Developing Luminescent Ratiometric Thermometers Based on a Covalent Organic Framework (COF)
Covalent Organic Frameworks (COFs), an emerging class of crystalline porous materials, are proposed as a new type of support for grafting lanthanide ions (Ln3+) and employing these hybrid materials as ratiometric luminescent thermometers. A TpBpy‐COF—prepared from 1,3,5‐triformylphloroglucinol (Tp)...
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| Published in | Angewandte Chemie International Edition Vol. 59; no. 5; pp. 1932 - 1940 |
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| Main Authors | , , , , , , |
| Format | Journal Article |
| Language | English |
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Germany
Wiley Subscription Services, Inc
27.01.2020
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| Edition | International ed. in English |
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| Abstract | Covalent Organic Frameworks (COFs), an emerging class of crystalline porous materials, are proposed as a new type of support for grafting lanthanide ions (Ln3+) and employing these hybrid materials as ratiometric luminescent thermometers. A TpBpy‐COF—prepared from 1,3,5‐triformylphloroglucinol (Tp) and 2,2′‐bipyridine‐5,5′‐diamine (Bpy) grafted with Eu/Tb and Dy acetylacetone (acac) complexes can be successfully used as a luminescent thermometer in the 10–360 K (Eu) and 280–440 K (Tb) ranges with good sensing properties (thermal sensitivity up to 1.403 % K−1, temperature uncertainty δT<1 K above 110 K). For the Eu/Tb systems, we observe an unusual and rarely reported behavior, that is, no thermal quenching of the Tb3+ emission, a result of the absence of ion‐to‐ligand/host energy back‐transfer. The LnCOF materials proposed here could be a new class of materials employed for temperature‐sensing applications following up on the well‐known luminescent metal–organic framework thermometers.
A hot candidate: Covalent organic frameworks (COFs) are reported to be an excellent support for the grafting of lanthanide ions/complexes and allow the development of novel types of luminescent thermometers. A unique behavior, that is, no thermal quenching of the Tb3+ emission, is observed in these LnCOF materials. |
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| AbstractList | Covalent Organic Frameworks (COFs), an emerging class of crystalline porous materials, are proposed as a new type of support for grafting lanthanide ions (Ln
3+
) and employing these hybrid materials as ratiometric luminescent thermometers. A TpBpy‐COF—prepared from 1,3,5‐triformylphloroglucinol (Tp) and 2,2′‐bipyridine‐5,5′‐diamine (Bpy) grafted with Eu/Tb and Dy acetylacetone (acac) complexes can be successfully used as a luminescent thermometer in the 10–360 K (Eu) and 280–440 K (Tb) ranges with good sensing properties (thermal sensitivity up to 1.403 % K
−1
, temperature uncertainty δ
T
<1 K above 110 K). For the Eu/Tb systems, we observe an unusual and rarely reported behavior, that is, no thermal quenching of the Tb
3+
emission, a result of the absence of ion‐to‐ligand/host energy back‐transfer. The LnCOF materials proposed here could be a new class of materials employed for temperature‐sensing applications following up on the well‐known luminescent metal–organic framework thermometers. Covalent Organic Frameworks (COFs), an emerging class of crystalline porous materials, are proposed as a new type of support for grafting lanthanide ions (Ln3+ ) and employing these hybrid materials as ratiometric luminescent thermometers. A TpBpy-COF-prepared from 1,3,5-triformylphloroglucinol (Tp) and 2,2'-bipyridine-5,5'-diamine (Bpy) grafted with Eu/Tb and Dy acetylacetone (acac) complexes can be successfully used as a luminescent thermometer in the 10-360 K (Eu) and 280-440 K (Tb) ranges with good sensing properties (thermal sensitivity up to 1.403 % K-1 , temperature uncertainty δT<1 K above 110 K). For the Eu/Tb systems, we observe an unusual and rarely reported behavior, that is, no thermal quenching of the Tb3+ emission, a result of the absence of ion-to-ligand/host energy back-transfer. The LnCOF materials proposed here could be a new class of materials employed for temperature-sensing applications following up on the well-known luminescent metal-organic framework thermometers.Covalent Organic Frameworks (COFs), an emerging class of crystalline porous materials, are proposed as a new type of support for grafting lanthanide ions (Ln3+ ) and employing these hybrid materials as ratiometric luminescent thermometers. A TpBpy-COF-prepared from 1,3,5-triformylphloroglucinol (Tp) and 2,2'-bipyridine-5,5'-diamine (Bpy) grafted with Eu/Tb and Dy acetylacetone (acac) complexes can be successfully used as a luminescent thermometer in the 10-360 K (Eu) and 280-440 K (Tb) ranges with good sensing properties (thermal sensitivity up to 1.403 % K-1 , temperature uncertainty δT<1 K above 110 K). For the Eu/Tb systems, we observe an unusual and rarely reported behavior, that is, no thermal quenching of the Tb3+ emission, a result of the absence of ion-to-ligand/host energy back-transfer. The LnCOF materials proposed here could be a new class of materials employed for temperature-sensing applications following up on the well-known luminescent metal-organic framework thermometers. Covalent Organic Frameworks (COFs), an emerging class of crystalline porous materials, are proposed as a new type of support for grafting lanthanide ions (Ln3+) and employing these hybrid