Selective Electrochemical Reduction of Carbon Dioxide to Ethanol on a Boron‐ and Nitrogen‐Co‐doped Nanodiamond
Electrochemical reduction of CO2 to ethanol, a clean and renewable liquid fuel with high heating value, is an attractive strategy for global warming mitigation and resource utilization. However, converting CO2 to ethanol remains great challenge due to the low activity, poor product selectivity and s...
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| Published in | Angewandte Chemie International Edition Vol. 56; no. 49; pp. 15607 - 15611 |
|---|---|
| Main Authors | , , , , , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Germany
Wiley Subscription Services, Inc
04.12.2017
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| Edition | International ed. in English |
| Subjects | |
| Online Access | Get full text |
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| Abstract | Electrochemical reduction of CO2 to ethanol, a clean and renewable liquid fuel with high heating value, is an attractive strategy for global warming mitigation and resource utilization. However, converting CO2 to ethanol remains great challenge due to the low activity, poor product selectivity and stability of electrocatalysts. Here, the B‐ and N‐co‐doped nanodiamond (BND) was reported as an efficient and stable electrode for selective reduction of CO2 to ethanol. Good ethanol selectivity was achieved on the BND with high Faradaic efficiency of 93.2 % (−1.0 V vs. RHE), which overcame the limitation of low selectivity for multicarbon or high heating value fuels. Its superior performance was mainly originated from the synergistic effect of B and N co‐doping, high N content and overpotential for hydrogen evolution. The possible pathway for CO2 reduction revealed by DFT computation was CO2→*COOH→*CO→*COCO→*COCH2OH→*CH2OCH2OH→CH3CH2OH.
Efficient and selective electrochemical reduction of CO2 to ethanol was achieved on a nonmetallic B‐ and N‐co‐doped nanodiamond used as an electrocatalyst. The synergistic effect of co‐doping, N content, and H2 evolution potential were used as key factors for tailoring ethanol selectivity. |
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| AbstractList | Electrochemical reduction of CO
to ethanol, a clean and renewable liquid fuel with high heating value, is an attractive strategy for global warming mitigation and resource utilization. However, converting CO
to ethanol remains great challenge due to the low activity, poor product selectivity and stability of electrocatalysts. Here, the B- and N-co-doped nanodiamond (BND) was reported as an efficient and stable electrode for selective reduction of CO
to ethanol. Good ethanol selectivity was achieved on the BND with high Faradaic efficiency of 93.2 % (-1.0 V vs. RHE), which overcame the limitation of low selectivity for multicarbon or high heating value fuels. Its superior performance was mainly originated from the synergistic effect of B and N co-doping, high N content and overpotential for hydrogen evolution. The possible pathway for CO
reduction revealed by DFT computation was CO
→*COOH→*CO→*COCO→*COCH
OH→*CH
OCH
OH→CH
CH
OH. Electrochemical reduction of CO2 to ethanol, a clean and renewable liquid fuel with high heating value, is an attractive strategy for global warming mitigation and resource utilization. However, converting CO2 to ethanol remains great challenge due to the low activity, poor product selectivity and stability of electrocatalysts. Here, the B- and N-co-doped nanodiamond (BND) was reported as an efficient and stable electrode for selective reduction of CO2 to ethanol. Good ethanol selectivity was achieved on the BND with high Faradaic efficiency of 93.2 % (-1.0 V vs. RHE), which overcame the limitation of low selectivity for multicarbon or high heating value fuels. Its superior performance was mainly originated from the synergistic effect of B and N co-doping, high N content and overpotential for hydrogen evolution. The possible pathway for CO2 reduction revealed by DFT computation was CO2 →*COOH→*CO→*COCO→*COCH2 OH→*CH2 OCH2 OH→CH3 CH2 OH.Electrochemical reduction of CO2 to ethanol, a clean and renewable liquid fuel with high heating value, is an attractive strategy for global warming mitigation and resource utilization. However, converting CO2 to ethanol remains great challenge due to the low activity, poor product selectivity and stability of electrocatalysts. Here, the B- and N-co-doped nanodiamond (BND) was reported as an efficient and stable electrode for selective reduction of CO2 to ethanol. Good ethanol selectivity was achieved on the BND with high Faradaic efficiency of 93.2 % (-1.0 V vs. RHE), which overcame the limitation of low selectivity for multicarbon or high heating value fuels. Its superior performance was mainly originated from the synergistic effect of B and N co-doping, high N content and overpotential for hydrogen evolution. The possible pathway for CO2 reduction revealed by DFT computation was CO2 →*COOH→*CO→*COCO→*COCH2 OH→*CH2 OCH2 OH→CH3 CH2 OH. Electrochemical reduction of CO 2 to ethanol, a clean and renewable liquid fuel with high heating value, is an attractive strategy for global warming mitigation and resource utilization. However, converting CO 2 to ethanol remains great challenge due to the low activity, poor product selectivity and stability of electrocatalysts. Here, the B‐ and N‐co‐doped nanodiamond (BND) was reported as an efficient and stable electrode for selective reduction of CO 2 to ethanol. Good ethanol selectivity was achieved on the BND with high Faradaic efficiency of 93.2 % (−1.0 V vs. RHE), which overcame the limitation of low selectivity for multicarbon or high heating value