optoelectronic properties, while the toxicity of... Low-dimensional luminescent lead halide perovskites have attracted tremendous attention for their fascinating optoelectronic properties, while the toxicity of... |
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SubjectTerms | Computer applications Deformation Dehydration Emission analysis Emissions Excitons Indium Lead Lead-free materials Metal halides Optoelectronics Organic solvents Perovskites Photoluminescence Photons Single crystals Toxicity Water detection |
Title | A Highly Red‐Emissive Lead‐Free Indium‐Based Perovskite Single Crystal for Sensitive Water Detection |
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