materials as ratiometric luminescent thermometers. A TpBpy‐COF—prepared from 1,3,5‐triformylphloroglucinol (Tp) and 2,2′‐bipyridine‐5,5′‐diamine (Bpy) grafted with Eu/Tb and Dy acetylacetone (acac) complexes can be successfully used as a luminescent thermometer in the 10–360 K (Eu) and 280–440 K (Tb) ranges with good sensing properties (thermal sensitivity up to 1.403 % K−1, temperature uncertainty δT<1 K above 110 K). For the Eu/Tb systems, we observe an unusual and rarely reported behavior, that is, no thermal quenching of the Tb3+ emission, a result of the absence of ion‐to‐ligand/host energy back‐transfer. The LnCOF materials proposed here could be a new class of materials employed for temperature‐sensing applications following up on the well‐known luminescent metal–organic framework thermometers. A hot candidate: Covalent organic frameworks (COFs) are reported to be an excellent support for the grafting of lanthanide ions/complexes and allow the development of novel types of luminescent thermometers. A unique behavior, that is, no thermal quenching of the Tb3+ emission, is observed in these LnCOF materials. Covalent Organic Frameworks (COFs), an emerging class of crystalline porous materials, are proposed as a new type of support for grafting lanthanide ions (Ln ) and employing these hybrid materials as ratiometric luminescent thermometers. A TpBpy-COF-prepared from 1,3,5-triformylphloroglucinol (Tp) and 2,2'-bipyridine-5,5'-diamine (Bpy) grafted with Eu/Tb and Dy acetylacetone (acac) complexes can be successfully used as a luminescent thermometer in the 10-360 K (Eu) and 280-440 K (Tb) ranges with good sensing properties (thermal sensitivity up to 1.403 % K , temperature uncertainty δT<1 K above 110 K). For the Eu/Tb systems, we observe an unusual and rarely reported behavior, that is, no thermal quenching of the Tb emission, a result of the absence of ion-to-ligand/host energy back-transfer. The LnCOF materials proposed here could be a new class of materials employed for temperature-sensing applications following up on the well-known luminescent metal-organic framework thermometers. Covalent Organic Frameworks (COFs), an emerging class of crystalline porous materials, are proposed as a new type of support for grafting lanthanide ions (Ln3+) and employing these hybrid materials as ratiometric luminescent thermometers. A TpBpy‐COF—prepared from 1,3,5‐triformylphloroglucinol (Tp) and 2,2′‐bipyridine‐5,5′‐diamine (Bpy) grafted with Eu/Tb and Dy acetylacetone (acac) complexes can be successfully used as a luminescent thermometer in the 10–360 K (Eu) and 280–440 K (Tb) ranges with good sensing properties (thermal sensitivity up to 1.403 % K−1, temperature uncertainty δT<1 K above 110 K). For the Eu/Tb systems, we observe an unusual and rarely reported behavior, that is, no thermal quenching of the Tb3+ emission, a result of the absence of ion‐to‐ligand/host energy back‐transfer. The LnCOF materials proposed here could be a new class of materials employed for temperature‐sensing applications following up on the well‐known luminescent metal–organic framework thermometers. |
| Author | Artizzu, Flavia Liu, Ying‐Ya Kaczmarek, Mariusz K. Liu, Hengshuo Kaczmarek, Anna M. Carlos, Luís D. Van Der Voort, Pascal |
| Author_xml | – sequence: 1 givenname: Anna M. surname: Kaczmarek fullname: Kaczmarek, Anna M. email: anna.kaczmarek@ugent.be organization: Ghent University – sequence: 2 givenname: Ying‐Ya surname: Liu fullname: Liu, Ying‐Ya organization: Dalian University of Technology – sequence: 3 givenname: Mariusz K. orcidid: 0000-0001-5254-8762 surname: Kaczmarek fullname: Kaczmarek, Mariusz K. organization: Kazimierz Wielki University in Bydgoszcz – sequence: 4 givenname: Hengshuo surname: Liu fullname: Liu, Hengshuo organization: Dalian University of Technology – sequence: 5 givenname: Flavia surname: Artizzu fullname: Artizzu, Flavia organization: Ghent University – sequence: 6 givenname: Luís D. surname: Carlos fullname: Carlos, Luís D. email: lcarlos@ua.pt organization: Universidade de Aveiro – sequence: 7 givenname: Pascal surname: Van Der Voort fullname: Van Der Voort, Pascal organization: Ghent University |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/31777996$$D View this record in MEDLINE/PubMed |
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| Keywords | Sensors Lanthanides Ratiometric Thermometers Covalent Organic Frameworks Quenching |
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| Snippet | Covalent Organic Frameworks (COFs), an emerging class of crystalline porous materials, are proposed as a new type of support for grafting lanthanide ions... Covalent Organic Frameworks (COFs), an emerging class of crystalline porous materials, are proposed as a new type of support for grafting lanthanide ions (Ln... Covalent Organic Frameworks (COFs), an emerging class of crystalline porous materials, are proposed as a new type of support for grafting lanthanide ions (Ln )... Covalent Organic Frameworks (COFs), an emerging class of crystalline porous materials, are proposed as a new type of support for grafting lanthanide ions (Ln3+... |
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| SubjectTerms | Acetylacetone Covalent Organic Frameworks Diamines Lanthanides Metal-organic frameworks Porous materials Quenching Ratiometric Thermometers Sensors Thermometers |
| Title | Developing Luminescent Ratiometric Thermometers Based on a Covalent Organic Framework (COF) |
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