Optical Coupling Between Chiral Biomolecules and Semiconductor Nanoparticles: Size-Dependent Circular Dichroism Absorption
Sizing up QDs: CdTe or CdSe quantum dots (QDs) stabilized by chiral biomolecules show size‐dependent circular dichroism (CD) characteristics in the visible light region. Theoretical calculations reveal that the origin of this CD is the combination of the weak optical activity of the biomolecules and...
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| Published in | Angewandte Chemie International Edition Vol. 50; no. 48; pp. 11456 - 11459 |
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| Main Authors | , , , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Weinheim
WILEY-VCH Verlag
25.11.2011
WILEY‐VCH Verlag Wiley Subscription Services, Inc |
| Edition | International ed. in English |
| Subjects | |
| Online Access | Get full text |
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| Abstract | Sizing up QDs: CdTe or CdSe quantum dots (QDs) stabilized by chiral biomolecules show size‐dependent circular dichroism (CD) characteristics in the visible light region. Theoretical calculations reveal that the origin of this CD is the combination of the weak optical activity of the biomolecules and the large enhancement effects from the strong absorption of QDs. |
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| AbstractList | Sizing up QDs: CdTe or CdSe quantum dots (QDs) stabilized by chiral biomolecules show size‐dependent circular dichroism (CD) characteristics in the visible light region. Theoretical calculations reveal that the origin of this CD is the combination of the weak optical activity of the biomolecules and the large enhancement effects from the strong absorption of QDs. |
| Author | Tang, Zhiyong Zhu, Zhening Huang, Wenxiao Zhou, Yunlong Zhang, Wei Liu, Wenjing Gao, Yan Liu, Xuefeng Wu, Shaojue |
| Author_xml | – sequence: 1 givenname: Yunlong surname: Zhou fullname: Zhou, Yunlong organization: Laboratory of Nanomaterials, National Center for Nanoscience and Technology, Beijing 100190 (P. R. China) – sequence: 2 givenname: Zhening surname: Zhu fullname: Zhu, Zhening organization: Laboratory of Nanomaterials, National Center for Nanoscience and Technology, Beijing 100190 (P. R. China) – sequence: 3 givenname: Wenxiao surname: Huang fullname: Huang, Wenxiao organization: Laboratory of Nanomaterials, National Center for Nanoscience and Technology, Beijing 100190 (P. R. China) – sequence: 4 givenname: Wenjing surname: Liu fullname: Liu, Wenjing organization: Laboratory of Nanomaterials, National Center for Nanoscience and Technology, Beijing 100190 (P. R. China) – sequence: 5 givenname: Shaojue surname: Wu fullname: Wu, Shaojue organization: Laboratory of Nanomaterials, National Center for Nanoscience and Technology, Beijing 100190 (P. R. China) – sequence: 6 givenname: Xuefeng surname: Liu fullname: Liu, Xuefeng organization: Laboratory of Nanomaterials, National Center for Nanoscience and Technology, Beijing 100190 (P. R. China) – sequence: 7 givenname: Yan surname: Gao fullname: Gao, Yan organization: Laboratory of Nanomaterials, National Center for Nanoscience and Technology, Beijing 100190 (P. R. China) – sequence: 8 givenname: Wei surname: Zhang fullname: Zhang, Wei email: zhang_wei@iapcm.ac.cn organization: Institute of Applied Physics and Computational Mathematics, Beijing 100088 (P. R. China) – sequence: 9 givenname: Zhiyong surname: Tang fullname: Tang, Zhiyong email: zytang@nanoctr.cn organization: Laboratory of Nanomaterials, National Center for Nanoscience and Technology, Beijing 100190 (P. R. China) |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/22113805$$D View this record in MEDLINE/PubMed |
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| Copyright | Copyright © 2011 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim |
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| Notes | National Natural Science Foundation of China - No. 20973047; No. 10874020; No. 2010DFA51700 Chinese Academy of Sciences ArticleID:ANIE201103762 This work was partially supported by the National Natural Science Foundation for Distinguished Youth Scholars of China (21025310, Z.Y.T.), the National Natural Science Foundation of China (20973047, Z.Y.T.; 10874020, W.Z.), the National Research Fund for Fundamental Key Project (2009CB930401, Z.Y.T.; 2011CB922204, W.Z.), the China-Korea Joint Research Project (2010DFA51700, Z.Y.T.), and the 100-Talent Program of the Chinese Academy of Sciences (Z.Y.T.). National Natural Science Foundation - No. 21025310 istex:BB79958219CF6346C415504F0028EF555C5D871C ark:/67375/WNG-2W66G57N-9 This work was partially supported by the National Natural Science Foundation for Distinguished Youth Scholars of China (21025310, Z.Y.T.), the National Natural Science Foundation of China (20973047, Z.Y.T.; 10874020, W.Z.), the National Research Fund for Fundamental Key Project (2009CB930401, Z.Y.T.; 2011CB922204, W.Z.), the China–Korea Joint Research Project (2010DFA51700, Z.Y.T.), and the 100‐Talent Program of the Chinese Academy of Sciences (Z.Y.T.). ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
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| Snippet | Sizing up QDs: CdTe or CdSe quantum dots (QDs) stabilized by chiral biomolecules show size‐dependent circular dichroism (CD) characteristics in the visible... |
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| SubjectTerms | Cadmium Compounds - chemistry chirality circular dichroism Circular Dichroism - methods Cysteine - chemistry Glutathione - chemistry Nanostructures - chemistry Nanostructures - ultrastructure Optics and Photonics - methods Quantum Dots Selenium Compounds - chemistry size dependence Tellurium - chemistry |
| Title | Optical Coupling Between Chiral Biomolecules and Semiconductor Nanoparticles: Size-Dependent Circular Dichroism Absorption |
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