fuels. Its superior performance was mainly originated from the synergistic effect of B and N co‐doping, high N content and overpotential for hydrogen evolution. The possible pathway for CO 2 reduction revealed by DFT computation was CO 2 →*COOH→*CO→*COCO→*COCH 2 OH→*CH 2 OCH 2 OH→CH 3 CH 2 OH. Electrochemical reduction of CO2 to ethanol, a clean and renewable liquid fuel with high heating value, is an attractive strategy for global warming mitigation and resource utilization. However, converting CO2 to ethanol remains great challenge due to the low activity, poor product selectivity and stability of electrocatalysts. Here, the B‐ and N‐co‐doped nanodiamond (BND) was reported as an efficient and stable electrode for selective reduction of CO2 to ethanol. Good ethanol selectivity was achieved on the BND with high Faradaic efficiency of 93.2 % (−1.0 V vs. RHE), which overcame the limitation of low selectivity for multicarbon or high heating value fuels. Its superior performance was mainly originated from the synergistic effect of B and N co‐doping, high N content and overpotential for hydrogen evolution. The possible pathway for CO2 reduction revealed by DFT computation was CO2→*COOH→*CO→*COCO→*COCH2OH→*CH2OCH2OH→CH3CH2OH. Efficient and selective electrochemical reduction of CO2 to ethanol was achieved on a nonmetallic B‐ and N‐co‐doped nanodiamond used as an electrocatalyst. The synergistic effect of co‐doping, N content, and H2 evolution potential were used as key factors for tailoring ethanol selectivity. Electrochemical reduction of CO2 to ethanol, a clean and renewable liquid fuel with high heating value, is an attractive strategy for global warming mitigation and resource utilization. However, converting CO2 to ethanol remains great challenge due to the low activity, poor product selectivity and stability of electrocatalysts. Here, the B‐ and N‐co‐doped nanodiamond (BND) was reported as an efficient and stable electrode for selective reduction of CO2 to ethanol. Good ethanol selectivity was achieved on the BND with high Faradaic efficiency of 93.2 % (−1.0 V vs. RHE), which overcame the limitation of low selectivity for multicarbon or high heating value fuels. Its superior performance was mainly originated from the synergistic effect of B and N co‐doping, high N content and overpotential for hydrogen evolution. The possible pathway for CO2 reduction revealed by DFT computation was CO2→*COOH→*CO→*COCO→*COCH2OH→*CH2OCH2OH→CH3CH2OH. |
| Author | Zhao, Huimin Quan, Xie Fan, Xinfei Hoffmann, Michael R. Zhang, Yujing Yu, Hongtao Su, Yan Chen, Shuo Liu, Yanming Cheng, Kai Zhang, Yaobin |
| Author_xml | – sequence: 1 givenname: Yanming surname: Liu fullname: Liu, Yanming organization: Dalian University of Technology – sequence: 2 givenname: Yujing surname: Zhang fullname: Zhang, Yujing organization: Dalian University of Technology – sequence: 3 givenname: Kai surname: Cheng fullname: Cheng, Kai organization: Dalian University of Technology – sequence: 4 givenname: Xie orcidid: 0000-0003-3085-0789 surname: Quan fullname: Quan, Xie email: quanxie@dlut.edu.cn organization: Dalian University of Technology – sequence: 5 givenname: Xinfei surname: Fan fullname: Fan, Xinfei organization: Dalian University of Technology – sequence: 6 givenname: Yan surname: Su fullname: Su, Yan organization: Dalian University of Technology – sequence: 7 givenname: Shuo surname: Chen fullname: Chen, Shuo organization: Dalian University of Technology – sequence: 8 givenname: Huimin surname: Zhao fullname: Zhao, Huimin organization: Dalian University of Technology – sequence: 9 givenname: Yaobin surname: Zhang fullname: Zhang, Yaobin organization: Dalian University of Technology – sequence: 10 givenname: Hongtao surname: Yu fullname: Yu, Hongtao organization: Dalian University of Technology – sequence: 11 givenname: Michael R. surname: Hoffmann fullname: Hoffmann, Michael R. organization: California Institute of Technology |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/28914470$$D View this record in MEDLINE/PubMed |
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| ContentType | Journal Article |
| Copyright | 2017 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. |
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| DOI | 10.1002/anie.201706311 |
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| Edition | International ed. in English |
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| Issue | 49 |
| Keywords | doped nanodiamond heterogeneous catalysis CO2 reduction electrocatalysis ethanol |
| Language | English |
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| Snippet | Electrochemical reduction of CO2 to ethanol, a clean and renewable liquid fuel with high heating value, is an attractive strategy for global warming mitigation... Electrochemical reduction of CO 2 to ethanol, a clean and renewable liquid fuel with high heating value, is an attractive strategy for global warming... Electrochemical reduction of CO to ethanol, a clean and renewable liquid fuel with high heating value, is an attractive strategy for global warming mitigation... |
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| SubjectTerms | Boron Calorific value Carbon dioxide Carbon monoxide Chemical reduction Climate change CO2 reduction Diamonds doped nanodiamond electrocatalysis Electrocatalysts Electrochemistry Ethanol Global warming heterogeneous catalysis Hydrogen evolution Liquid fuels Nanostructure Nitrogen Renewable fuels Resource utilization Selectivity Synergistic effect |
| Title | Selective Electrochemical Reduction of Carbon Dioxide to Ethanol on a Boron‐ and Nitrogen‐Co‐doped Nanodiamond |
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